Recent advances in bioinorganic spectroscopy

Current Opinion in Chemical Biology

Volumn 5, Issue 2, 2001, Pages 176-187

  Lehnert, Nicolai ^a   George, Serena DeBeer ^a   Solomon, Edward I ^a  

^a STANFORD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ENZYME; LIGAND; METAL; METALLOPROTEIN;

BINDING SITE; COVALENT BOND; ELECTRON SPIN RESONANCE; ENZYME ACTIVE SITE; ENZYME STRUCTURE; LIGAND BINDING; MATHEMATICAL MODEL; METAL BINDING; POLARIZATION; QUANTUM CHEMISTRY; REVIEW; SPECTROSCOPY; STRUCTURE ANALYSIS; TECHNIQUE;

EID: 0035313437     PISSN: 13675931     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1367-5931(00)00188-5     Document Type: Review

References (41)

1. Inorganic spectroscopy - An overview
2. Bioinorganic spectroscopy
3. Geometric and electronic structure/function correlations in non-heme iron enzymes
4. Polarized absorption spectroscopy
5. MCD C-term signs, saturation behavior, and determination of band polarizations in randomly oriented systems with spin S≥1/2. Applications to S=1/2 and S=5/2
6. A novel, general method of analyzing magnetic circular dichroism spectra and magnetization curves of high-spin metal ions: Application to the protein oxidized rubredoxin, Desulfovibrio gigas
7. Magnetic circular dichroism of symmetry and spin forbidden transitions of high-spin metal ions
8. Calculation of zero-field splittings, g-values, and the relativistic nephelauxetic effect in transition metal complexes. Application to high-spin ferric complexes
9. Theory of magnetic circular dichroism
10. Magnetic circular dichroism
11. Magnetic circular dichroism
12. Magnetic circular dichroism spectroscopy as a probe of the geometric and electronic structure of non-heme ferrous enzymes
13. Magnetic circular dichroism anisotropy from coherent Raman detected electron paramagnetic resonance spectroscopy: Application to spin-1/2 transition metal ion centers in proteins
14. Probing the electronic structure of transition metal ion centres in proteins by coherent Raman-detected electron paramagnetic resonance spectroscopy
15. 6H): A model for the high-spin Fe(III) site in rubredoxin
16. 1 ground-state zero-field splitting
17. 6H): The electronic structure of the ferric tetrathiolate active site
18. Spectroscopic studies of the non-heme ferric active site in soybean lipoxygenase: Magnetic circular dichroism as a probe of electronic and geometric structure: Ligand-field origin of zero-field splitting
19. Electronic structure of activated bleomycin: Oxygen intermediates in heme versus nonheme iron
20. Ligand K-edge Xray absorption spectroscopy: A direct probe of ligand-metal covalency
21. 4(2-)
22. Copper l-edge spectral studies: A direct experimental probe of the ground state covalency in the blue copper site in plastocyanin
23. Spectroscopic and electronic structural studies of blue copper model complexes. 1: Perturbation of the thiolate-Cu bond
24. Spectroscopic and electronic structural studies of blue copper model complexes. 2: Comparison of 3- and 4-coordinate Cu(II) thiolate complexes and fungal laccase
25. Variable photon energy photoelectron spectroscopic studies of copper chlorides: An experimental probe of metal-ligand bonding and changes in electronic structure on ionization
26. Spectroscopic and theoretical-studies of the unusual electron-paramagnetic-resonance parameters of distorted tetrahedral cupric sites: Correlations to X-ray spectral features of core levels
27. X-ray absorption spectroscopic studies of the blue copper site: Metal and ligand K-edge studies to probe the origin of the EPR hyperfine splitting in plastocyanin
28. Investigation of the electronic structure of 2Fe-2S model complexes and the Rieske protein using ligand K-edge X-ray absorption spectroscopy
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31. Heme/copper terminal oxidases
32. Copper A of cytochrome c oxidase, a novel, long-embattled, biological electron-transfer site
33. The currents of life: The terminal electron-transfer complex of respiration
34. The cupric site in nitrous-oxide reductase contains a mixed-valence [Cu(II) Cu(I)] binuclear center: A multifrequency electron-paramagnetic resonance investigation
35. a type centers: Ligand-field control of ground-state properties related to electron-transfer
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37. A site in bovine heart cytochrome aa(3) and cytochrome caa(3) and cytochrome ba(3) from Thermus thermophilus
38. Redox-coupled crystal structural changes in bovine heart cytochrome c oxidase