Dependence on ionic strength of polyamine protonation in NaCl aqueous solution

Journal of Chemical and Engineering Data

Volumn 46, Issue 6, 2001, Pages 1425-1435

  de Robertis, A ^a   Foti, C ^a   Giuffre O ^a   Sammartano, S ^a  

^a UNIVERSITY OF MESSINA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

DEBYE-HUCKEL TYPE EQUATION; PITZER EQUATIONS; POLYAMINE PROTONATION; POTENTIOMETRIC MEASUREMENTS; SODIUM CHLORATE;

IONIC STRENGTH; MATHEMATICAL MODELS; NUMERICAL ANALYSIS; SODIUM CHLORIDE; SOLUTIONS; SUBSTITUTION REACTIONS;

AMINES;

EID: 0035506389     PISSN: 00219568     EISSN: None     Source Type: Journal    
DOI: 10.1021/je010143g     Document Type: Article

References (53)

1. Russell, D. H. Clinical Relevance of Polyamines. Crit. Rev. Lab. Sci. 1982, 18, 261-311.
2. Wolfe, S. L. Biologia Molecolare e Cellulare; Edises: 1994.
3. Tabor, H. The Protective Effect of Spermine and Other Polyamines Against Heat Denaturation of Deoxyribonucleic Acid. Biochemistry 1962, 1, 496-501.
4. Maga, J. A. Amines in Foods. CRC Crit. Rev. Food Sci. Nutr. 1978, 4, 373-403.
5. Sillén, L. G.; Martell, A. E. Stability Constants of Metal Ion Complexes; Special Publication 17; The Chemical Society: London, U.K., 1964.
6. Sillén, L. G.; Martell, A. E. Stability Constants of Metal Ion Complexes; Suppl. 1, Special Publication 25; The Chemical Society: London, U.K., 1975.
7. Smith, R. M.; Martell, A. E. Critical Stability Constants; Plenum: New York, 1974-1989; Vol. 1-6.
8. Martell, A. E.; Smith, R. M.; Motekaitis R. J. NIST Critically Selected Stability Constants of Metal Complexes; database version 4; NIST: Gaithersburg, MD, 1997.
9. Pettit, L. D.; Powell, K. IUPAC Stability Constants Database; Academic Software: Otley, U.K., 1997.
10. Murray, K.; May, P. M. Joint Expert Speciation System; Jess Primer, Murdoch: Western Australia, 2000.
11. Järvinen, R. A Thermodynamic Study of the Ionization of N,N,N′,N′-tetraethylenediamine in Aqueous Solution. Suomen Kem. 1969, B42, 409-412.
12. Näsänen, R.; Tilus, P.; Eskolin, E. Protonation Constant Values for N-isopropyl-2-methyl-1,2-propanediamine in Aqueous Solution. Suomen Kem. 1972, B45, 87-89.
13. Koskinen, M.; Kollin, K. The Effect of Ionic Strength on the Protonation of N,N′-dimethyl-1,3-propanediamine and N,N-dibutyl- 1,3-propanediamine in Sodium Perchlorate Solutions. Suomen Kem. 1972, B45, 114-116.
14. Näsänen, R.; Tilus, P.; Teikari, T. Protonation Constant Values for N,N,N′,N′-tetramethyl-1,3-propanediamine in Aqueous Solution. Finn. Chem. Lett. 1974, 263-265.
15. Näsänen, R. Ionisation of 1,2-diaminopropane in Aqueous Salt Solutions. Suomen Kem. 1961, B34, 4-7.
16. Näsänen, R.; Koskinen, M.; Alatalo, M.; Adler, L.; Koskela, S.; Stability Constant Values for the Protonation and Copper(II) Complex Formation of N,N-diethyl-N′-methylethylenediamine and N,N,N′,N′- tetramethylethylenediamine in Aqueous Solution. Suomen Kem., 1967, B40, 124-127.
17. Näsänen, R.; Tilus, P.; Huttunen, E.; Turunen, E. R. Stability Constant Values for the Protonation and Copper(II) and Nickel-(II) Complex Formation of N-ethylethylenediamine in Aqueous Solution. Suomen Kem. 1969, B42, 390-393.
18. Näsänen, R.; Koskinen, M.; Tilus, P.; Ilomä ki, A. Stability Constant Values for the Protonation and Copper(II) and Nickel-(II) Complex Formation of N-methylethylenediamine in Aqueous Solution. Suomen Kem. 1970, B43, 34-38.
