A mass spectrometric study of the thermodynamic properties of oxide melts

Glass Physics and Chemistry

Volumn 27, Issue 1, 2001, Pages 3-15

  Stolyarova, V L ^a  

^a GREBENSHCHIKOV INSTITUTE OF SILICATE CHEMISTRY   (Russian Federation)

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[No Author keywords available]

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EID: 0035529938     PISSN: 10876596     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1009599502138     Document Type: Article

References (122)

1. Stolyarova, V.L. and Semenov, G.A., Mass Spectrometric Study of the Vaporization of Oxide Systems, Chichester: Wiley, 1994.
2. Asano, M., Kubo, K., and Nakagawa, H., Determination of Heats of Formation for Solid and Liquid Lithium Metasilicates by Vaporization Method, J. Nucl. Sci. Technol., 1983, vol. 20, no. 12, pp. 1051-1053.
3. Nakagawa, H., Asano, M., and Kubo, K., Mass Spectrometric Study of the Vaporization of Lithium Metasilicate, J. Nucl. Mater., 1981, vol. 102, no. 3, pp. 292-297.
4. 2, Silicaty, 1973, no. 4, pp. 269-281.
5. Altemose, V.O. and Tong, S.S.C., Evaporation from Binary Glasses by High Temperature Mass Spectrometry, J. Non-Cryst. Solids, 1980, vols. 38-39, pp. 587-592.
6. Argent, B.B., Jones, K., and Kirkbride, B.J., Vapours in Equilibrium with Glass Melts, in The Industrial Use of Thermochemical Data, Special Publication no. 34, Barry, T.I., Ed., London, 1980, pp. 379-390.
7. Piacente, V. and Matousek, J., Alkali Vapor Pressures over Some Simple Silicate Melts, Collect. Czech. Chem. Commun., 1983, vol. 48, no. 6, pp. 1528-1531.
8. 2 System, Fiz. Khim. Stekla, 1987, vol. 13, no. 2, pp. 168-172.
9. Vovk, O.M., Rudnyi, E.B., Sidorov, L.N., Stolyarova, V.L., Shakhmatkin, B.A., and Rakhimov, V.I., Determination of Thermodynamic Properties in the Sodium Silicate System by Ion-Molecule Equilibrium Method, Fiz. Khim. Stekla, 1988, vol. 14, no. 2, pp. 218-225.
10. 2 Solutions by a Knudsen Effusion Mass Spectrometric Method, in NBS Special Publication 561/1: Characterization of High Temperature Vapors and Gases, Washington, 1979, vol. 1, pp. 265-281.
11. 3, Rev. Int. Hautes Temp. Refract., 1979, vol. 16, no. 3, pp. 255-261.
12. 2 System, Advances in the Science of Iron and Steelmaking, Japan-United States Seminar, Kyoto, 1983, pp. 49-57.
13. Kambayashi, S. and Kato, E., A Thermodynamic Study of (Magnesium Oxide-Silicon Dioxide) by Mass Spectrometry, J. Chem. Thermodyn., 1983, vol. 15, no. 7, pp. 701-707.
14. Kambayashi, S. and Kato, E., A Thermodynamic Study of (Magnesium Oxide-Silicon Dioxide) by Mass Spectrometry at 1973 K, J. Chem. Thermodyn., 1984, vol. 16, no. 3, pp. 241-248.
15. 2 System, J. Electrochem. Soc., 1991, vol. 138, no. 12, pp. 3710-3714.
16. Semenov, G.A. and Petrova, M.A., Mass-Spectrometric Study of Stability of Gaseous Compounds of the "Double" Oxide Type, Tezisy dokl. soveshchaniya po problemam sovremennoi khimii koordinatsionnykh soedinenii (Abstracts of Papers, Conf. on Problems in Modern Chemistry of Coordination Compounds), Leningrad: Khimiya, 1966, p. 39.
