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Neutron scattering study of nitrogen adsorbed on basal-plane-oriented graphite
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Neutron scattering studies of the structure and dynamics of methane adsorbed on MgO(100)
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••This review outlines the preparation and use of MgO as a substrate for adsorption studies as a well-defined substrate with only a single exposed crystal face (100). Tunnelling spectra is used to determine the wetting behaviour and the molecular orientation of methane on MgO
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Larese J.Z. Neutron scattering studies of the structure and dynamics of methane adsorbed on MgO(100). Physica B. 248:1998;297-303. ••This review outlines the preparation and use of MgO as a substrate for adsorption studies as a well-defined substrate with only a single exposed crystal face (100). Tunnelling spectra is used to determine the wetting behaviour and the molecular orientation of methane on MgO.
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Wu H., Hess G.B. Multilayer adsorption of deuterium hydride on graphite. Phys Rev. B57:1998;6720-6730.
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Madih-Ayadi K., Rakotozafy S., Ceva T., et al. Growth mode of dichloromethane physisorbed on graphite. Thermodynamic and structural characterisations. Surf Sci. 436:1999;99-106.
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Low coverage structure of tetramethyltin adsorbed on graphite
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Asmussen B., Strzelczyk M., Press W., Larese J.Z. Low coverage structure of tetramethyltin adsorbed on graphite. Surf Sci. 406:1998;138-148.
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4243518549
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New neutron scattering techniques to characterise the structure of solid monolayers adsorbed from condensed phases to solid substrates
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Castro M.A., Clarke S.M., Inaba A., Thomas R.K. New neutron scattering techniques to characterise the structure of solid monolayers adsorbed from condensed phases to solid substrates. Physica. B241-243:1998;1086-1088.
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Castro, M.A.1
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Inaba, A.3
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10
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0000706016
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Competitive adsorption of simple linear alkane mixtures onto graphite
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•This paper demonstrates that many simple alkanes form solid monolayers when adsorbed from their liquids and solutions
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Castro M.A., Clarke S.M., Inaba A., Arnold T., Thomas R.K. Competitive adsorption of simple linear alkane mixtures onto graphite. J Phys Chem. B102:1998;10528-10534. •This paper demonstrates that many simple alkanes form solid monolayers when adsorbed from their liquids and solutions.
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J Phys Chem
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Castro, M.A.1
Clarke, S.M.2
Inaba, A.3
Arnold, T.4
Thomas, R.K.5
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11
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0001298317
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Neutron diffraction studies of the structure, growth and melting of intermediate length n-alkanes adsorbed on graphite
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••The unusual mechanism of melting of two-dimensional layers has been of interest for some time. This paper and others outline the so-called 'foot print reduction' mechanism where motion perpendicular to the surface makes vacancies in the adsorbed layer which allow translational and rototational disorder to develop
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Taub H., Herwig K.W., Matthies B., Hansen F.Y. Neutron diffraction studies of the structure, growth and melting of intermediate length n-alkanes adsorbed on graphite. Inorg Mater. 35:1999;847-851. ••The unusual mechanism of melting of two-dimensional layers has been of interest for some time. This paper and others outline the so-called 'foot print reduction' mechanism where motion perpendicular to the surface makes vacancies in the adsorbed layer which allow translational and rototational disorder to develop.
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Inorg Mater
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Taub, H.1
Herwig, K.W.2
Matthies, B.3
Hansen, F.Y.4
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12
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0000200969
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A molecular dynamics study of the structure of water layers adsorbed on MgO(100)
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Marmier A., Hoang P.N.M., Picard S., Girardet C., Lynden-bell R.M. A molecular dynamics study of the structure of water layers adsorbed on MgO(100). J Chem Phys. 109:1998;3245-3254.
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J Chem Phys
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Marmier, A.1
Hoang, P.N.M.2
Picard, S.3
Girardet, C.4
Lynden-Bell, R.M.5
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15
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0033231012
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The investigation of mixed monolayers adsorbed from solution: Octane and nonane mixtures on graphite
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••This paper combines coherent and incoherent neutron scattering to investigate competitive adsorption of binary alkanes, providing absolute surface composition as a function of bulk solution composition. The mixing behaviour is explained in terms of the structures of the monolayers of the pure components
-
Castro M.A., Clarke S.M., Inaba A., Thomas R.K., Arnold T. The investigation of mixed monolayers adsorbed from solution: octane and nonane mixtures on graphite. Phys Chem Chem Phys. 1:1999;5017-5023. ••This paper combines coherent and incoherent neutron scattering to investigate competitive adsorption of binary alkanes, providing absolute surface composition as a function of bulk solution composition. The mixing behaviour is explained in terms of the structures of the monolayers of the pure components.
