메뉴 건너뛰기




Volumn , Issue 12, 2001, Pages 3187-3197

Seven-coordinate d0 and d10 ions - Computational and experimental studies on tris(tropolonato)metal(III)-TOPO adducts

Author keywords

Chelates; Coordination chemistry; Density functional calculations; Hypervalent compounds; Thallium; Yttrium

Indexed keywords

CHELATION; CHEMICAL BONDS; GALLIUM; GALLIUM COMPOUNDS; INDIUM COMPOUNDS; IONS; LIGANDS; MOLECULAR ORBITALS; SOLVENT EXTRACTION; THALLIUM COMPOUNDS; YTTRIUM;

EID: 0035208559     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200112)2001:12<3187::AID-EJIC3187>3.0.CO;2-Z     Document Type: Article
Times cited : (10)

References (54)
  • 6
    • 85163227239 scopus 로고
    • Springer Verlag, Berlin, chapters 1 and 8
    • D. L. Kepert, Inorganic Stereochemistry, Springer Verlag, Berlin, 1982, chapters 1 and 8, pp. 1-6 and 92-111.
    • (1982) Inorganic Stereochemistry , pp. 1-6
    • Kepert, D.L.1
  • 8
    • 84913393992 scopus 로고
    • (Eds.: A. S. Kertes, Y. Marcus), Wiley-Interscience
    • T. V. Healy, in Solvent Extraction Research (Eds.: A. S. Kertes, Y. Marcus), Wiley-Interscience, 1969, p. 257-279.
    • (1969) Solvent Extraction Research , pp. 257-279
    • Healy, T.V.1
  • 12
    • 0003806853 scopus 로고
    • (Ed.: A. J. Downs), Blackie Academic & Professional, London, chapter 8
    • D. G. Tuck, in Chemistry of Aluminium, Gallium, Indium and Thallium (Ed.: A. J. Downs), Blackie Academic & Professional, London, 1993, chapter 8, p. 430-473.
    • (1993) Chemistry of Aluminium, Gallium, Indium and Thallium , pp. 430-473
    • Tuck, D.G.1
  • 16
    • 85163224797 scopus 로고    scopus 로고
    • note
    • Neither the double bond nor the negative charge was fixed on the ligand; the electron density was distributed on the atoms of the chelate in the course of the optimisation procedure.
  • 26
    • 0003973732 scopus 로고
    • (Eds.: G. H. F Dierksen, S. Wilson), Reidel, Dordrecht, The Netherlands
    • B. O. Roos, in Methods of Computational Molecular Physics (Eds.: G. H. F Dierksen, S. Wilson), Reidel, Dordrecht, The Netherlands, 1979.
    • (1979) Methods of Computational Molecular Physics
    • Roos, B.O.1
  • 32
    • 85163224685 scopus 로고    scopus 로고
    • note
    • The total energies of the distorted structures were calculated for both components of the same geometry as they had in the adduct with the optimised structure. This means that all the atoms belonging to one of the adduct components were removed, preserving the interatomic distances and angles in the other, and then the energy was calculated for the remaining system of total charge equal to zero. Then the same procedure was repeated for the other component.
  • 33
    • 85163223215 scopus 로고    scopus 로고
    • note
    • B bond was broken, but the geometry of the subunits was maintained the same as that in the adduct. The total charges (Δq) on all the atoms of the separated subunits were equal to zero, contrary to the case when in the adduct.
  • 34
    • 0004073057 scopus 로고
    • CAOS/CAMM Center Nijmegen, The Netherlands
    • G. Shaftenaar, Molden, CAOS/CAMM Center Nijmegen, The Netherlands, 1991.
    • (1991) Molden
    • Shaftenaar, G.1
  • 35
    • 85163234284 scopus 로고    scopus 로고
    • note
    • This concentration extraction constant correctly describes the system, provided the concentrations are low enough and the activity coefficients are close to one.
  • 36
    • 85163230441 scopus 로고    scopus 로고
    • note
    • 3] formed no TOPO adducts.
  • 47
    • 85163230892 scopus 로고    scopus 로고
    • note
    • [32]).
  • 50
    • 85163234911 scopus 로고    scopus 로고
    • note
    • [7]).
  • 52
    • 27544471275 scopus 로고    scopus 로고
    • (Ed.: Kin-ya Akiba), Wiley-VCH, New York, chapters 1 and 2
    • [42b] Kin-ya Akiba, in Chemistry of Hypervalent Compounds (Ed.: Kin-ya Akiba), Wiley-VCH, New York, 1999, chapters 1 and 2, p. 1-47.
    • (1999) Chemistry of Hypervalent Compounds , pp. 1-47
    • Akiba, K.-Y.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.