Cationic five-coordinate Bis(butadiene)iridium(I) complexes from the highly labile cis-[Ir(η2-C8H14)2(acetone) 2]+ cation as the precursor

European Journal of Inorganic Chemistry

Volumn , Issue 12, 2001, Pages 3181-3185

  Bosch, Marco ^a   Ilg, Kerstin ^a   Werner, Helmut ^a  

^a UNIVERSITY OF WÜRZBURG   (Germany)

Author keywords

Acetone complexes; Alkene ligands; Antimony; Arsenic; Iridium; P ligands

Indexed keywords

ANTIMONY COMPOUNDS; ARSENIC; BUTADIENE; CRYSTAL STRUCTURE; IRIDIUM COMPOUNDS; LIGANDS; POSITIVE IONS;

ACETONE COMPLEX; ALKENE LIGANDS; APICAL POSITIONS; CATIONICS; COORDINATE COMPLEXES; CYCLOOCTENE; P LIGANDS; PHOSPHANE LIGANDS; SQUARE-PYRAMIDAL GEOMETRY; X-RAY CRYSTAL STRUCTURE ANALYSIS;

ACETONE;

1,3 BUTADIENE; ACETONE; CATION; IRIDIUM COMPLEX; LIGAND;

ARTICLE; COMPLEX FORMATION; CRYSTAL STRUCTURE; GEOMETRY; REACTION ANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 0035208482     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200112)2001:12<3181::AID-EJIC3181>3.0.CO;2-Y     Document Type: Article

References (29)

1. H. Werner, M. Bosch, C. Hahn, F. Kukla, M. Laubender, M. Manger, M. E. Schneider, B. Weberndörfer, B. Windmüller, J. Chew. Soc., Dalton Trans. 1998, 3549-3558.
2. [2a] M. E. Schneider, H. Werner, 10th International Symposium on Homogeneous Catalysis, Princeton, 1996;
3. [2b] M. E. Schneider, Dissertation, Universität Würzburg, 1996.
4. M. Bosch, M. Laubender, B. Weberndörfer, H. Werner, Chem. Eur. J. 1999, 5, 2203-2211.
5. M. Bosch, M. Brookhart, K. Ilg, H. Werner, Angew. Chem. 2000, 112, 2388-2391;
6. Angew. Chem. Int. Ed. 2000, 39, 2304-2307.
7. R. R. Schrock, J. A. Osborn, J. Am. Chem. Soc. 1971, 93, 3089-3090.
8. A. C. Sievert, E. L. Muetterties, Inorg. Chem. 1981, 20, 489-501.
9. B. Windmüller, J. Wolf, H. Werner, J. Organomet. Chem. 1995, 502, 147-161.
10. A. L. Onderdelinden, A. van der Ent, Inorg. Chim. Acta 1972, 6, 420-426.
11. [9a] T. C. van Soest, A. van der Ent, E. C. Royers, Cryst. Struct. Commun. 1973, 3, 527-529;
12. [9b] J. Müller, B. Passon, Z. Naturforsch., Teil B 1982, 37, 1358-1359;
13. [9c] J. Müller, W. Hähnlein, B. Passon, Z. Naturforsch., Teil B 1982, 37, 1573-1579;
14. [9d] J. Müller, C. Friedrich, T. Akhnoukh, K. Qiao, J. Organomet. Chem. 1994, 476, 93-99.
15. G. del Piero, G. Perego, M. Cesari, Gazz. Chim. Ital. 1975, 105, 520-537.
16. [11a] R. W. Lass, P. Steinert, J. Wolf, H. Werner, Chem. Eur. J. 1996, 2, 19-23;
17. [11b] H. Werner, R. W. Lass, O. Gevert, J. Wolf, Organometallics 1997, 16, 4077-4088;
18. [11c] K. Ilg, H. Werner, Organometallics 1999, 18, 5426-5428;
19. [11d] K. Ilg, H. Werner, Angew. Chem. 2000, 112, 1691-1694;
20. Angew. Chem. Int. Ed. 2000, 39, 1632-1634;
21. [11e] H. Werner, K. Ilg, B. Weberndörfer, Organometallics 2000, 19, 3145-3153.
22. [12a] D. N. Cox, R. Roulet, J. Organomet. Chem. 1988, 342, 87-95;
23. [12b] D. N. Cox, R. Roulet, Organometallics 1985, 4, 2001-2005;
24. [12c] R. Poli, L.-S. Wang, J. Am. Chem. Soc. 1998, 120, 2831-2842.
25. R. S. Dickson, Organometallic Chemistry of Rhodium and Iridium, Academic Press, London, 1983.
26. A. L. Onderdelinden, A. van der Ent, Inorg. Synth. 1973, 14, 92-95.
27. S. Samaan, in Methoden der Organischen Chemie (Houben-Weyl) (Ed.: E. Müller), 4th Ed., Thieme, Stuttgart, 1978, Vol. XIII/8, p. 45 and 445.
28. G. M. Sheldrick, Acta Crystallogr., Sect. A 1990, 46, 467-473.
29. G. M. Sheldrick, A Program for Crystal Structure Refinement, University of Göttingen, 1993.