Impact of 2-D bubble dynamics on the selectivity of fast gas-liquid reactions

AIChE Journal

Volumn 47, Issue 10, 2001, Pages 2304-2319

  Khinast, Johannes G ^a  

^a RUTGERS UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BUBBLES (IN FLUIDS); COMPUTER SIMULATION; MASS TRANSFER; OPTIMIZATION; REYNOLDS NUMBER; WAKES;

GAS-LIQUID INTERFACES;

FLUID DYNAMICS;

REACTION;

ANALYSIS; ARTICLE; CHEMICAL REACTION; DYNAMICS; EXPERIMENTAL MODEL; FLOW; GAS; LIQUID; MASS; MATHEMATICAL ANALYSIS; PARAMETER; PROCESS DESIGN; PROCESS OPTIMIZATION; QUALITATIVE ANALYSIS; RESEARCH; SCALE UP; SIMULATION; SYNTHESIS; TIME; VORTEX MOTION;

EID: 0035483803     PISSN: 00011541     EISSN: None     Source Type: Journal    
DOI: 10.1002/aic.690471015     Document Type: Article

References (77)

1. Arters, D. C., and L. S. Fan, "Experimental Methods and Correlation of Solid-Liquid Mass Transfer in Fluidized Beds," Chem. Eng. Sci., 45, 965 (1990).
2. Baird, H. I., and J. F. Davidson, "Gas Absorption by Rising Large Bubbles," Chem. Eng. Sci., 17, 5109 (1962).
3. Baldyga, J., and J. R. Bourne, Turbulent Mixing and Chemical Reactions, Wiley, New York (1999).
4. Beenackers, A. A. C. M., and W. P. H. van Swaaij, "Chemical Reactor Design and Technology," Washington Nato Advanced Study Institute Series, H. I. DeLasa, ed., Martinus Nijhoff, p. 463 (1986).
5. Bhaga, D., and M. E. Weber, "Bubbles in Viscous Liquids: Wakes, Shapes and Velocities," J. Fluid Mech., 105, 61 (1981).
6. Bourne, J. R., E. Crivelli, and P. Rys, "Mixing-Disguised Azo Coupling Reactions," Helv. Chim. Acta, 60, 2944 (1977).
7. Braza, M., P. Chassaing, and H. Ha Minh, "Numerical Study and Physical Analysis of the Pressure and Velocity Field in the Near Wake of a Circular Cylinder," J. Fluid Mech., 165, 79 (1986).
8. Brenan, K. E., S. L. Campbell, and L. R. Petzold, Numerical Solution of Initial-Value Problems in Differential-Algebraic Equations, Society for Industrial and Applied Mathematics, Philadelphia (1995).
9. Brignell, A. S., "Mass Transfer from Spherical Cap Bubbles in Laminar Flow," Chem. Eng. Sci., 29, 135 (1974).
10. Calderbank, P. H., D. S. L. Johnson, and J. London, "Mechanics and Mass Transfer of Single Bubbles in Free Rise Through Some Newtonian and Non-Newtonian Liquids," Chem. Eng. Sci., 25, 235 (1970).
11. Carra, S., and M. Morbidelli, "Transient Mass Transfer onto Small Particles and Drops," Handbook of Heat and Mass Transfer, Vol. 2, P. Cheremisinoff, ed., Gulf Publishing, Houston (1986).
12. Chowdhry, S., and A. A. Linninger, "Computer Aided Formulation and Analysis of Dynamic Systems," AIChE Meeting, Dallas, TX (1999).
13. Clift, R., J. R. Grace, and M. E. Weber, Bubbles, Drops and Particles, Academic Press, New York (1978).
14. Coppus, J. H. C., and K. Rietema, "Theoretical Deviation of the Mass Transfer Coefficient at the Front of a Spherical Cap Bubble," Chem. Eng. Sci., 35, 1497 (1980).
15. Coppus, J. H. C., and K. Rietema, "Mass Transfer from Spherical Cap Bubbles, the Contribution of the Bubble Rear," Trans. Inst. Chem. Engrs., 59, 54 (1981).
