Reactivity of the base-stabilized bis(silylene)iron complex (η5-C5H5)Fe(CO)(η2-SiMe 2-OtBu-SiMe2): Elevated temperature trapping of SiMe2 by R3EH (R = Me3Si, E = Si, Ge) and elimination of Me2(OtBu)SiSiMe2H by n-Bu3SnH

Organometallics

Volumn 20, Issue 1, 2001, Pages 7-9

  Sharma, Hemant K ^a   Pannell, Keith H ^a  

^a UNIVERSITY OF TEXAS AT EL PASO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST ACTIVITY; CHEMICAL BONDS; CONCENTRATION (PROCESS); NUCLEAR MAGNETIC RESONANCE; PHOTOCHEMICAL REACTIONS; THERMAL EFFECTS;

BASE-FREE COMPLEXES; PHOTOCHEMICAL IRRADIATION;

ORGANOMETALLICS;

EID: 0035128082     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000563j     Document Type: Article

References (8)

1. (a) Corey, J. Y.; Braddock-Wilking, J. Chem. Rev. 1999, 99, 175.
2. (b) Sharma, H. K.; Pannell, K. H. Chem. Rev. 1995, 95, 1351.
3. Tilley, T. D. In The Silicon Heteroatom Bond; Patai, S., Rappoport, Z., Eds.; Wiley: New York, 1991; Chapters 9 and 10.
4. (a) Harrod, J.; Zeigler, T.; Tschinke, V. Organometallics 1990, 9, 897.
5. (b) Yamashita, H.; Tanaka, M.; Goto, M. Organometallics 1992, 11, 3227.
6. (c) Gavin, F.; Harrod, J. F.; Woo, H. G. Adv. Organomet. Chem. 1998, 42, 363.
7. (d) Tilley, T. D. Comments Inorg. Chem. 1990, 10, 37.
8. (e) Hengge, E.; Weinberger, J. J. Organomet. Chem. 1993, 443, 167.