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Volumn 49, Issue 4, 2001, Pages 468-472

Stereoselective reactions. XXXIV. Enantioselective deprotonation of prochiral 4-substituted cyclohexanones using chiral bidentate lithium amides having a bulky group instead of a phenyl group on the chiral carbon

(5) Toriyama, M a Sugasawa, K a Motohashi, S a Tokutake, N a Koga, K a

a NARA INSTITUTE OF SCIENCE AND TECHNOLOGY (Japan)

Author keywords

15N NMR; 6Li NMR; Chiral lithium amide; Eight membered cyclic transition state model; Enantioselective deprotonation

Indexed keywords

AMIDE; CARBON; CHLOROTRIMETHYLSILANE; CYCLOHEXANONE DERIVATIVE; HEMPA; LITHIUM DERIVATIVE; PHENYL GROUP; TETRAHYDROFURAN;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; STEREOCHEMISTRY;

CYCLOHEXANONES; INDICATORS AND REAGENTS; LITHIUM; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR CONFORMATION; PROTONS; STEREOISOMERISM;

EID: 0035061926 PISSN: 00092363 EISSN: None Source Type: Journal
DOI: 10.1248/cpb.49.468 Document Type: Article

Times cited : (14)

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