Regioselective metalation of a tertiary phosphine. Synthesis and structural characterization of an unusual tetramerie lithium phosphinomethanide

Organometallics

Volumn 20, Issue 4, 2001, Pages 648-653

  Izod, Keith ^a   O'Shaughnessy, Paul ^a   Clegg, William ^a   Liddle, Stephen T ^a  

^a NEWCASTLE UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTALLIZATION; HEAT TREATMENT; LITHIUM COMPOUNDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION KINETICS; STRUCTURE (COMPOSITION); SYNTHESIS (CHEMICAL); THERMAL EFFECTS; TOLUENE; X RAY CRYSTALLOGRAPHY;

REGIOSELECTIVE METALATION; TERTIARY PHOSPHINE; TETRAMERIC LITHIUM PHOSPHINOMETHANIDE;

PHOSPHORUS COMPOUNDS;

EID: 0035249106     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000876e     Document Type: Article

References (4)

1. Edwards, G. L. In Comprehensive Organic Functional Group Transformations; Katritzky, A. R., Meth-Cohn, O., Rees, C. W., Eds.; Elsevier: Oxford, 1995; pp 579-627.
2. Peterson, D. J. J. Organomet. Chem. 1967, 8, 199.
3. For examples of the application of P-stabilized carbanions in organic synthesis see: (a) Horner, L.; Hoffmann, H.; Wippel, H. G.; Klahre, G. Chem. Ber. 1959, 92, 2499.
4. (b) Maryanoff, B. E.; Reitz, D. B. Chem. Rev. 1989, 89, 863.