A kinetic model for the oxidation of U(IV) to U(VI) with O2: Determination of stability constants via oxidation kinetic experiments

Radiochimica Acta

Volumn 89, Issue 2, 2001, Pages 75-82

  Landgren, A ^a   Rameback H ^a  

^a Evox Rifa AB   (Sweden)

Author keywords

Hydrolysis; Oxidation; Reaction rate; Uranium

Indexed keywords

OXYGEN; URANIUM DERIVATIVE;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; HYDROLYSIS; OXIDATION; REACTION ANALYSIS; THERMODYNAMICS;

EID: 0035073939     PISSN: 00338230     EISSN: None     Source Type: Journal    
DOI: 10.1524/ract.2001.89.2.075     Document Type: Article

References (12)

1. 2O(am)
2. Kinetics of the oxidation of uranium(IV) by molecular oxygen in aqueous perchloric acid solution
3. Rate of oxidation of tetravalent uranium ions with molecular oxygen
4. PHREEQE, A computer program for geochemical calculations
5. Investigation of the hydrolytic properties of tetravalent uranium. II. Conditions of formation of mononuclear and polynuclear hydroxo complexes of U(IV)
6. The hydrolysis of uranium tetrafluoride
7. Hydrolytic behavior of metal ions: I. The acid constants of uranium(IV) and plutonium(IV)
8. General computer program for the computation of stability constants from absorbance data