Coupling model explanation of salient dynamic properties of glass-forming substances

IEEE Transactions on Dielectrics and Electrical Insulation

Volumn 8, Issue 3, 2001, Pages 329-344

  Ngai, K L ^a  

^a NAVAL RESEARCH LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

FORMABILITY; GLASS TRANSITION; MATHEMATICAL MODELS; MOLECULAR DYNAMICS; MOLECULAR STRUCTURE; RELAXATION PROCESSES;

GLASS-FORMERS; STRUCTURAL RELAXATION;

GLASS;

EID: 0035359810     PISSN: 10709878     EISSN: None     Source Type: Journal    
DOI: 10.1109/94.933340     Document Type: Article

References (108)

1. Dynamic and thermodynamic properties of glass-forming substances
2. Nachtrag uber die elastische Nachwirkung beim Cocon und glasfaden
3. Theorie des electrischen ruckstandes in der leidener flasche
4. Universality of low-frequency fluctuation, dissipation and relaxation properties of condensed matter
5. Frequency dependence of dielectric loss in condensed matter
6. Low-frequency relaxation in condensed matter and the evolution of entropy
7. Slowing down of relaxation in a complex system by constraint dynamics
8. Relaxation phenomena and stability of probability densities
9. Toward a theory of relaxation in correlated systems: Diffusion in the phase space of a chaotic Hamiltonian
10. The symmetric and fully distributed solution to a generalized dining philosophers problem: An analog of the coupling theory of relaxations in complex correlated systems
11. Fractal phase space transport dynamics and relaxations in complex correlated systems
12. Relaxation in interacting arrays of oscillators
13. Dynamics of relaxing systems subjected to nonlinear interactions
14. Similarity of Relaxation in supercooled liquids and interacting arrays of oscillators
15. Short time and long time relaxation dynamics of glass-forming substances: A coupling model perspective
16. Supercooled liquids, advances and novel applications
17. Dirac constraint dynamics and slowing down of relaxation: Theory
18. Dirac constraint dynamics and slowing down of relaxation: Applications
19. Comparisons between coupling model and molecular dynamics simulation for local chain dynamics
20. Identification of different modes of molecular motion in polymers that cause thermorheological complexity
21. Some examples of possible descriptions of dynamic properties of polymers by means of the coupling midel
22. A Review of critical experimental facts in electrical relaxation and ionic diffusion in ionically conducting glasses and melts
23. Correlation between the activation energies for ionic conductivity for short and long time scales and the Kohlrausch stretching parameter (for ionically conducting solids and melts
24. Polymer dynamics in solutions: Probe diffusion and viscosity
25. A coupling model analysis of dynamics of concentrated colloidal suspensions
26. β and consequences
27. Intercomparisons of dielectric relaxation, dynamic light scattering, and viscoelastic properties of the local segmental motion in amorphous polymers
28. Breakdown of Debye-Stokes-Einstein and Stokes-Einstein relations in glass-forming liquids: An explanation from the coupling model
29. A Modification of the Adam-Gibbs model of glass transition for consistency with experimental data
30. Synergy of entropy and intermolecular coupling in supercooling liquids
31. An alternative explanation of the difference between translational diffusion and rotational diffusion in supercooled liquids
32. Relation between some secondary relaxations and the relaxations in glass-forming materials according to the coupling model
33. Correlation between β relaxation and α relaxation in the family of poly (n-butyl methacrylate-stat-styrene) random copolymers
34. Relationship between the primary and the secondary dielectric relaxation processes in propylene glycol and its oligomers
35. Removal of cooperativity in glass-forming materials to reveal the primitive α relaxation of the coupling model
36. Decoupled molecular dynamics of glass-forming liquids confined in nano-meter pores
37. Reduction of the glass temperature of thin freely standing polymer films by the decrease of the coupling parameter in the coupling model
38. Effect of confinement on relaxation in glass-formers: Magnitude, trends and dependence on the Kohlrausch exponent
39. A constraint dynamics approach to rubber elasticity
40. Thermodynamic fragility and kinetic fragility in supercooled liquids: A missing link in molecular liquids
41. Viscoelastic properties of amorphous polymers. 1. Different temperature dependences of segmental relaxation and terminal dispersion
42. Viscoelastic properties of amorphous polymers, 2, anomalous temperature dependance of the steady-state recoverable compliance in low molecular weight polymers
43. Viscoelastic properties of polymers 4. Thermorheological complexity of the softening dispersion in polyisobutylene
44. Viscoelastic properties of amorphous polymers 5. A coupling model analysis of the thermorheological complexity of polyisobutylene in the glass-robber softening dispersion
45. Viscoelastic properties of amorphous polymers 7. Changes of the anomalous behavior of low molecular weight polystyrene with the addition of a diluent
46. Nature of nonexponential loss of correlation above the glass transition investigated by multidimensional NMR
