Reduction of dioxygen by a dimanganese unit bonded inside a cavity provided by a pyrrole-based dinucleating ligand

Chemistry - A European Journal

Volumn 7, Issue 7, 2001, Pages 1468-1478

  Franceschi, Federico ^a   Guillemot, Geoffroy ^a   Solari, Euro ^a   Floriani, Carlo ^a   Re, Nazzareno ^b   Birkedal, Henrik ^a   Pattison, Philip ^a  

^a UNIVERSITY OF LAUSANNE   (Switzerland)

^b UNIVERSITY OF CHIETI   (Italy)

Author keywords

Manganese; N ligands; Oxygen reduction; Schiff bases; Structural elucidation

Indexed keywords

ANTIFERROMAGNETIC MATERIALS; CRYSTAL STRUCTURE; DERIVATIVES; MANGANESE; NUCLEATION; OXYGEN; SYNCHROTRON RADIATION;

DINUCLEATING LIGANDS;

REDUCTION;

1,2 PHENYLENEDIAMINE; 2 PYRROLALDEHYDE; 2,4,6 TRIMETHYLPHENYL; ALDEHYDE DERIVATIVE; ETHYLENEDIAMINE; HYDROPEROXIDE DERIVATIVE; LIGAND; MANGANESE; METAL; METHYL GROUP; OXYGEN; PORPHYRIN; PYRROLE; SCHIFF BASE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHIRALITY; COMPLEX FORMATION; CRYSTAL STRUCTURE; DIFFRACTION; MAGNETISM; OXIDATION REDUCTION REACTION; POLYMERIZATION; SYNCHROTRON; SYNTHESIS;

EID: 0035312754     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3765(20010401)7:7<1468::AID-CHEM1468>3.0.CO;2-A     Document Type: Article

References (53)