16. Danckwerts, P. V., "The Effect of Incomplete Mixing on Homogeneous Reactions," Chem. Eng. Sci., 8, 93 (1958).
17. David, R., and J. Villermaux, "Interpretation of Micromixing Effects on Fast Consecutive Competing Reactions in Semi-Batch Stirred Tanks by a Simple Interaction Model," Chem. Eng. Commun., 54, 333 (1987).
18. Deuflhard, P., E. Hairer, and J. Zugck, "One-Step and Extrapolation Methods for Differential-Algebraic Systems," Numer. Math., 51, 1 (1987).
19. Doraiswamy, L. K., and M. M. Sharma, Heterogeneous Reactions, Vol. 2, Fluid-Fluid-Solid Reactions, Wiley, New York (1984).
20. Ehrig, R., U. Nowak, L. Oeverdieck, and P. Deuflhard, "Advanced Extrapolation Methods for Large-Scale Differential Algebraic Problems," High-Performance Scientific and Engineering Computing, H.-J. Bungartz, F. Durst, and C. Zenger, eds., Vol. 8, Springer, New York, p. 233 (1999).
21. Epstein, I. R., "The Consequences of Imperfect Mixing on Autocatalytic Chemical and Biological Systems," Nature, 374, 231 (1995).
22. Fan, L. S., Gas-Liquid-Solid Fluidization Engineering, Butterworth-Heinemann, Boston (1989).
23. Fan, L.-S., and K. Tsuchiya, Bubble Wake Dynamics in Liquids and Liquid-Solid Suspensions, Butterworth-Heinemann, Boston (1990).
24. Fletcher, C. A. J., Computational Techniques for Fluid Dynamics, Springer, New York (1997).
25. Fox, R. O., "On the Relationship Between Lagrangian Micromixing Models and Computational Fluid Dynamics," Chem. Eng. Process, 37, 521 (1998).
26. Froncioni, A. M., F. J. Muzzio, R. L. Peskin, and P. D. Swanson, "Chaotic Motion of Fluid and Solid Particles in Plane Wakes," Chaos Solitons Fractals, 8(1), 109 (1997).
27. Gianetto, A., and O. L. Silveston, Multiphase Chemical Reactors, Hemisphere, Washington, DC (1986).
28. Grace, J. R., T. Wairegi, and T. H. Nguyen, "Shapes and Sizes of Bubbles Rising in Infinite Liquids," Trans. Inst. Chem. Eng., 54, 167 (1976).
29. Haberman, W. L., and R. K. Morton, David K. Taylor Model Basin Report 802, Navy Dept., Washington, DC (1953).
30. Hills, J. H., "The Two-Dimensional Elliptical Cap Bubble," J. Fluid Mech., 68, 503 (1975).
31. Hyndman, C., F. Larachi, and C. Guy, "Understanding Gas-Phase Hydrodynamics in Bubble Columns: A Convective Model Based on Kinetic Theory," Chem. Eng. Sci., 52, 63 (1997).
32. Jean, R. H., and L.-S. Fan, "Rise Velocity and Gas-Liquid Mass Transfer of a Single Large Bubble in Liquids and Liquid-Solid Fluidized Beds," Chem. Eng. Sci., 45, 1057 (1990).
33. Jordan, S. K., and J. E. Fromm, "Oscillatory Drag, Lift and Torque on a Circular Cylinder in a Uniform Flow," Phys. Fluids, 8, 371 (1972).
34. Kleinman, L. S., and X. B. Reed Jr., "Interphase Mass Transfer from Bubbles, Drops, and Solid Spheres: Diffusional Transport Enhanced by External Chemical Reaction," Ind. Eng. Chem. Res., 35, 3621 (1995).
35. Khinast, J., D. Luss, T. M. Leib, and M. P. Harold, "Impact of an Undesired Reaction on a Boiling Slurry Reactor," Chem. Eng. Sci., 54, 2295 (1999a).