17. Hilpert, K., Chemistry of Inorganic Vapors, Struct. Bonding (Berlin), 1990, vol. 73, pp. 1-198.
18. 2 System, Fiz. Khim. Stekla, 1986, vol. 12, no. 3, pp. 285-292.
19. 2 Systems, Fiz. Khim. Stekla, 1986, vol. 12, no. 4, pp. 385-390.
20. 2 System, Fiz. Khim. Stekla, 1987, vol. 13, no. 6, pp. 830-838.
21. 2 System, Chemical Metallurgy of Iron and Steel, Proc. Int. Symp. on Metallurgical Chemistry: Application in Ferrous Metallurgy, London, 1973, pp. 26-27.
22. 3 et au calcul des equilibres de desoxydation, Thèse, Inst. Nat. Polytechnique de Grenoble, Grenoble, 1983.
23. Dhima, A., Stafa, B., and Allibert, M., Activity Measurements in Steelmaking-Related Oxide Melts by Differential Mass Spectrometry, High Temp. Sci., 1986, vol. 21, no. 2, pp. 143-159.
24. 2 in the Temperature Range 1330-1540 K, Fiz. Khim. Stekla, 1979, vol. 5, no. 6, pp. 651-658.
25. 2 System, Izv. Akad. Nauk SSSR, Neorg. Mater., 1979, vol. 15, no. 6, pp. 1002-1007.
26. 2 Glassforming Melts, J. Non-Cryst. Solids, 1980, vols. 38-39, pp. 581-586.
27. 2 System, Dokl. Akad. Nauk SSSR, 1979, vol. 246, no. 1, pp. 154-156.
28. 2 from the Data of High-Temperature Mass Spectrometry, Zh. Fiz. Khim., 1996, vol. 70, no. 6, pp. 997-998.
29. 2 System, Fiz. Khim. Stekla, 1977, vol. 3, no. 6, pp. 535-537.
30. 2 System, in Sovremennye problemy neorganicheskoi khimii (Modern Problems in Inorganic Chemistry), Available from ONII TEKhim, 1978, Cherkassy, no. 2215/78, pp. 88-92.
31. 3 System, Fiz. Khim. Stekla, 1978, vol. 4, no. 6, pp. 653-661.
32. 3 System, Fiz. Khim. Stekla, 1981, vol. 7, no. 3, pp. 380-382.
33. 2 Glass-Forming System, Fiz. Khim. Stekla, 1981, vol. 7, no. 5, pp. 606-611.
34. 3 System, Fiz. Khim. Stekla, 1979, vol. 5, no. 1, pp. 42-51.
35. Blackburn, P.E. and Buchler, A., The Thermodynamics of Vaporization in the Beryllium Oxide-Boron Oxide System, J. Phys. Chem., 1965, vol. 69, no. 12, pp. 4250-4255.
36. Gusarov, A.V., Determination of Stability of Gaseous Magnesium Metaborates, Teplofiz. Vys. Temp., 1970, vol. 8, no. 6, pp. 1186-1191.
37. Stolyarova, V.L., Shilov, A.L., and Seetharaman, S., Relative Volatility of Borate Glasses and Melts Studied by High Temperature Mass Spectrometry, Proc. Int. Congress on Glass, Beijing: Chinese Ceram. Soc., 1995, vol. 7, pp. 155-160.
38. Stolyarova, V.L. and Seetharaman, S., Vaporization Studies of Oxide Systems Using a QMS-420 Mass Spectrometer, Vacuum, 1998, vol. 49, no. 3, pp. 161-165.
39. 3 System, High Temp. Sci., 1987, vol. 24, no. 1, pp. 1-19.
40. 4 (s), J. Chem. Thermodyn., 1988, vol. 20, no. 10, pp. 1149-1156.
41. 2 (g), Bull. Inst. At. Energy, Kyoto Univ., 1988, vol. 73, no. 3, p. 50.
42. 3 System, Bull. Inst. At. Energy, Kyoto Univ., 1988, vol. 73, no. 3, p. 49.