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(1999)
Phys Chem Chem Phys
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, pp. 5017-5023
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Castro, M.A.1
Clarke, S.M.2
Inaba, A.3
Thomas, R.K.4
Arnold, T.5
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16
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0031245449
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Solid monolayers adsorbed at the solid-liquid interface studied by incoherent elastic neutron scattering
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••The use of incoherent elastic neutron scattering as a rapid and effective method to investigate adsorbed layers is demonstrated in this work
-
Castro M.A., Clarke S.M., Inaba A., Thomas R.K. Solid monolayers adsorbed at the solid-liquid interface studied by incoherent elastic neutron scattering. J Phys Chem. B101:1997;8878-8882. ••The use of incoherent elastic neutron scattering as a rapid and effective method to investigate adsorbed layers is demonstrated in this work.
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J Phys Chem
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, pp. 8878-8882
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Castro, M.A.1
Clarke, S.M.2
Inaba, A.3
Thomas, R.K.4
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17
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0000385798
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Quasielastic neutron scattering and molecular dynamics simulations studies of the melting transition in butane and hexane monolayers adsorbed on graphite
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Herwig K.W., Wu Z., Dai P., Taub H., Hansen F.Y. Quasielastic neutron scattering and molecular dynamics simulations studies of the melting transition in butane and hexane monolayers adsorbed on graphite. J Chem Phys. 107:1997;5186-5196.
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, pp. 5186-5196
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Herwig, K.W.1
Wu, Z.2
Dai, P.3
Taub, H.4
Hansen, F.Y.5
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18
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0343622019
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Tokyo: Arcadia Ichigaya
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Castro M., Clarke S.M., Inaba A., Perdigon A., Prestidge A., Thomas R.K. International Conference on Colloid and Surface Science, solid monolayers of simple alkyl molecules adsorbed from their liquid to graphite: the influence of different chemical groups. 2000;Arcadia Ichigaya, Tokyo.
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(2000)
International Conference on Colloid and Surface Science, Solid Monolayers of Simple Alkyl Molecules Adsorbed from Their Liquid to Graphite: The Influence of Different Chemical Groups
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Castro, M.1
Clarke, S.M.2
Inaba, A.3
Perdigon, A.4
Prestidge, A.5
Thomas, R.K.6
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Clarke SM, Inaba A, Arnold T, Thomas RK, Castro M. Proceedings of ASR-2000, dynamics of monolayers adsorbed at the solid-liquid interface, 2000.
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Proceedings of ASR-2000, Dynamics of Monolayers Adsorbed at the Solid-liquid Interface
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Clarke, S.M.1
Inaba, A.2
Arnold, T.3
Thomas, R.K.4
Castro, M.5
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21
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0033571128
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Anomalous behaviour of pentane adsorbed at the graphite/liquid interface
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•This paper uses coherent and incoherent neutron scattering to identify the formation of a solid monolayer of pentane adsorbed from its liquid to graphite. The pre-melting of the bulk material is exploited to separate monolayer and bulk melting
-
Castro M.A., Clarke S.M., Inaba A., Arnold T., Thomas R.K. Anomalous behaviour of pentane adsorbed at the graphite/liquid interface. Phys Chem Chem Phys. 1:1999;5203-5207. •This paper uses coherent and incoherent neutron scattering to identify the formation of a solid monolayer of pentane adsorbed from its liquid to graphite. The pre-melting of the bulk material is exploited to separate monolayer and bulk melting.
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(1999)
Phys Chem Chem Phys
, vol.1
, pp. 5203-5207
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Castro, M.A.1
Clarke, S.M.2
Inaba, A.3
Arnold, T.4
Thomas, R.K.5
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22
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0032182101
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Surface vibrational spectroscopy of lubricants adsorbed at the iron-water interface
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Duffy D.C., Friedmann A., Boggis S.A., Klenerman D. Surface vibrational spectroscopy of lubricants adsorbed at the iron-water interface. Langmuir. 14:1998;6518-6527.
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Langmuir
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Duffy, D.C.1
Friedmann, A.2
Boggis, S.A.3
Klenerman, D.4
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24
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0001217003
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The structure of chloromethane monolayers adsorbed on graphite
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Morishige K., Tajima Y., Kittaka S., Clarke S.M., Thomas R.K. The structure of chloromethane monolayers adsorbed on graphite. Mol Phys. 72:1991;395-411.