36. Khinast, J., D. Luss, T. M. Leib, and M. P. Harold, "The Adiabatic Boiling Slurry Reactor: Influence of Axial Dispersion," Chem. Eng. Sci., 54, 5021 (1999b).
37. Kondepudi, D. K., K. L. Bullock, J. A. Digits, and P. D. Yarborough, "Stirring Rate as a Critical Parameter in Chiral Symmetry Breaking Crystallization," J. Am. Chem. Soc., 117, 401 (1995).
38. Kramers, H., "Physical Factors in Chemical Reaction Engineering," Chem. Eng. Sci., 8, 45 (1958).
39. Krishna, R., and J. Ellenberger, "A Unified Approach to the Scale-Up of 'Fluidized' Multiphase Reactors," Trans. Inst. Chem. Eng., 73(A), 217 (1995).
40. Krishna, R., M. I. Urseanu, J. M. Van Baten, and J. Ellenberg, "Influence of Scale on the Hydrodynamics of Bubble Columns Operating in the Churn-Turbulent Regime: Experiments vs. Eulerian Simulations," Chem. Eng. Sci., 54, 4903 (1999).
41. Leal, L. G., "Vorticity Transport and Wake Structure for Bluff Bodies at Finite Reynolds Numbers," Phys. Fluids A, 1, 124 (1989).
42. Lin, T.-J., J. Reese, T. Hong, and L. S. Fan, "Quantitative Analysis and Computation of Two-Dimensional Bubble Columns," AIChE J., 42, 301 (1996).
43. Lindt, J. T., "Note on the Wake Behind a Two-Dimensional Bubble," Chem. Eng. Sci., 26, 1776 (1971).
44. Lindt, J. T., "On the Periodic Nature of the Drag on a Rising Bubble," Chem. Eng. Sci., 27, 1775 (1972).
45. Long, W. M., and L. V. Kalachev, "On Dissolution of a Spherical Gas Bubble in the Presence of Fast Reaction," Chem. Eng. Sci., 55, 2295 (2000).
46. Masliyah, J. H., and N. Epstein, "Numerical Solution of Heat and Mass Transfer from Spheroids in Steady and Axisymmetric Flow," Proc. Int. Symp. on Two-Phase Systems, Pergamon Press, New York (1972).
47. Mills, P. L., and R. V. Chaudhari, "Reaction Engineering of Emerging Oxidation Processes," Catal. Today, 48, 17 (1999).
48. Miyahara, T., K. Tsuchiya, and L.-S. Fan, "Wake Properties of a Single Gas Bubble in a Three-Dimensional Liquid-Solid Fluidized Bed," Int. J. Multiphase Flow, 14, 749 (1988).
49. Moore, D. W., PhD Thesis, Univ. of Cambridge, Cambridge, UK (1958).
50. Mudde, R., D. Lee, and L. S. Fan, "Role of Coherent Structures on Reynolds Stresses in a 2-D Bubble Column," AIChE J., 43, 913 (1997a).
51. Mudde, R. F., J. Groen, and H. Van Den Akker, "Liquid Velocity Field in a Bubble Column: LDA Experiments," Chem. Eng. Sci., 52, 4217 (1997b).
52. Nienow, A. W., S. M. Drain, A. P. Boyes, R. Mann, A. M. El-Hamouz, and H. J. Carpenter, "A New Pair of Reactions to Characterize Imperfect Macromixing and Partial Segregation in a Stirred Semi-Batch Reactor," Chem. Eng. Sci., 47, 2825 (1992).
53. Noh, W. F., and P. Woordward, "SLIC (Simplified Line Interface Calculation," in Lecture Notes in Physics, A. I. van Dooren and P. J. Zandbergen, eds., Vol. 59, Springer, New York, p. 330 (1976).
54. Nyugen-Tien, K., A. N. Patwari, A. Schumpe, and W.-D. Decker, "Chemical Selectivities Disguised by Mass Diffusion," AIChE J., 31, 194 (1985).
55. Panton, R. L., Incompressible Flow, Wiley, New York (1996).
56. Paul, E. L., and R. E. Treybal, "Mixing and Product Distribution for a Liquid Phase, Second Order, Competitive-Consecutive Reaction," AIChE J., 17, 718 (1971).