43. 2 (g), J. Chem. Thermodyn., 1990, vol. 22, no. 12, pp. 1223-1230.
44. Il'in, M.K., Makarov, A.V., and Nikitin, O.T., Mass-Spectrometric Study of Vaporization Processes in Barium Metaborate, Vestn. Mosk. Univ., Ser. 2: Khim., 1974, no. 5, pp. 436-438.
45. 6 (s), J. Chem. Thermodyn., 1989, vol. 21, no. 8, pp. 837-845.
46. 3 System, High Temp. Sci., 1990, vol. 29, no. 3, pp. 171-187.
47. 3 System, Proc. Sundaram Symp., Kalpakkam, India, 1991, pp. 429-431.
48. 3 System, Fiz. Khim. Stekla, 1987, vol. 13, no. 5, p. 672-676.
49. 3 System, Fiz. Khim. Stekla, 1987, vol. 13, no. 4, pp. 542-547.
50. 3 Glass-Forming System, Fiz. Khim. Stekla, 1981, vol. 7, no. 2, pp. 223-227.
51. 5 System, High Temp.-High Press., 1988, vol. 20, no. 4, pp. 361-378.
52. Semenov, G.A., Lopatin, S.I., Kozyukova, N.V., and Kuligina, L.A., Thermodynamics of Formation of the Gaseous Ternary Oxide Compounds of Alkaline-Earth Metals at High Temperatures, High Temp.-High Press., 1988, vol. 20, no. 6, pp. 637-641.
53. Lopatin, S.I. and Semenov, G.A., Mass Spectrometric Study of Thermal Dissociation of Alkaline-Earth Metal Monophosphates, Izv. Akad. Nauk SSSR, Neorgan. Mater., 1989, vol. 25, no. 4, pp. 645-650.
54. Lopatin, S.I., Vaporization in Phosphate Systems, Zh. Obshch. Khim., 1997, vol. 67, no. 2, pp. 193-211.
55. 5 System, Zh. Fiz. Khim., 1996, vol. 70, no. 3, pp. 485-491.
56. 5 System, in Razrabotka, issledovanie i primenenie fosfatnykh materialov v stroitel'stve. Tr. Tsentral'nogo Issledovatel'skogo Inst. Stroitel'nykh Konstruktsii im. V.A. Kucherenko (Development, Study, and Application of Phosphate Materials in Building, Proc. Kucherenko Central Res. Inst. of Building Constructions), Moscow: TsNIISK, 1992, pp. 32-46.
57. 5 System, Rapid Commun. Mass Spectrom., 1990, vol. 4, no. 12, pp. 510-512.
58. 5 Slags, Tetsu to Hagane, J. Iron Steel Inst. Jpn., 1984, vol. 70, no. 12, p. 863.
59. 5 Systems, Tetsu to Hagane, J. Iron Steel Inst. Jpn., 1985, vol. 71, no. 16, pp. 1911-1918.
60. Chatillon, C., Allibert, M., and Pattoret, A., Etude thermodinamique par spectrometrie de masse des alliages aliminium-silicium de 1000 à 1700 K, High Temp.-High Press., 1975, vol. 7, no. 5, pp. 583-594.
61. 2, Rapid Commun. Mass Spectrom., 1994, vol. 8, no. 5, pp. 478-480.
62. Blackburn, P.E., Buchler, A., and Stauffer, J.L., Thermodynamics of Vaporization in the Aluminum Oxide-Boron Oxide System, J. Phys. Chem., 1966, vol. 70, no. 8, pp. 2469-2474.
63. 3 System at 1248-1850 K, Rapid Commun. Mass Spectrom., 1995, vol. 9, no. 13, p. 1244-1251.
64. Lopatin, S.I. and Semenov, G.A., Vaporization Processes in Silicon and Germanium Diphosphates, Zh. Obshch. Khim., 1995, vol. 65, no. 7, pp. 1060-1064.
65. Preston, E. and Turner, W.E.S., Volatilization and Vapor Tension at High Temperatures of the Sodium Silicate-Silica Glasses, J. Soc. Glass Technol., 1932, vol. 16, no. 3, pp. 331-349.