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Mol Phys
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Morishige, K.1
Tajima, Y.2
Kittaka, S.3
Clarke, S.M.4
Thomas, R.K.5
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25
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0001738390
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The structure of a methyl iodide monolayer adsorbed on graphite
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Bucknall R.E., Clarke S.M., Shapton R.A., Thomas R.K. The structure of a methyl iodide monolayer adsorbed on graphite. Mol Phys. 67:1989;439-446.
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Mol Phys
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Bucknall, R.E.1
Clarke, S.M.2
Shapton, R.A.3
Thomas, R.K.4
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26
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0041463109
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The structure and heat capacity of fluoromethane monolayers adsorbed on graphite
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Inaba A., Chihara H., Clarke S.M., Thomas R.K. The structure and heat capacity of fluoromethane monolayers adsorbed on graphite. Mol Phys. 72:1991;109-120.
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Mol Phys
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Inaba, A.1
Chihara, H.2
Clarke, S.M.3
Thomas, R.K.4
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0031678786
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Structural study of a chloroform film adsorbed on graphite
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Bah A., Ceva T., Croset B., Dupont-Pavlovsky N., Ressouche E. Structural study of a chloroform film adsorbed on graphite. Surf Sci. 395:1998;307-316.
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Surf Sci
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Bah, A.1
Ceva, T.2
Croset, B.3
Dupont-Pavlovsky, N.4
Ressouche, E.5
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Diffusion quasielastic des neutrons
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Jobic H. Diffusion quasielastic des neutrons. J Phys. 10:2000;1-77.
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Diffusive motion of water molecules in harmotome studied by neutron scattering
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Stockmeyer R. Diffusive motion of water molecules in harmotome studied by neutron scattering. Ber Bunsenges Phys Chem. 102:1998;623-628.
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31
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0033899128
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Diffusive motion in model soft matter systems: Quasielastic neutron scattering study of short and intermediate length alkane layers
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•Measurements of the translational and rotational diffusion coefficients of simple alkanes C32 and C7 and their mixture on graphite are presented and compared to the diffusion coefficient of the bulk. There is a useful table summarizing translational and diffusion coefficients of the bulk and adsorbed layers
-
Fuhrmann D., Criswell L., Mo H., et al. Diffusive motion in model soft matter systems: quasielastic neutron scattering study of short and intermediate length alkane layers. Physica B. 276-278:2000;345-346. •Measurements of the translational and rotational diffusion coefficients of simple alkanes C32 and C7 and their mixture on graphite are presented and compared to the diffusion coefficient of the bulk. There is a useful table summarizing translational and diffusion coefficients of the bulk and adsorbed layers.
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Physica B
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Fuhrmann, D.1
Criswell, L.2
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Calculation of rotational states of methane molecules in a square lattice
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Ozaki Y., Prager M., Asmussen B. Calculation of rotational states of methane molecules in a square lattice. J Phys Chem Solids. 60:1999;1523-1526.
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Ozaki, Y.1
Prager, M.2
Asmussen, B.3
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0034688628
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The behaviour of liquid alkanes near interfaces
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•Computer simulation work on the competitive adsorption of binary alkane mixtures. Interestingly this work found that the shorter alkane was preferentially adsorbed
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Smith P., Lynden-Bell R.M., Smith W. The behaviour of liquid alkanes near interfaces. Mol Phys. 98:2000;255-260%. •Computer simulation work on the competitive adsorption of binary alkane mixtures. Interestingly this work found that the shorter alkane was preferentially adsorbed.
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Mol Phys
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, pp. 255-260
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Smith, P.1
Lynden-Bell, R.M.2
Smith, W.3
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0032074299
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Isotopic ordering in adsorbed hydrogen single layers
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Bianfait M., Gay J.M., Zeppenfeld P., Vilches O.E., Mirebeau I., Lauter H.J. Isotopic ordering in adsorbed hydrogen single layers. J Low Temp Phys. 111:1998;555-560.
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J Low Temp Phys
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Bianfait, M.1
Gay, J.M.2
Zeppenfeld, P.3
Vilches, O.E.4
Mirebeau, I.5
Lauter, H.J.6
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35
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0031548196
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Structure of monolayer films of hydrogen isotope mixtures
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2 on graphite identifying isotopic clustering below 8 K. By careful control of coverage the authors address compressibility differences as a driving force for phase separation. Additionally they report on the kinetics of phase separation, which are found to be very slow
-
2 on graphite identifying isotopic clustering below 8 K. By careful control of coverage the authors address compressibility differences as a driving force for phase separation. Additionally they report on the kinetics of phase separation, which are found to be very slow.
