Synthesis of a tridentate hydrosilane and its reaction with palladium(0) complexes

Chemistry Letters

Volumn , Issue 11, 2001, Pages 1096-1097

  Chen, Wanzhi ^a   Shimada, Shigeru ^a   Hayashi, Teruyuki ^a   Tanaka, Masato ^a  

^a NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0035541163     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2001.1096     Document Type: Article

References (19)

1. For recent reviews, see: M. S. Eisen, in "The Chemistry of Organic Silicon Compounds," ed. by Z. Rappoport and Y. Apeloig, Wiley, New York (1998), Vol. 2, Part 3, Chap. 35, p 2037; H. Ogino and H. Tobita, Adv. Organomet. Chem., 42, 223 (1998); J. Y. Corey and J. Braddock-Wilking, Chem. Rev., 99, 175 (1999).
2. For recent reviews, see: M. S. Eisen, in "The Chemistry of Organic Silicon Compounds," ed. by Z. Rappoport and Y. Apeloig, Wiley, New York (1998), Vol. 2, Part 3, Chap. 35, p 2037; H. Ogino and H. Tobita, Adv. Organomet. Chem., 42, 223 (1998); J. Y. Corey and J. Braddock-Wilking, Chem. Rev., 99, 175 (1999).
3. For recent reviews, see: M. S. Eisen, in "The Chemistry of Organic Silicon Compounds," ed. by Z. Rappoport and Y. Apeloig, Wiley, New York (1998), Vol. 2, Part 3, Chap. 35, p 2037; H. Ogino and H. Tobita, Adv. Organomet. Chem., 42, 223 (1998); J. Y. Corey and J. Braddock-Wilking, Chem. Rev., 99, 175 (1999).
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8. G.-R. Sun, Ph. D. Thesis, Kyoto University, Kyoto, Japan, 1995; private communications from K. Tamao.
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11. 3: C, 58.95; H, 6.60%. Found: C, 58.79; H, 6.57%.
12. 3 column chromatography (for 5b).
13. 2SiH).
14. Examples of μ-silylene-bridged dinuclear palladium complexes, see: a) M. Suginome, Y. Kato, N. Takeda, H. Oike, and Y. Ito, Organometallics, 17, 495 (1998).
15. b) Y.-J. Kim, S.-C. Lee, J.-I. Park, K. Osakada, J.-C. Choi, and T. Yamamoto, Organometallics, 17, 4329 (1998).
16. Y.-J. Kim, S.-C. Lee, J.-I. Park, K. Osakada, J.-C. Choi, and T. Yamamoto, J. Chem. Soc., Dalton Trans., 2000, 417.
17. 2 = 0.140 (for all data (4366 reflections)).
18. 2 = 0.135 (for all data (4650 reflections)).
19. Tilley has reported that a tris(silyl)(hidorido)platinum(IV) complex can be an intermediate for the dehydrocoupling reaction of phenylsilane: R. H. Heyn and T. D. Tilley, J. Am. Chem. Soc., 114, 1917 (1992).