Unique reactivity of a diphenyldisilane unit incorporated into the bicyclic ring system: Generation of a disilanyllithium via silicon-phenyl bond cleavage with lithium

Chemistry of Heterocyclic Compounds

Volumn 37, Issue 11, 2001, Pages 1369-1374

  Tsuji, H ^a   Toshimitsu, A ^a   Tamao, K ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

Bicyclic disilane; Calas type reaction; Disilanyllithium; Methylene tethers; Silicon carbon bond cleavage; Silyllithium

Indexed keywords

BICYCLO COMPOUND; CARBON; DIPHENYLDISILANE; DISILANYLLITHIUM; LITHIUM DERIVATIVE; PHENYL GROUP; SILANE DERIVATIVE; SILICON; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; COVALENT BOND; DISSOCIATION; ELECTRON TRANSPORT; KINETICS; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0035523458     PISSN: 00093122     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1017947100644     Document Type: Article

References (10)