57. Ponoth, S. S., and J. B. McLaughlin, "Numerical Simulation of Mass Transfer for Bubbles in Water," Chem. Eng. Sci., 55, 1237 (2000).
58. Pruppacher, H. R., B. P. LeClaire, and A. E. Hamielec, "Some Relations between Drag and Flow Pattern of Viscous Flow Past a Sphere and a Cylinder at Low and Intermediate Reynolds Number," J. Fluid Mech., 44, 781 (1970).
59. Ramachandran, P. A., and R. V. Chaudhari, Three Phase Catalytic Reactors, Gordon & Breach, New York (1983).
60. Reese, J., and L.-S. Fan, Chem. Eng. Sci., 52, 1553 (1997).
61. Rigby, G. R., and C. E. Capes, "Bed Expansion and Bubble Wakes in Three-Phase Fluidization," Can. J. Chem. Eng., 48, 19 (1984).
62. Ryskin, G. R., and L. G. Leal, "Numerical Solution of Free-Boundary Problems in Fluid-Mechanics, Part 1. The Finite Difference Technique," J. Fluid Mech., 148, 1 (1984a).
63. Ryskin, G. R., and L. G. Leal, "Numerical Solution of Free-Boundary Problems in Fluid-Mechanics, Part 2. Buoyancy Driven Motion of a Gas Bubble Through a Quiescent Liquid," J. Fluid Mech., 148, 19 (1984b),
64. Saffman, P. G., "Viscous Fingering in Hele-Shaw Cells," J. Fluid Mech., 173, 73 (1986).
65. Shah, Y. T., Gas-Liquid-Solid Reactor Design, McGraw-Hill, New York (1979).
66. Song, G.-H., and L.-S. Fan, "Gas-Liquid Mass Transfer of a Single Large Bubble in Liquids and Liquid-Solid Fluidized Beds, "AIChE J., 36, 439 (1990).
67. Sun, Y., R. N. Landau, J. Wang, C. LeBlond, and D. G. Blackmond, "Asymmetric Hydrogenation of Ethyl Pyruvate: Diffusion Effects on Enantioselectivity," J. Amer. Chem. Soc., 118, 1348 (1996).
68. Sun, Y., J. Wang, C. LeBlond, R. A. Reamer, J. Laquidara, J. R. Sowa, Jr., and D. Blackmond,"Kinetic Influences on Enantio-selectivity in Asymmetric Catalytic Hydrogenation," J. of Organmetall. Chem., 548, 65 (1997).
69. Sundaresan, S., "Modeling the Hydrodynamics of Multiphase Flow Reactors: Current Status and Challenges," AIChE. J., 46, 1102 (2000).
70. Tannehill, J. C., D. A. Anderson, and R. H. Pletcher, Computational Fluidmechanics and Heat Transfer, Taylor and Francis, Washington, (1997).
71. Tritton, D. J., "A Note on Vortex Streets Behind Circular Cylinders at Low Reynolds Numbers," J. Fluid Mech., 45, 203 (1971).
72. van Krevelen, D. W., "Micro- and Macro-Kinetics," Chem. Eng. Sci., 8, 5 (1958).
73. Villermaux, J., L. Falk, M. C. Fournier, and C. Detrez, "Use of Parallel-Competing Reactions to Characterize Micromixing Efficiency," AIChE Symp. Ser., Vol. 90, No. 299 (1992).
74. Villermaux, J., and L. Falk, "A Generalized Mixing Model for Initial Contacting of Reactive Fluids," Chem. Eng. Sci., 49, 5127 (1994).
75. Weber, M. E., "The Effect of Surface Active Agents on Mass Transfer from Spherical Cap Bubbles," Chem. Eng. Sci., 30, 1507 (1975).
76. Wu, T. Y., "Inviscid Cavity and Wake Flows," Basic Developments in Fluid Dynamics, M. Holt, ed. Academic Press, New York (1968).
77. Yabe, K., and D. Kunii, "Dispersion of Molecules Diffusing from a Gas Bubble into a Liquid," Inst. Chem. Eng., 18, 666 (1978).