66. Harrison, H.C., Lawrence, W.G., and Nucker, D.J., An Investigation of the Volatility of Glaze Constituents by the Use of the Spectrograph, J. Am. Ceram. Soc., 1940, vol. 23, no. 4, pp. 111-116.
67. 3: IV. Vapor Pressures of Boric Oxide, Sodium Metaborate and Sodium Diborate Between 1150°C and 1400°C, J. Am. Ceram. Soc., 1935, vol. 18, no. 3, pp. 82-85.
68. Kroger, C. and Stratmann, J., Dampfund Lersetzungsdrucke einiger an der Glasschmelze beteiligter Alkaliverbindungen, Glastech. Ber., 1961, vol. 34, no. 5, pp. 311-320.
69. Solomin, N.V., On the Chemical Compounds in Borate Glasses, in Stroenie stekla (Glass Structure), Moscow: Nauka, 1955, pp. 230-233.
70. Oldfield, L.F. and Wright, R.D., The Volatilization of Constituents from Borosilicate Glass at Elevated Temperatures, in Advances in Glass Technology, New York, 1962, part 1, pp. 35-51.
71. 2 System as a Method of Investigation into the Nature of the Vitreous State, in Stroenie stekla (Glass Structure), Moscow: Nauka, 1955, pp. 234-244.
72. Kroger, C. and Sorstrom, L.A., Dampfdruck von silicaglasern und deren Bestandteilen, Glastech. Ber., 1965, vol. 38, no. 8, pp. 313-322.
73. Kazenas, E.K. and Tsvetkov, Yu.V., Isparenie oksidov (Oxide Vaporization), Moscow: Nauka, 1997.
74. Semenov, G.A., Nikolaev, E.N., and Frantseva, K.E., Primenenie mass spektrometrii v neorganicheskoi khimii (Application of Mass Spectrometry in Inorganic Chemistry), Leningrad: Khimiya, 1976.
75. Sidorov, L.N., Korobov, M.V., and Zhuravleva, L.V., Mass-spektral'nye termodinamicheskie issledovaniya (Mass-Spectrometric Thermodynamic Investigations), Moscow: Mosk. Gos. Univ., 1985.
76. Farber, M. and Srivastava, R.D., Effusion Mass Spectrometric Determination of the Thermodynamic Properties of KAlO (g) and KSiO (g), High Temp. Sci., 1986, vol. 21, no. 1, pp. 17-26.
77. 2O (g), High Temp. Sci., 1973, vol. 5, no. 1, pp. 62-67.
78. 2 System in the Temperature Range 800-1200°C, Fiz. Khim. Stekla, 1980, vol. 6, no. 2, pp. 129-135.
79. Sanders, D.M. and Haller, W.K., A High Temperature Transpiration Apparatures for Study of the Atmosphere above Viscous Incongruently Vaporizing Melts, NBS Special Publication 561/1: Characterization of High Temperature Vapors and Gases, Washington, 1979, pp. 111-124.
80. Konsaka, S., Sato, S., and Yokokawa, T., E.m.f. Measurements of Molten Oxide Mixtures. III. Sodium Oxide + Silicon Dioxide, J. Chem. Thermodyn., 1979, vol. 11, no. 6, pp. 547-551.
81. Neudorf, D.A. and Elliot, J.F., Thermodynamic Properties of Sodium Oxide-Silica-Calcium Oxide Melts at 1000-1100°C, Metall. Trans. B, 1980, vol. 11, no. 4, pp. 607-614.
82. 2 Melts by Chemical Equilibrium Method, Tetsu to Hagane, J. Iron Steel Inst. Jpn., 1985, vol. 71, no. 7, pp. 815-822.
