The incorporation of hydroxyl groups and molecular water in natural zircon (ZrSiO4)

American Journal of Science

Volumn 301, Issue 10, 2001, Pages 831-857

  Nasdala, Lutz ^a   Beran, Anton ^b   Libowitzky, Eugen ^b   Wolf, Dieter ^c  

^a JOHANNES GUTENBERG UNIVERSITY   (Germany)

^b UNIVERSITY OF VIENNA   (Austria)

^c TU BERGAKADEMIE FREIBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTAL CHEMISTRY; HYDROXYL RADICAL; WATER; ZIRCON;

EID: 0035565272     PISSN: 00029599     EISSN: None     Source Type: Journal    
DOI: 10.2475/ajs.301.10.831     Document Type: Article

References (54)

1. Aines, R. D., and Rossman, G. R., 1986, Relationships between radiation damage and trace water in zircon, quartz and topaz: American Mineralogist, v. 71, p. 1186-1193.
2. Akhmanova, M. V., and Leonova, L. L., 1961, Investigation of the metamict decay of zircon using infrared absorption spectra (in Russian): Geokhimiya, v. 1961/5, p. 401-414.
3. Bell, D.R., Ihinger, P.D., and Rossman, G.R., 1995, Quantitative analysis of trace OH in garnet and pyroxenes: American Mineralogist, v. 80, p. 465-474.
4. Beran, A., 1999, Contribution of IR spectroscopy to the problem of water in the Earth's mantle, in Wright, K., and Catlow, R., editors, Microscopic Properties and Processes in Minerals: Dordrecht, Kluwer Academic Publishers, p. 523-538.
5. - unit: Mineralogy and Petrology, v. 61, p. 223-235.
6. Biagini, R., Memmi, I., and Olmi, F., 1997, Radiation damage in zircons: Neues Jahrbuch für Mineralogie Monatshefte, v. 1997, p. 257-270.
7. Caruba, R., Baumer, A., Ganteaume, M., and Iacconi, P., 1985, An experimental study of hydroxyl groups and water in synthetic and natural zircons: a model of the metamict state: American Mineralogist, v. 70, p. 1224-1231.
8. Caruba, R., and Iacconi, P., 1983, Les zircons des pegmatites de Narssârssuk (Groënland) - l'eau et les groupments OH dans les zircons metamictes: Chemical Geology, v. 38, p. 75-92.
9. Chakoumakos, B. C., Murakami, T., Lumpkin, G. R., and Ewing, R. C., 1987, Alpha-decay-induced fracturing in zircon: The transition from the crystalline to the metamict state: Science, v. 236, p. 1556-1559.
10. Coleman, R. G., and Erd, R. C., 1961, Hydrozircon from the Wind River formation, Wyoming: of the United States Geological Survey, Journal of Research, v. 256, p.297-300.
11. Daniels, P., Krosse, S., Werding, G., and Schreyer, W., 1997, "Pseudosinhalite", a new hydrous MgAl-borate: synthesis, phase characterization, crystal structure, and PT-stability: Contributions to Mineralogy and Petrology, v. 128, p. 261-271.
12. 4): Journal of Physics C: Solid State Physics, v. 4, p. 240-256.
13. Deliens, M., Delhal, J., and Tarte, P., 1977, Metamictization and U-Pb systematics - a study by infrared absorption spectrometry of Precambrian zircons: Earth and Planetary Science Letters, v. 33, p. 331-344.
14. Frondel, C., 1953, Hydroxyl substitution in thorite and zircon: American Mineralogist, v. 38, p. 1007-1018.
15. Griffiths, P. R., and de Haseth, J. A., 1986, Fourier transform infrared spectroscopy: New York, John Wiley & Sons.
16. 8(OH)]: American Mineralogist, v. 83, p. 569-576.
17. Ilchenko, E. A., 1994, On hydroxyl-bearing zircons from kimberlites and kimberlit-like rocks (in Russian): Mineralogicheskij Zurnal, v. 16, p. 46-62.
18. Irmer, G., 1985, Zum Einfluβ der Apparatefunktion auf die Bestimmung von Streuquerschnitten und Lebensdauern aus optischen Phononenspektren: Experimentelle Technik der Physik, v. 33, p. 501-506.
19. Kosztolanyi, C., Eloy, J.-F., and Bertrand, J.-M., 1986, Étude de l'hétérogénéité des zircons du granite d'Anfeg (Algérie) à l'aide de méthodes microanalytiques: Bulletin de Minéralogie, v. 109, p. 265-274.
20. Lee, J. K. W., and Tromp, J., 1995, Self-induced fracture generation in zircon: Journal of Geophysical Research, v. 100, p. 17,753-17,770.
21. Libowitzky, E., 1999, Correlation of O-H stretching frequencies and O-H · · · O hydrogen bond lengths in minerals: Monatshefte für Chemie, v. 130, p. 1047-1059.
22. Libowitzky, E., and Rossman, G. R., 1996, Principles of quantitative absorbance measurements in anisotropic crystals: Physics and Chemistry of Minerals, v. 23, p. 319-327.
23. Libowitzky, E., and Rossman, G. R., 1997, An IR absorption calibration for water in minerals: American Mineralogist, v. 82, p. 1111-1115.
24. Lumpkin, G. R., and Chakoumakos, B. C., 1988, Chemistry and radiation effects of thorite-group minerals from the Harding pegmatite, Taos County, New Mexico: American Mineralogist, v. 73, p. 1405-1419.
25. Maldener J., Rauch, F., Gavranic, M., and Beran, A., 2001, OH absorption coefficients of rutile and cassiterite deduced from nuclear reaction analysis and FTIR spectroscopy: Mineralogy and Petrology, v. 71, p. 21-29.
