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Volumn , Issue 5, 2001, Pages 1287-1293

Structure, magnetic properties and magnetic phase diagram of a layered, bimetallic, cyanide-bridged CrIII-NiII metamagnet

Author keywords

Chromium; Cyanides; Magnetic properties; Nickel

Indexed keywords

ANTIFERROMAGNETISM; CHROMIUM COMPOUNDS; CYANIDES; FERROMAGNETIC MATERIALS; FERROMAGNETISM; MAGNETIC PROPERTIES; NICKEL COMPOUNDS; PHASE DIAGRAMS;

EID: 0035036178     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200105)2001:5<1287::aid-ejic1287>3.0.co;2-p     Document Type: Article
Times cited : (74)

References (51)
  • 28
    • 85152996681 scopus 로고    scopus 로고
    • note
    • Here we restrict the word dimensionality to coordination bonds, a two dimensional system is one where coordination bonds (metal - cyanides, for example) spread in the two directions of space.
  • 40
    • 85152990557 scopus 로고    scopus 로고
    • note
    • III.
  • 41
    • 85153017597 scopus 로고    scopus 로고
    • note
    • MT has no real meaning because at this temperature the magnetization is field dependent, nevertheless the high value indicates the presence of a large correlation within the layers.
  • 42
    • 85152998986 scopus 로고    scopus 로고
    • note
    • It was checked that ac susceptibility vs. temperature plots performed at 0 and 50 Oe static applied field are identical to those of Figure 6 which indicate that saturation effects are nonexistent at such low fields. On the other hand, such measurements made at different frequencies of the oscillating field and with zero static field confirm the presence of a magnetic ordering at T = 14 K.
  • 44
    • 85153000650 scopus 로고    scopus 로고
    • note
    • We must be cautious at this stage because our measurements were carried out on a powder and not on an oriented single crystal with the applied field parallel to the easy axis, but the shape of the M = f(H) curve, which is the sum of the parallel and the perpendicular components of the magnetization, presents a too sharp transition to be that of a spin-flop phase.
  • 46
    • 85153012657 scopus 로고    scopus 로고
    • note
    • For the previously reported cyclam-based compound, the largest susceptibility value measured (within the same applied field as for the present compound i.e. 30 Oe) was found to be one order of magnitude smaller than for the present compound.
  • 50
    • 85153015608 scopus 로고    scopus 로고
    • G. M. Sheldrick, Institüt für Anorganische Chemie der Universität, Tammanstraße 4, 3400 Göttingen, Germany, 1998
    • G. M. Sheldrick, Institüt für Anorganische Chemie der Universität, Tammanstraße 4, 3400 Göttingen, Germany, 1998.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.