Chemoselective reduction of α-imino carbonyl compounds into α-amino carbonyl compounds with titanium tetraiodide

Chemistry Letters

Volumn , Issue 8, 2001, Pages 792-793

  Shimizu, Makoto ^a   Sahara, Tetsuya ^a   Hayakawa, Ryuuichirou ^a  

^a MIE UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0035538670     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2001.792     Document Type: Article

References (15)

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14. 4 and concentrated in vacuo. Purification by silica gel flash column chromatography (n-hexane : ethyl acetate = 4 : 1 as an eluent) gave 1,2-diphenyl-2-p-toluenesulfonylaminoethanone (78.0 mg, 90%) as a colorless oil.
15. 1H NMR studies, and the subsequent reaction with aldehyde actually gave an aldol product. (Equation Presented)