Synthesis of bromohydrosilanes: Reactions of hydrosilanes with CuBr2 in the presence of CuI

Chemistry Letters

Volumn , Issue 12, 2001, Pages 1228-1229

  Kunai, Atsutaka ^a   Ochi, Takahiko ^a   Iwata, Arihiro ^a   Ohshita, Joji ^a  

^a HIROSHIMA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0035528506     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2001.1228     Document Type: Article

References (24)

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22. 9BrSi: C, 48.40; H, 4.51%. Found: C, 48.52; H, 4.60%.
23. Nevertheless, diethyl ether can be used as the solvent for bromination, unless the reaction requires longer reaction time. The reaction in ether is faster than in benzene, and subsequent work up is easy due to the low boiling point.
24. Dibromination of hexylsilane (run 7) may complete also faster under reflux conditions.