26. Meldrum, A., Boatner, L. A., Weber, W. J., and Ewing, R. C., 1998, Radiation damage in zircon and monazite: Geochimica et Cosmochimica Acta, v. 62, p. 2509-2520.
27. 2H: confirmation of the chemical formula by neutron powder diffraction: American Mineralogist, v. 77, p. 839-842.
28. Mertz, L., 1965, Transformations in optics: New York, Wiley.
29. Mikenda, W., 1986, Stretching frequency versus bond distance correlation of O-D(H) · · · Y (Y = N, O, S, Se, Cl, Br, I) hydrogen bonds in solid hydrates: Journal of Molecular Structures, v. 147, p. 1-15.
30. Mumpton, F. A., and Roy, R., 1961, Hydrothermal stability studies of the zircon-thorite group: Geochimica et Cosmochimica Acta, v. 21, p. 217-238.
31. Murakami, T., Chakoumakos, B. C., Ewing, R. C., Lumpkin, G. R., Weber, W. J., 1991, Alpha-decay event damage in zircon: American Mineralogist, v. 76, p. 1510-1532.
32. Mursic, Z., Vogt, T., Boysen, H., and Frey, F., 1992, Single-crystal neutron diffraction study of metamict zircon up to 2000 K: Journal of Applied Crystallography, v. 25, p. 519-523.
33. Nasdala, L., Pidgeon, R. T., and Wolf, D., 1996, Heterogeneous metamictization of zircon on a microscale: Geochimica et Cosmochimica Acta, v. 60, p. 1091-1097.
34. Nasdala, L., Pidgeon, R. T., Wolf, D., and Irmer, G., 1998, Metamictization and U-Pb isotopic discordance in single zircons: a combined Raman microprobe and SHRIMP ion probe study: Mineralogy and Petrology, v. 62, p. 1-27.
35. Nasdala, L., Wolf, D., and Irmer, G., 1995, The degree of metamictization in zircon: a Raman spectroscopic study: European Journal of Mineralogy, v. 7, p. 471-478.
36. Novak, A., 1974, Hydrogen bonding in solids. Correlation of spectroscopic and crystallographic data: Structure and Bonding, v. 18, p. 177-216.
37. 3OH]: a single-crystal X-ray, FTIR, and structure modeling study: American Mineralogist, v. 82, p. 841-848.
38. Paterson, M.S., 1982, The determination of hydroxyl by infrared absorption in quartz, silicate glasses and similar materials: Bulletin de Minéralogie, v. 105, p. 20-29.
39. Robinson, K., Gibbs, G. V., and Ribbe, P. H., 1971, The structure of zircon: a comparison with garnet: American Mineralogist, v. 56, p. 782-790.
40. Rossman, G. R., 1990, Hydrogen in "anhydrous" minerals: Nuclear Instruments and Methods in Physics Research, v. B45, p. 41-44.
41. Rossman, G. R., and Aines, R. D., 1991, The hydrous components in garnets: Grossular-hydrogrossular: American Mineralogist, v. 76, p. 1153-1164.
42. Rudnitskaya, E. S., and Lipova, I. M., 1972, Infrared spectroscopic and NMR investigation of natural zircons (in Russian): Geologia i Razvedka, v. 1974/4, p. 43-50
43. Sahama, T. G., 1981, Growth structure in Ceylon zircon: Bulletin de Minéralogie, v. 104, p. 89-94.
44. Skogby, H., and Rossman, G.R., 1991, The intensity of amphibole OH bands in the infrared absorption spectrum: Physics and Chemistry of Minerals, v. 18, p. 64-86.
45. Smith, D. G. W., de St Jorre, L., Reed, J. S. B., and Long, J. V. P., 1991, Zonally metamictized and other zircons from Thor Lake, Northwest Territories: Canadian Mineralogist, v. 29, p. 301-309.
46. Sommerauer, J., ms, 1976, Die chemisch-physikalische Stabilität natürlicher Zirkone und ihr U-(Th)-Pb System: PhD thesis, Eidgenössische Technische Hochschule, Zürich.
47. Suzuki, K., 1988, Heterogeneous distribution of uranium within zircon grains: Implications for fission-track dating: Journal of the Geological Society (Japan), v. 94, p. 1-10.
48. Verma, P., Abbi, S. C., and Jain, K. P., 1995, Raman-scattering probe of anharmonic effects in GaAs: Physical Review B, v. 51, p. 16,660-16,667.
49. Wasiliewski, P. J., Senftle, F. E., Vaz, J. E., Thorpe, A. N., and Alexander, C. C., 1973, A study of the natural α-recoil damage in zircon by infrared spectra: Radiation Effects, v. 17, p. 191-199.
50. Weber, W. J., 1990, Radiation-induced effects and amorphization in zircon: Journal of Materials Research, v. 5, p. 2687-2697.
51. Weber, W. J., Ewing, R. C., and Meldrum, A., 1997, The kinetics of alpha-decay-induced amorphization in zircon and apatite containing weapons-grade plutonium or other actinides: Journal of Materials Research, v.250, p. 147-155.
52. Weber, W. J., Ewing, R. C., and Wang, L.-M., 1994, The radiation-induced crystalline-to-amorphous transition in zircon: Journal of Materials Research, v. 9, p. 688-698.
53. Woodhead, J. A., Rossman, G. R., and Silver, L. T., 1991, The metamictization of zircon: Radiation dose-dependent structural characteristics: American Mineralogist, v. 76, p. 74-82.
54. Woodhead, J. A., Rossman, G. R., and Thomas, A. P., 1991, Hydrous species in zircon: American Mineralogist, v. 76, p. 1533-1546.