Unique evidence for a RhIII to RhI reduction by deoxygenation of a carbonate moiety to CO2 by an out-of-sphere phosphane

European Journal of Inorganic Chemistry

Volumn , Issue 7, 2001, Pages 1801-1806

  Aresta, Michele ^a   Dibenedetto, Angela ^a   Tommasi, Immacolata ^a,b  

^a UNIVERSITY OF BARI   (Italy)

^b UNIVERSITÉ DE BOURGOGNE   (France)

Author keywords

Carbon dioxide; Deoxygenation; Phosphanes; Redox chemistry; Rhodium

Indexed keywords

CARBON DIOXIDE; CARBONATION; CATALYST ACTIVITY; CATALYTIC OXIDATION; SODIUM CARBONATE; STYRENE;

% REDUCTIONS; CONDITION; DEOXYGENATIONS; OXIDATION OF STYRENE; PHOSPHANES; REDOX CHEMISTRY;

RHODIUM COMPOUNDS;

PHOSPHANILIC ACID; RHODIUM; STYRENE;

ARTICLE; OSCILLATION; OXIDATION; OXYGENATION; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; REDUCTION; STOICHIOMETRY;

EID: 0034954004     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200107)2001:7<1801::AID-EJIC1801>3.0.CO;2-X     Document Type: Article

References (22)

1. P. J. Hayward, D. M. Blake, G. Wilkinson, C. J. Nyman, J. Am. Chem. Soc. 1970, 92, 5873-5878.
2. L. Malatesta, R. Ugo, J. Chem. Soc. 1963, 2080-2082.
3. M. Aresta, C. F. Nobile, J. Chem. Soc., Dalton Trans. 1977, 708-714.
4. M. Aresta, E. Quaranta, A. Ciccarese, C1 Mol. Chem. 1985, 1, 267-281.
5. M. Aresta, I. Tommasi, E. Quaranta, C. Fragale, J. Mascetti, M. Tranquille, F. Galan, M. Fouassier, Inorg. Chem. 1996, 35, 4254-4260.
6. M. Borowiak, J. Mol., Catal., 2000, in press.
7. COST-D3/007/94 Project: "Modelling of selective energy transfer, spatial and time coherence in catalytic reactions, tested on carbon dioxide reactions", 1998 Report.
8. M. Aresta, E. Quaranta, I. Tommasi, J. Mascetti, M. Tranquille, M. Borowiak, in Advances in Chemical Conversion for Mitigating Carbon Dioxide, Studies in Surface Science and Catalysis (Eds.: T. Inui, M. Anpo, K. Izui, S. Yanagida, T. Yamaguchi), Elsevier Science B. V., 1998, 114, 677-680.
9. M. Aresta, E. Quaranta, I. Tommasi, Proceedings of the 215th ACS National Meeting, Dallas, Texas, March 29-April 2, 1998, COLL 086.
10. M. Aresta, M. A. Borowiak, M. G. H. Jamroz, I. Tommasi, E. Quaranta, J. Mol. Catal. A 2000, in press.
11. M. Aresta, I. Tommasi, A. Dibenedetto, M. Fouassier, J. Mascetti forthcoming paper.
12. M. Aresta, E. Quaranta, A. Ciccarese, J. Mol. Catal. 1987, 41, 355-359.
13. M. Aresta, C. Fragale, E. Quaranta, I. Tommasi, J. Chem. Soc., Chem. Commun. 1992, 315-317.
14. M. Aresta, A. Dibenedetto, Proceedings of the X Congresso Brasileiro de Catalise, 22-24 September 1999, Salvador, Bahia, Brazil, 410-413.
15. M. Aresta, A. Dibenedetto, Appl. Organomet. Chem., in press.
16. 2 conversion and utilisation in refinery and chemical processing, ACS Meeting, March 26-30, 2000, San Francisco, 108-109.
17. First workshop of the COST D9 Action, Advanced Computational Chemistry of Increasingly Complex Systems, July 2-4, 1999, Geneva, Switzerland.
18. J. C. Dobrowolski, M. H. Jamroz, J. K. Kazimirski, K. Bajdor, M. Borowiak, R. Larsson, J. Mol. Struct. 1999, 483, 183-187.
19. 3] may also be formed, M. Aresta, M. Rossi, A. Sacco, Inorg. Chim. Acta 1969, 3, 227-231.
20. K. Yamamoto, K. Sato Japan Pat., (mar 9, 1953); Chem. Abstr. 1954, 48, 2996.
21. Y. A. Chang, H. Ahamad, Thermodynamic Data on Metal Carbonates and Related Oxides, Warrendale, Pa.: Metallurgical Society of AIME, 1982.
22. D. D. Perrin, W. L. Armarego, D. R. Perrin, Purification of Laboratory Chemical Pergamon Press, Oxford, England, 1986.