Simple relationships for the estimation of melting temperatures of homologous series

Journal of Chemical and Engineering Data

Volumn 46, Issue 3, 2001, Pages 562-573

  Chickos, James S ^a   Nichols, Gary ^a  

^a UNIVERSITY OF MISSOURI ST LOUIS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HOMOLOGOUS SERIES;

CORRELATION METHODS; LIQUID CRYSTALS; MELTING; MOLECULES; POLYMERS; THERMAL EFFECTS;

CRYSTALLINE MATERIALS;

EID: 0035324546     PISSN: 00219568     EISSN: None     Source Type: Journal    
DOI: 10.1021/je0002235     Document Type: Article

References (41)

1. Ubbelohde, A. Melting and Crystal Structure; Oxford University Press: London, 1965.
2. Flory, P. J. Thermodynamics of Crystallization of High Polymers, IV. J. Chem. Phys. 1949, 17, 223.
3. Flory, P. J.; Vrij, A. Melting points of linear chain homologues. The normal paraffin hydrocarbons. J. Am. Chem. Soc. 1963, 85, 3548.
4. Wunderlich, B.; Czornyj, G. A study of equilibrium melting of polyethylene. Macromolecules 1977, 10, 906-13.
5. Buckley, C. P.; Kovacs, A. J. Melting behavior of low molecular weight poly(ethylene oxide fractions. I. Extended chain crystals. Prog. Colloid Polym. Sci. 1975, 58, 44.
6. Mandelkern, L.; Stack, G. N. Equilibrium melting temperature of long chain molecules. Macromolecules 1984, 1, 871 and references cited.
7. Lutton, E. S. Thermal Properties and Crystal State. In Fatty Acids, Part 4, 2nd ed.; Markley, K. S., Ed.; Interscience Publishers: New York, 1967; Chapter XXII.
8. Yalkowski, S. H.; Krzyzaniak, J. F.; Myrdal, P. B. Relationships between melting point and boiling point of organic compounds. Ind. Eng. Chem. 1994, 33, 1872.
9. Tsakanikas, P. D.; Yalkowsky, S. H. Estimation of the melting point of flexible molecules: Aliphatic hydrocarbons. Toxicol. Environ. Chem. 1988, 17, 19.
10. Krzyzaniak, J. F.; Myrdal, P. B.; Simamora, P.; Yalkowski, S. H. Boiling point and melting point prediction for aliphatic nonhydrogen bonding compounds. Ind. Eng. Chem. 1995, 34, 2530.
11. Katritzky, A. R.; Lobanov, V. S.; Karelson, M. QSPR: The correlation and quantitative prediction of chemical and physical properties from structure. Chem. Soc. Rev. 1995, 279.
12. Gavezzotti, A. Molecular symmetry. Melting temperatures and melting enthalpies of substituted benzenes and naphthalenes. J. Chem. Soc., Perkin Trans. 2 1995, 1399.
13. Shriner, R. L.; Herman, C. F. K.; Morrill, T. C.; Curtin, D. Y.; Fuson, R. C. The Systematic Identification of Organic Compounds, 7th ed.; Wiley: New York, 1998.
14. Aldrich Catalog Handbook of Fine Chemicals; Aldrich Chemical Co.: Milwaukee, WI, 2000.
15. The 2000 Catalog; Lancaster Synthesis Inc.: PO Box 1000, Windham, NH 03087, 2000.
16. TRC Thermodynamic Tables, Non-Hydrocarbons; Marsh, K. N. (Director)
17. The Texas A&M University System: College Station, TX, 1991; Supplement 64.
18. Benson, S. W. Thermochemical Kinetics; Methods for the Estimation of Thermochemical Data and Rate Parameters, 2nd ed.; Wiley: New York, 1976.
19. Zeberg-Mikkelsen, C. K.; Stenby, E. H. Predicting the melting points and enthalpies of fusion of saturated triglycerides by a group contribution method. Fluid Phase Equilib. 1999, 162, 7-17.