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Physica B
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, pp. 159-163
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Bianfait, M.1
Zeppenfeld, P.2
Bovie, L.J.3
Vilches, O.E.4
Lauter, H.J.5
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37
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0031696781
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Crystalline monolayer of dodecanoic acid adsorbed on graphite from n-heptane solution
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Castro M.A., Clarke S.M., Inaba A., Dong C.C., Thomas R.K. Crystalline monolayer of dodecanoic acid adsorbed on graphite from n-heptane solution. J Phys Chem. B102:1998;777-781.
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J Phys Chem
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, pp. 777-781
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Castro, M.A.1
Clarke, S.M.2
Inaba, A.3
Dong, C.C.4
Thomas, R.K.5
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38
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0032073235
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Krypton adsorption on graphite pre-plated with dichloromethane
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Madih-Ayadi K., Dupont-Pavlovsky N., Ceva T., Convert P., Croset B., Ayadi A. Krypton adsorption on graphite pre-plated with dichloromethane. Surf Sci. 405:1998;192-200.
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Surf Sci
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, pp. 192-200
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Ceva, T.3
Convert, P.4
Croset, B.5
Ayadi, A.6
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39
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0032025603
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An X-ray diffraction study of sulphur hexafluoride-krypton mixtures on graphite
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Castro M.A., Thomas R.K. An X-ray diffraction study of sulphur hexafluoride-krypton mixtures on graphite. Surf Sci. 399:1998;212-218.
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(1998)
Surf Sci
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, pp. 212-218
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Castro, M.A.1
Thomas, R.K.2
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0001095421
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Hydrogen in mechanically prepared nanostructured graphite
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Orimo S., Majer G., Fukunaga T., Fujil H. Hydrogen in mechanically prepared nanostructured graphite. Appl Phys Letts. 75:1999;3093-3095.
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Appl Phys Letts
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Neutron diffraction investigation of water on MgO(001) surfaces, from monolayer to bulk condensation
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Demirdjian B., Suzanne J., Ferry D., Coulomb J.P., Giordano L. Neutron diffraction investigation of water on MgO(001) surfaces, from monolayer to bulk condensation. Surf Sci. 462:2000;L581-L586.
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Suzanne, J.2
Ferry, D.3
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Molecular-dynamics simulations of MgO surfaces in liquid water using a shell-model potential for water
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Leeuw N.H.D., Parker S.C. Molecular-dynamics simulations of MgO surfaces in liquid water using a shell-model potential for water. Phys Rev. B58:1998;13901-13908.
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Surface and pore structure characterisation by neuton scattering techniques
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•Useful review outlining the use of neutron scattering to probe adsorbates in porous media
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Ramsay J.D.F. Surface and pore structure characterisation by neuton scattering techniques. Adv Colloid Interface Sci. 76-77:1998;13-37. •Useful review outlining the use of neutron scattering to probe adsorbates in porous media.
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Adv Colloid Interface Sci
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Ramsay, J.D.F.1
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0001113419
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Intramolecular and lattice melting in n-alkanes: An analog of melting in lipid bilayers
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Hansen F.Y., Herwig K.W. Intramolecular and lattice melting in n-alkanes: an analog of melting in lipid bilayers. Phys Rev Lett. 83:1999;2362-2365.
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Herwig, K.W.2
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47
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0031632448
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Response of the surface phase transition to an abrupt pressure change: Comparitative study of the 2D gas-liquid and 2D fluid-solid phase transitions
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•Although not neutron scattering this paper outlines important dynamic effects in adsorbed layers
-
Kitayama Y., Sakai Y., Asada H. Response of the surface phase transition to an abrupt pressure change: comparitative study of the 2D gas-liquid and 2D fluid-solid phase transitions. Adsorp Sci Technol. 16:1998;391-404. •Although not neutron scattering this paper outlines important dynamic effects in adsorbed layers.
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Adsorp Sci Technol
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, pp. 391-404
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-
Kitayama, Y.1
Sakai, Y.2
Asada, H.3
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48
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0033152202
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Microphase separation kinetics in n-alkane mixtures
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•Phase separation kinetics of bulk and adsorbed alkane mixtures are presented
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Gilbert E.P., Reynolds P.A., Thiyagarajan P., Wozniak D.G., White J.W. Microphase separation kinetics in n-alkane mixtures. Phys Chem Chem Phys. 1:1999;2715-2722. •Phase separation kinetics of bulk and adsorbed alkane mixtures are presented.
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Phys Chem Chem Phys
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Gilbert, E.P.1
Reynolds, P.A.2
Thiyagarajan, P.3
Wozniak, D.G.4
White, J.W.5
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