Study of aqueous al2(so4)3 solution under hydrothermal conditions: Sulfate ion pairing, hydrolysis, and formation of hydronium alunite

Journal of Solution Chemistry

Volumn 30, Issue 6, 2001, Pages 527-548

  Rudolph, Wolfram W ^a,b   Mason, Roger ^a  

^a MEMORIAL UNIVERSITY OF NEWFOUNDLAND   (Canada)

^b DRESDEN UNIVERSITY OF TECHNOLOGY   (Germany)

Author keywords

Al(III) sulfato complex formation; Al(III) hydrolysis; Aluminum sulfate solution; Hydronium alunite; Raman and infrared spectroscopy; Unit cell parameters; X ray diffraction

Indexed keywords

EID: 0035535616     PISSN: 00959782     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1010334818580     Document Type: Article

References (25)

1. 1. A. V. Zotov, Geochem. Intern. 1, 71 (1971).
2. 2. K. Scott, Amer. Mineral. 72, 178 (1987).
3. 3. A. Lükewille and J. Prenzel, Appli. Geochem. Suppl. 131 (1993).
4. 4. J. W. Akitt, J. A. Farnsworth, and P. Letellier, J. Chem. Soc. Faraday Trans. I. 81, 193 (1985).
5. 5. W. W. Rudolph and S. Schönherr, Z. Phys. Chem. (München) 172, 31 (1991).
6. 6. W. W. Rudolph and S. Schönherr, Z. Phys. Chem. (Leipzig) 270, 1121 (1989).
7. 7. W. W. Rudolph, R. Mason, and C. C. Pye, Phys. Chem. Chem. Phys. 2, 5030 (2000).
8. 8. W. W. Rudolph, Z. Phys. Chem. 194, 73 (1996).
9. 9. A. I. Vogel, A Text-Book of Quantitative Inorganic Analysis. 3rd edn., (Longman, London, 1961).
10. 10. W. E. Harris and B. Kratochvil, An introduction to Chemical Analysis (Saunders College, Philadelphia, PA, 1981), pp. 75, 203.
11. 11. W. W. Rudolph and C. C. Pye, J. Solution Chem. 28, 1045 (1999).
12. 12. M. H. Brooker, N. O. Faurskov, and E. Praestgaard, 19, 71 (1988).
13. 13. W. W. Rudolph, J. Chem. Soc. Faraday Trans. 94, 489 (1998).
14. 14. C. Finch, Current Res., Newfoundland Department of Mines and Energy, Geological Survey Branch, Reprt. 93-1, p. 435 (1993).
15. 15. P. M. Bertsch, The Environmental Chemistry of Aluminum ed., G. Sposito ed. (CRC Press, Boca Raton, FL, 1989), Chap. 4.
16. 16. W. W. Rudolph and C. C. Pye, J. Solution Chem. 29, 1045 (2000).
17. 17. W. W. Rudolph, M. H. Brooker, and P. R. Tremaine, Z. Phys. Chem. 209. 181 (1999).
18. 18. W. W. Rudolph, M. H. Brooker, and P. R. Tremaine, J. Solution Chem. 28, 621 (1999).
19. 19. K. Nakamoto, J. Fujita, S. Tanaka, and M. Kobayashi, J. Amer. Chem. Soc. 79, 4904 (1957).
20. 20. D. A. Palmer and D. J. Wesolowski, Geochim. Cosmochim. Acta 57, 2929 (1993).
21. 21. R. E. Stoffregen and Ch. N. Alpers, Amer. Mineral. 77, 1092 (1992).
22. 22. V. C. Farmer, The Infrared Spectra of Minerals (Mineralogical Society, London, 1974).
23. 23. J. W. Akitt, N. N. Greenwood, and B. L. Khandelwal, J. C. Hem. Soc. Dalton, 1226 (1972).
24. 24. C. C. Pye and W. W. Rudolph, J. Phys. Chem. A, 105, 905 (2001).
25. 25. S. Menchetti and C. Sabelli, N. Jb. Miner. Mh., 406 (1976).