1. a) Photosynthesis (Ed.: W. R. Briggs); ARL, New York, 1989;
2. b) K. Wieghardt, Angew. Chem. 1989, 101, 1179-1198;
3. Angew. Chem. Int. Ed. Engl. 1989, 28, 1153-1172;
4. c) G. W. Brudwig, R. H. Crabtree, Progr. Inorg. Chem. 1989, 37, 99-142;
5. d) Manganese Redox Enzimes (Ed.: V. L. Pecoraro), VCH, New York, 1992;
6. e) The Photosynthetic Reaction Center, Vols. I and II (Eds.: J. Deisenhofer, J. R. Norris), Academic, New York, 1993;
7. f) E. Gallo, E. Solari, S. De Angelis, C. Floriani, N. Re, A. Chiesi-Villa, C. Rizzoli, J. Am. Chem. Soc. 1993, 115, 9850-9851;
8. g) R. Manchanda, G. W. Brudvig, R. H. Crabtree, Coord. Chem. Rev. 1995, 144, 1-38;
9. h) G. C. Dismukes, Chem. Rev. 1996, 96, 2909-2906;
10. i) J. Limburg, J. S. Vrettos, L. M. Liable-Sands, A. L. Rheingold, R. H. Crabtree, G. Brudvig, Science 1999, 283, 1524-1527;
11. l) C. E. Dubé, R. Sessoli, M. P. Hendrich, D. Gatteschi, W. H. Armstrong, J. Am. Chem. Soc. 1999, 121, 3537-3538.
12. S. I. Murahashi, T. Naota in Comprehensive Organometallic Chemistry II: A Review of the Literature 1982-1994, Vol. 12 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, Oxford (UK), 1995, Chapter 11.3.
13. E. N. Jacobsen in Comprehensive Organometallic Chemistry II: A Review of the Literature 1982-1994, Vol. 12 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon, Oxford (UK), 1995, Chapter 11.1.
14. M. Calligaris, L. Randaccio in Comprehensive Coordination Chemistry, Vol. 2 (Eds.: G. Wilkinson, R. D. Gillard, J. A. McLeverty), Pergamon, Oxford (UK), 1987, Chapt. 20.1.
15. Hydrogen-bond geometries: D⋯A and D-A⋯A are 2.960(2) Å and 157.2° for N1A-H1A⋯N3B, 2.955(2) Å and 155.5° for N1B-H1B⋯ N3A, 2.889(2) Å and 156.2° for N4A-H4A⋯N2B, 2.912(2) Å and 154.7° for N4B-H4B⋯N2A.
16. C Piguet, G. Bernardinelli, G. Hopfgartner, Chem. Rev. 1997, 97, 2005-2062.
17. F. H. Allen, J. E. Davies, J. J. Galloy, O. Johnson, O. Kennard, C. F. Macrae, E. M. Mitchell, G. F. Mitchell, J. M. Smith, D. G. Watson, J. Chem. Inf. Comput. Sci. 1991, 31, 187-204.
18. T. Kikuchi, C. Kabuto, H. Yokoi, M. Iwaizumi, W. Mori, J. Chem. Soc. Chem. Commun. 1983, 1306-1307.
19. F. Franceschi, C. Floriani, unpublished results.
20. C. Stern, F. Franceschi, E. Solari, C. Floriani, N. Re, R. Scopelliti, J. Organomet. Chem. 2000, 593, 86-95.
21. G. C. van Stein, G. van Koten, H. Passenier, O. Steinbach, K. Vrieze, Inorg. Chim. Acta 1984, 89, 79-87.
22. Gaussian98 (Revision A.7), Gaussian, Inc., Pittsburgh, PA, 1998.
23. a) P. J. Pospisil, D. H. Carsten, E. N. Jacobsen, Chem. Eur. J. 1996, 2, 974-980;
24. b) E. Gallo, E. Solari, N. Re, C. Floriani, A. Chiesi-Villa, C. Rizzoli, J. Am. Chem. Soc. 1997, 119, 5144-5154;
25. c) L. Canali, D. C. Sherrington, Chem. Soc. Rev. 1999, 28, 85-93, and references therein.
26. E. Gallo, E. Solari, C. Floriani, A. Chiesi-Villa, C. Rizzoli, Inorg. Chem. 1997, 36, 2178-2186.
27. a) M. R. Bermejo, A. Castiñeiras, J. C. Garcia-Monteagudo, M. Ray, A. Sousa, M. Watkinson, C. A. McAuliffe, R. G. Pritchard, R. Beddoes, J. Chem. Soc. Dalton Trans. 1996, 2935-2944;
28. b) H. Torayama, T. Nishide, H. Asada, M. Fujiwara, T. Matsushita, Polyhedron 1998, 17, 105-118.
29. V. L. Pecoraro in Manganese Redox Enzymes (Ed.: V. L. Pecoraro), VCH, New York, 1992, Chapter 10, and references therein.
30. V. L. Pecoraro, M. J. Baldwin, A. Gelasco, Chem. Rev. 1994, 94, 807-826, and references therein.
31. E. Gallo, E. Solari, N. Re, C. Floriani, A. Chiesi-Villa, C. Rizzoli, Angew. Chem. 1996, 108, 2113-2115;
32. Angew. Chem. Int. Ed. Engl. 1996, 35, 1981-1983.
33. R. Bhula, G. J. Gainsford, D. C. Weatherburn, J. Am. Chem. Soc. 1988, 110, 7550-7552.
34. U. Bossek, T. Weyhermüller, K. Wieghardt, B. Nuber, J. Weiss, J. Am. Chem. Soc. 1990, 112, 6387-6388.
35. D. Ramalakshmi, M. V. Rajasekharan, Acta Crystallogr. Sect. B 1999, 55, 186-191, and references therein.
36. M. Lockwood, K. Wang, J. M. Mayer, J. Am. Chem. Soc. 1999, 121, 11 894-11 895, and references therein.
37. K. Wang, J. M. Mayer, J. Am. Chem. Soc. 1997, 119, 1470-1471.
38. a) R. Hoffmann, W. N. Lipscomb, J. Chem. Phys. 1962, 36, 2179-2189;
39. b) R. Hoffmann, J. Chem. Phys. 1963, 59, 1397-1412.
40. O. Kahn, Molecular Magnetism, VCH, New York, 1992.
41. K. Wieghardt, U. Bossek, J. Bonvoisin, P. Beaullivain, J. J. Girerd, B. Nuber, J. Weiss, J. Heinze, Angew. Chem. 1986, 98, 1026-1027;
42. Angew. Chem. Int. Ed. Engl. 1986, 25, 1030-1031.
43. E. Solari, F. Musso, E. Gallo, C. Floriani, N. Re, A. Chiesi-Villa, C. Rizzoli, Organometallics 1995, 14, 2265-2276.
44. F. A. Cotton, F. Calderazzo, Inorg. Chem. 1962, 1, 30-36.
45. E. A. Boudreaux, L. N. Mulay, Theory and Applications of Molecular Paramagnetism, Wiley, New York, 1976, pp. 491-495.
46. C. Mealli, D. M. Proserpio, J. Chem. Educ. 1990, 67, 399-402.
47. S. Alvarez, Tables of Parameters for Extended Hückel Calculations, Universitat de Barcelona, Barcelona (Spain), 1993.
48. G. M. Sheldrick, SHELXS-97, Program for the Solution of Crystal Structures, University of Göttingen, (Germany), 1997.
49. G. M. Sheldrick, SHELXL-97, Program for the Refinement of Crystal Structures, University of Göttingen, (Germany), 1997.
50. XP 5.0.4, Siemens Analytical X-ray Insts., 1996.
51. Z. Otwinowski, W. Minor, Methods Enzymol. A 1997, 276, 307-326.
52. teXsan 1.0.1 for Windows, Molecular Structure Corporation, a Rigaku company, 3200 Research Forest Drive, The Woodlands, TX 77381 - 4238 (USA), 1997.
53. CrysAlis-RED, release 1.6.2, Kuma Diffraction Instruments GmbH, PSE-EPFL module 3.4, CH-1015, Lausanne (Switzerland), 1999.