The photo-nazarov cyclization of 1-cyclohexenyl(phenyl)methanone revisited - Trapping of the 2-oxyallyl intermediates by olefins

European Journal of Organic Chemistry

Volumn , Issue 14, 2001, Pages 2719-2726

  Leitich, Johannes ^a   Heise, Ingeborg ^a   Rust, Jürgen ^b   Schaffner, Kurt ^a  

^a MAX PLANCK INSTITUTE FOR CHEMICAL ENERGY CONVERSION   (Germany)

^b MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG   (Germany)

Author keywords

Ene reactions; Intermediates; Photochemistry; Reaction mechanisms

Indexed keywords

ALKADIENE; ALKENE; ALLYL COMPOUND; CYCLOPENTADIENE DERIVATIVE; KETONE; OCTANE; OXYGEN;

ARTICLE; CYCLIZATION; IRRADIATION; PHOTOCHEMISTRY; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0034938636     PISSN: 1434193X     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0690(200107)2001:14<2719::aid-ejoc2719>3.0.co;2-z     Document Type: Article

References (14)

1. Unbracketed compounds in Scheme 1 were stable enough to be isolated or detected in solution even after prolonged times at room temperature. In all schemes in this work, arrows bearing "hv" refer to photochemical reactions, while arrows without "hv" refer to dark reactions at room temperature. In all schemes, stereoformulae are intended to designate relative, not absolute, configurations.
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