20. Chickos, J. S. Heats of Sublimation. In Molecular Structure and Energetics; Liebman, J. F., Greenberg, A., Eds.; VCH Publishers: New York, 1987; Vol. 2, Chapter 3.
21. Gray, G. W.; Jones, B. J.; Marson, F. Mesomorphism and Chemical Constitution. Part VII. The Effect of Halogen Substitution on the Mesomorphism of the trans-p-n-Alkoxycinnamic Acids. J. Chem. Soc. 1956, 1417.
22. Barrall, E. M., II; Johnson, J. F. Thermal Properties of Liquid Crystals. In Liquid Crystals and Plastic Crystals; Gray, G. W., Winsor, P. A., Eds.; Ellis Horwood Limited: Chichester, U.K., 1974; Vol. 2, Chapter 10.
23. Chickos, J. S.; Acree, W. E., Jr.; Liebman, J. F. Estimating Solid- Liquid Phase Change Enthalpies and Entropies. J. Phys. Chem. Ref. Data 1999, 28, 1535-1674.
24. Brandrup, J., Immergut, E. H., Ed. Polymer Handbook, 3rd ed.; Wiley: New York, 1989.
25. Stephenson, R. M.; Malonowski, S. Handbook of the Thermodynamics of Organic Compounds; Elsevier: New York, 1987.
26. Dreisbach, D. Physical Properties of Chemical Compounds, Vol. I-III; Advances in Chemistry Series 15, 22, 29; American Chemical Society: Washington, DC, 1955, 1959, 1961.
27. Beilstein Handbook of Organic Chemistry; Springer-Verlag: New York.
28. Lutton, E. S. In Fatty Acids, Their Chemistry, Properties, Production and Uses; Markley, K. S., Ed.; Wiley: New York, 1967; Part 4.
29. Markley, K. S. In Fatty Acids, Their Chemistry, Properties, Production and Uses; Markley, K. S., Ed.; Wiley: New York, 1967; Part 4.
30. Ralston, A. W. Fatty Acids and Their Derivatives; Wiley: New York, 1948.
31. Rappoport, Z., Ed. CRC Handbook of Tables for Organic Compound Identification, 3rd ed.; CRC Press: Boca Raton, FL, 1967.
32. The Merck Index, 7th ed.; Merck and Co.: Rahway, NJ, 1960.
33. Carfagna, C.; Vacatello, M.; Corradini, P. Melting behavior of a series of monoamides. Thermochim. Acta 1979, 28, 265.
34. Gray, G. W.; Hartley, J. B.; Jones, B. Mesomorphism and chemical constitution. Part V. The mesomorphic properties of the 4c-n- alkoxydiphenyl-4-carboxylic Acids and their simple alkyl esters. J. Chem. Soc. 1955, 1412.
35. Gray, G. W.; Jones, B. J.; Marson, F. Mesomorphism and Chemical Constitution. The Effect of Halogen Substitution on the Mesomorphism of the trans-p-n-Alkoxycinnamic Acids. J. Chem. Soc. 1956, 1417.
36. Gondova, T.; Kralik, P.; Gonda, J. Determination of Some Thermodynamic Characteristics of Melting of 8-Alkyltheophyllines by the DSC Method. Thermochim. Acta 1989, 156, 147.
37. Gray, G. W.; Jones, B. J. The Mesomorphic Transition Points of the p-n-Alkoxybenzoic Acids. A Correction. J. Chem. Soc. 1953, 4179.
38. Gray, G. W.; Jones, B. J. Mesomorphism and chemical constitution. The Effect of Halogen Substitution on the Mesomorphism of the p-n-Alkoxybenzoic Acids. J. Chem. Soc. 1954, 2556.
39. Gray, G. W.; Jones, B. J. Mesomorphism and chemical constitution. Part I. The n-alkoxynaphthoic acids. J. Chem. Soc. 1954, 683.
40. Barrall, E. M., II; Johnson, J. F. In Liquid Crystals and Plastic Crystals; Gray, G. W., Winsor, P. A., Eds.; Ellis Horwood Limited: Chichester, U.K., 1974; Vol. 2, Chapter 10.
41. Starkweather, W., Jr. Melting and crystalline transitions in normal perfluoroalkanes and poly(tetrafluoroethylene). Macromolecules 1986, 19, 1131.