19. Näsänen, R.; Koskinen, M.; Anttila, L.; Korvola, M. L. Formation Constant Values for the Association of N,N′-dimethyl- ethylenediamine with Hydrogen, Copper and Nickel ions in Aqueous Solution. Suomen Kem. 1966, B39, 122-127.
20. Näsänen, R.; Koskinen, M.; Salonen, R.; Kiiski, A. Tendency of 1,3-diaminopropane and 1,3-diaminobutane to Form Copper Complexes in Aqueous Solution. Suomen Kem. 1965, B38, 81-86.
21. Näsänen, R.; Meriläinen, P.; Koskinen, M.; Ionisation of N,Ndiethylethylenediamine and the Stabilities of its Copper Complexes in Aqueous Solution. Suomen Kem. 1963, B36, 9-13.
22. Näsänen, R.; Meriläinen, P.; A Potentiometric Study of the Ionisation of N,N′-diethylethylenediamine and its Copper Complexes in Aqueous Solution. Suomen Kem. 1963, B36, 205-208.
23. Orama, M.; Ahtola, R.; Kunkka, P. Stability of Nickel(II) Complexes of N,N,N′,N′-tetra(2-hydroxyethyl)ethylenediamine and N,N-di(2-hydroxyethyl)-1,3-propanediamine in Aqueous Solution. Finn. Chem. Lett. 1976, 161-164.
24. Näsänen, R.; Lindell, E.; Tilus, P. Stability Constant Values for the Protonation and Copper(II) Complex Formation of N,N-di(2-hydroxyethyl)1, 3-propanediamine in Aqueous Solution. Anal. Chem. 1977, 49, 95-101.
25. Näsänen, R.; Tilus, P.; Järvinen, H.; Komsi, I. Stability Constant Values for the Protonation and Copper(II) Complex Formation of 2-hydroxy-1,3-propanediamine in Aqueous Solution. Suomen Kem. 1970, B43, 154-157.
26. Näsänen, R.; Meriläinen, P.; Lukkari, S. Ionisation of 1,3-diamino- N-(β-hydroxyethyl)-propane and its Copper Complexes in Aqueous Solution. Suomen Kem. 1963, B36, 135-138.
27. Näsänen, R.; Tilus, P.; Rinne, A. Ionisation of N-(2-hydroxyethyl)-ethylenediamine and its Tendency to Form Copper(II) and Nickel-(II) Complexes in Aqueous Solution. Suomen Kem. 1965, B39, 45-49.
28. Näsänen, R.; Koskinen, M.; Tilus, P.; Lindell, E.; Lihavainen, J.; Pinomä ki, M. Ionisation of Some Aminoalkanols in Aqueous Sodium Perchlorate Solutions. Suomen Kem. 1973, B46, 61-63.
29. Näsänen, R.; Koskinen, M.; Tilus, P.; Klemala, O.; Leinonen, E.; Wuolijoki, E. Ionisation of Some Aminalkanols in Aqueous Sodium Perchlorate Solutions. Part II. Suomen Kem. 1973, B46, 181-183.
30. Delfini, M.; Segre, A. L.; Conti, F.; Barbucci, R.; Barone, V.; Ferruti, P. On the Mechanism of Protonation of Triamines. J. Chem. Soc., Perkin Trans. 2 1980, 900-903.
31. 13C-NMR Investigation. Gazz. Chim. Ital. 1984, 114, 249-251.
32. Clay, R. M.; Corr, S.; Micheloni, M.; Paoletti, P. Noncyclic Reference Ligands for Tetraazamacrocycles. Synthesis and Thermodynamic Properties of a Series of α,ω-Di-N-methylated Tetraaza Ligands and their Copper(II) Complexes. Inorg. Chem. 1985, 24, 3330-3336.
33. Casale, A.; De Robertis, A.; Licastro, F.; Rigano, C. Salt Effects on the Protonation of Ethylenediamine: a Complex-Formation Model. J. Chem. Res. 1990, (S) 204, (M) 1601-1620.
34. De Robertis, A.; De Stefano, C.; Patanè, G. Salt Effect on the Protonation of Diethylenetriamine. A Complex Formation Model. Thermochim. Acta 1992, 209, 7-24.
35. De Robertis, A.; De Stefano, C.; Patanè, G.; Sammartano, S. Effects of Salt on the Protonation in Aqueous Solution of Triethylenetetramine and Tetraethylenepentamine. J. Solution Chem. 1993, 22, 927-940.