83. Ushakov, V.M., Borisova, N.V., Starodubtsev, A.M., and Shultz, M.M., Heat Capacities and Enthalpies of Formation of Sodium Silicate Glasses, Tezisy dokl. konf. "Problemy kalorimetrii i khimicheskoi termodinamiki" (Abstracts of Papers, Conf. "Problems in Calorimetry and Chemical Thermodynamics"), Chernogolovka, 1984, vol. 2, pp. 411-413.
84. 2 Solutions, J. Am. Ceram. Soc., 1967, vol. 50, no. 12, pp. 631-640.
85. 3 at 1600°C, Trans. Metall. Soc. Am. Inst. Mining Energies, 1965, vol. 233, no. 3, pp. 415-425.
86. Elliott, J.F., Gleiser, M., and Ramakrishna, V., Thermochemistry for Steelmaking, Massachusetts, 1963, vol. 2.
87. Mehta, S.R. and Richardson, F.D., Activities of Manganese Oxide and Mixing Relationships in Silicate and Aluminate Melts, J. Iron Steel Inst. London, 1965, vol. 203, no. 5, pp. 524-528.
88. 2 System, Metall. Trans. ASM-AIME, 1970, vol. 1, no. 4, pp. 871-876.
89. Matsushita, Y. and Goto, K., On the Rate of Fluidized-Bed Reduction of Iron Ore, J. Iron Steel Inst. Jpn., 1964, vol.4, no. 2, pp. 128-138.
90. Esin, O.A., Sryvalin, I.T., and Khlynov, V.V., Thermodynamic Analysis of Sodium-Lead Silicate Melts, Zh. Neorg. Khim., 1957, vol. 2, no. 10, pp. 2429-2442.
91. 2 System, Metall. Trans. B, 1981, vol. 12, pp. 311-317.
92. Schulmann, R. and Ensio, P.J., Thermodynamics of Iron-Silicate Slags: Slags Saturated with Gamma Iron, J. Met., 1951, vol. 3, no. 5, pp. 401-411.
93. 2 Silicate Systems, Metallurgiya (NRB), 1984, vol. 39, no. A-10, pp. 9-12.
94. 3 System, J. Jpn. Inst. Met., 1961, vol. 25, no. 2, pp. 139-143.
95. Sharma, R.A. and Richardson, F.D., The Solubility of Calcium Sulphide and Activities in Lime-Silica Melts, J. Iron Steel Inst. Jpn., 1962, vol. 200, no. 5, pp. 373-379.
96. 2 System, Izv. Vyssh. Uchebn. Zaved., Chern. Metall., 1985, no. 11, pp. 1-4.
97. Rocket, T.Y. and Foster, W.R., Phase Relations in the System Boron Oxide-Silica, J. Am. Ceram. Soc., 1965, vol. 48, no. 1, pp. 75-80.
98. Navrotsky, A., Hervig, R.L., Roy, B.N., and Huffman, M., Thermochemical Studies of Silicates, Aluminosilicate and Borosilicate Glasses, High Temp. Sci., 1985, vol. 19, no. 2, pp. 139-150.
99. Hervig, R.L. and Navrotsky, A., Thermochemistry of Sodium Borosilicate Glasses, J. Am. Ceram. Soc., 1985, vol. 68, no. 6, pp. 314-319.
100. 2 System, Fiz. Khim. Stekla, 1980, vol. 6, no. 1, pp. 51-60.
101. Kohsaka, S., Sato, S., and Yokokawa, T., E.m.f., Measurements on Molten Mixtures of Sodium Oxide + Germanium Dioxide, J. Chem. Thermodyn., 1978, vol. 10, no. 2, pp. 117-127.
102. 2 System, Thermochim. Acta, 1993, vol. 224, no. 1, pp. 19-32.
103. Baret, G., Etude thermodynamique et experimentale de melanges d'oxydes á basse temperature de fluage pour l'electronique, Thèse, Laboratoroire de Thermodynamique et Physico-Chimie Metallurgiques (ENSEEG), Grenoble, 1984.
104. 1 System in the Temperature Range 700-1000°C, Fiz. Khim. Stekla, 1978, vol. 4, no. 3, pp. 271-277.