47. On the temperature dependence of cooperative relaxation properties in glass-forming liquids
48. Nature of the non-exponential primary relaxation in structural glass-formers probed by dynamically selective experiments
49. From conformational transitions in a polymer chain to segmental relaxation in a bulk polymer
50. Comment on dynamics of glass-forming polymers: 'Homogeneous' versus 'Heterogeneous' scenario
51. Arbe et al. reply
52. Calorimetric study of glassy and liquid toluene and ethylbenzene
53. Translational and rotational molecular-motion in supercooled liquids studied by NMR and forced Rayleigh-scattering
54. Translational diffusion on Heterogeneous lattices: A model for dynamics in glass forming materials
55. Heterogeneity at the glass transition: Translational and rotational self-diffusion
56. 2 fast-ion conductors
57. Light-scattering study of a supercooled epoxy resin
58. Chiral studies in amorphous solids: The effect of the polymeric glassy state on the racemization kinetics of bridged paddled binaphthals
59. Excess wing in the dielectric loss of glass formers: A Johari-Goldstein β relaxation?
60. Contributions to the entropy of a glass, liquid and the dielectric relaxation time
61. Nanoscopic-confinement effects on local dynamics
62. Effect of free surfaces on the glass transition temperature of thin polymer films
63. Relaxation dynamics in ultrathin polymer films
64. Interface and chain confinement effects on the glass transition temperature of thin polymer films
65. Dynamics of confined polymer melts: Recent Monte Carlo simulation results
66. Thermodynamic determination of fragility in liquids and a fragile-to-strong liquid transition in water
67. The application of the energy landscape model to polymers
68. 1995 Bingham medal address: Oh, thermorheological simplicity, wherefore art thou?
69. Crossover from Debye to non-Debye dynamical behavior of the alpha relaxation observed by quasielastic neutron scattering in a glass-forming polymer
70. Interpretation of anomalous momentum transfer dependences of local chain motion of polymers observed by quasielastic incoherent neutron scattering experiments
71. Neutron scattering study of the picosecond dynamics of polybutadiene and polyisoprene
72. Some connections between viscoelastic properties of PVC and plasticized PVC and molecular kinetics
73. Physical interpretations of various dynamic light scattering data, their interconnections and relations to other relaxation data
74. High frequency relaxation of o-terphenyl
75. Structural relaxation dynamics of ortho-terphenyl
76. Structure and dynamics of glasses and glass formers
77. Distribution of reorientational times of optically anisotropic molecular liquids from depolarized light-scattering studies
78. High-frequency dielectric of Na (-alumina:evidence for relaxation crossover
79. Dynamic-light-scattering study of glasses of hard colloidal spheres
80. Glass transition in colloidal hard spheres: Measurement and mode-coupling-theory analysis of the coherent intermediate scattering function
81. Scaling of the dynamic scattering function of concentrated colloidal suspensions
82. Dynamic light scattering measurements of single particle motions in hard-sphere suspensions near the glass transition
83. 3 by dielectric spectroscopy and light scattering
84. ll
85. Is the susceptibility minimium of glass-forming liquids due to the β relaxation of the mode coupling theory or caused by the ubiquitous constant loss?
86. Structural dependence of fast relaxation in glassforming substances and correlation with the stretch exponent of the slow structural α relaxation
87. An asymmetric double-well potential model for structural relaxation processes in amorphous materials
88. An interpretation of the observed influence of mesophase structures on the β relaxation in side chain liquid crystal polymers
89. An improved theory of polymer dynamics in solution: Probe diffusion and viscosity
90. Segmental relaxation in miscible polymer blends
91. Segmental relaxation and the correlation of time and temperature dependencies in poly (vinyl methyl ether)/polystyrene mixtures
92. Observation of the component dynamics in a miscible polymer blend by dielectric and mechanical spectroscopies
93. Relaxation dynamics in poly (methylphenylsiloxane), 1,1-bis (P-methoxyphenyl) cydohexane, and their mixtures
94. A Connection between the modification of solvent dynamics by polymer in polymer-solutions and component dynamics in miscible polymer blends
95. Anomalous reduction of solvent friction in chlorinated biphenyl solutions of 1,2-polybutadiene
96. Trends in the temperature dependency of segmental relaxation in TMPC/PS blends
97. Component dynamics in polystyrene/bis (2-ethythexyl) phthalate solutions by polarized and depolarized light scattering and dielectric spectroscopy
98. Component dynamics in polyisoprene/ poly (vinylethylene) blends
99. Dielectric and mechanical relaxation in PMPS, BMC and their mixtures
100. A dielectric relaxation study of the relaxation in tetramethylbisphenol a polycarbonate plasticized by tris (2-ethythexyl) phosphate
101. Positranium annihilation lifetime and dynamic mechanical studies of relaxation in BPA-PC and TMBPA-PC plasticized by TOP