36. De Robertis, A.; De Stefano, C.; Giuffrè, O.; Sammartano, S. Binding of Carboxylic Ligands by Protonated Amines. J. Chem. Soc., Faraday Trans. 1996, 92 (21), 4219-4226.
37. Daniele, P. G.; Prenesti, E.; De Robertis, A.; De Stefano, C.; Foti, C.; Giuffrè, O.; Sammartano, S. Binding of Inorganic and Organic Polyanions by Protonated Open Chain Polyamines in Aqueous Solution. Ann. Chim. (Rome) 1997, 87, 415-447; errata corrige 1998, 88, 447-448.
38. (5n-2) in NaCl Aqueous Solution at Different Ionic Strengths. Ann. Chim. (Rome) 1998, 88, 55-70.
39. 2 (n = 2-10) in NaCl Aqueous Solution at Different Ionic Strengths. J. Chem. Eng. Data 1999, 44, 735-738.
40. Cascio, S.; De Robertis, A.; Foti, C. Protonation of Polyamines in NaCl Aqueous Solution and Binding of Cl- by Polyammonium Cations. Fluid Phase Equilib. 2000, 170, 167-181.
41. Cascio, S.; De Robertis, A.; De Stefano, C.; Foti, C.; Gianguzza, A.; Sammartano, S. Stability-Charge and Stability-Structure Relationships in the Binding of Dicarboxylic Ligands by Open- Chain Polyammonium Cations. J. Chem. Eng. Data 2000, 45, 717-723.
42. De Stefano, C.; Sammartano, S.; Mineo, P.; Rigano, C. Computer Tools for the Speciation of Natural Fluids. In Marine Chemistrys An Environmental Analytical Chemistry Approach; Gianguzza, A., Pellizzetti, E., Sammartano, S., Eds.; Kluwer Academic Publishers: Amsterdam, The Netherlands, 1997; pp 71-83.
43. Daniele, P. G.; De Stefano, C.; Foti, C.; Sammartano, S. The Effect of Ionic Strength and Ionic Medium on the Thermodynamic Parameters of Protonation and Complex Formation. Curr. Top. Solution Chem. 1997, 2, 253-274.
44. Pitzer, K. S. Thermodynamics of electrolytes. I. Theoretical basis and general equations. J. Phys. Chem. 1973, 77, 268-277.
45. Pitzer, K. S. Activity Coefficients in Electrolyte Solutions, 2nd ed.; CRC Press: Boca Raton, FL, 1991.
46. Millero, F. J.; Hawke, D. J. Ion Interactions of Divalent Metals in Natural Waters. Mar. Chem. 1992, 40, 19 and references cited therein.
47. Millero, F. J.; Roy, R. N. A Chemical Equilibrium Model for the Carbonate System, in Natural Waters. Croatia Chem. Acta 1997, 70, 1-38. and references cited therein.
48. 4, KCl and KBr at 298 K. Dependence on Ionic Strength. J. Chem. Eng. Data 1998, 43, 876-879 and references cited therein.
49. Barriada, J. L.; Brandariz, I.; Sastre de Vicente, M. E. Acid-base Equilibria of Monocarboxylic Acids in Various Saline Media: Analysis of Data Using Pitzer Equations. J. Chem. Eng. Data 2000, 45, 1173-1178 and references cited therein.
50. De Robertis, A.; De Stefano, C.; Foti, C. Medium Effects on the Protonation of Carboxylic Acids at Different Temperatures. J. Chem. Eng. Data 1999, 44, 262-270 and references cited therein.
51. Foti, C.; Gianguzza, A.; Piazzese, D.; Trifiletti, G. Inorganic Speciation of Organotin(IV) Cations in Natural Waters with Particular References to Seawater. Chem. Spec. Bioavail. 2000, 12, 41-52 and references cited therein.
52. De Stefano, C.; Foti, C.; Gianguzza, A.; Sammartano, S. The Interaction of Amino Acids with the Major Constituents of Natural Waters at Different Ionic Strengths. Mar. Chem. 2000, 72, 61-76 and references cited therein.
53. Bencini, A.; Bianchi, A.; Garcia-España, E.; Micheloni, M.; Ramirez, J. A. Proton Coordination by Polyamine Compounds in Aqueous Solution. Coord. Chem. Rev. 1999, 188, 97-156.