105. Richardson, F.D., Physical Chemistry of Melts in Metallurgy, London: Academic, 1974, vol. 1.
106. Dai, C., Zhang, X., and Shui, L., A New Method for Measuring Activities in Slags Containing Volatile Component, Metall. Trans. B, 1995, vol. 26, no. 3, pp. 651-653.
107. 2O (M = Li, Na, K), Trans. Jpn. Inst. Met., 1976, vol. 17, no. 12, pp. 818-827.
108. 3, Can. Metall. Quart., 1968, vol. 7, no. 4, pp. 191-198.
109. 3, Sci. Rep. Tohoku Univ., Ser. A, 1959, vol. 11, no. 3, pp. 244-263.
110. Sakagami, R., Electochemical Study on Molten Slags, J. Iron Steel Inst. Jpn., 1953, vol. 39, pp. 587-595, 688-697, 1240-1250.
111. Yang, L., McCabe, C.L., and Miller, R., A Summary of Some Experimental Work on the Activity of Silica in Liquid Silicate Systems, in The Physical Chemistry of Steelmaking, New York, 1958, pp. 63-64.
112. 3 Slags, Sci. Sin. (Engl. Ed.), 1963, vol. 12, no. 8, pp. 1249-1250.
113. Kay, D.A.R. and Taylor, J., Activity of Silica in Lime-Alumina-Silica System, Trans. Faraday Soc., 1960, vol. 56, part 9, pp. 1372-1386.
114. 2 Slags, Sci. Sin. (Engl. Ed.), 1962, vol. 11, no. 9, pp. 1287-1302.
115. Stolyarova, V.L., Application of the Belton-Fruehan Mass Spectrometric Method to Study Thermodynamic Properties of Oxide Melts, Proc. V. Int. Conf. on Molten Slags, Fluxes and Salts'97, Sydney, 1997, pp. 761-768.
116. Bauer, E. and Brunner, R., Uber das Verhalten von Sauerstoffelectroden in Carbonatschmelzen, Z. Electrochem., 1935, vol. 41, no. 11, pp. 794-796.
117. Ostvold, T. and Kleppa, O.J., Thermochemistry of Liquid Borates: Partial Enthalpies of Solution of Boric Oxide in Its Liquid Mixtures with Lithium, Sodium and Potassium Oxides, Inorg. Chem., 1970, vol. 9, no. 6, pp. 1395-1400.
118. Rudnyi, E.B., Determination of Reaction Enthalpies from Equilibrium Constants: Second or Third Law?, Primenenie matematicheskikh metodov dlya opisaniya i izucheniya fiziko-khimicheskikh ravnovesii. Rasshirennye tezisy dokl. V Vses. shkoly (Extended Abstracts of Papers, V All-Union School on the Application of Mathematical Methods to Description and Study of Physicochemical Equilibria), Novosibirsk, 1985, part 1, pp. 105-109.
119. Shultz, M.M., Borisova, N.V., and Kozhina, E.L., Thermodynamics of High-Melting Oxide Systems from the Viewpoint of Criteria for Stability of Equilibrium, in Khimiya silikatov i oksidov (Chemistry of Silicates and Oxides), Leningrad: Nauka, 1982, pp. 3-19.
120. Storonkin, A.V. and Shultz, M.M., Some Problems in Thermodynamics of Multicomponent Heterogeneous Systems: II. Necessary Conditions for the Stability of Heterogeneous Systems, Zh. Fiz. Khim., 1960, vol. 34, no. 9, pp. 1928-1932.
121. Stolyarova, V.L., Vaporization Features of Oxide Systems Studied by High-Temperature Mass Spectrometry, J. Nucl. Mater., 1997, vol. 247, nos. 2-3, pp. 7-10.
122. Shultz, M.M., The Acid-Base Concept as Applied to Oxide Melts and Glasses and the D.I. Mendeleev Theory of the Vitreous State, Fiz. Khim. Stekla, 1984, vol. 10, no. 2, pp. 129-138.