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The negative control in the absence of the clay gave oligomers up to only trimers and trace amounts of letramers. Chain length of each oligomer was estimated by comparison with an authentic sample of r(pA)26.
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15 In order to evaluated the selectivity, they used low concentration conditions of racemic ImpA to minimize the formation of trimers and longer oligomers. Therefore, their results might not reflect the selectivity in the reactions producing longer oligomers. Indeed, they focused on the product ratio of only four dimers for evaluation of the selectivity, although we observed six dimers in the racemic reaction.
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