Kinetic and equilibrium study on the axial-ligand substitution reaction of the head-to-tail α-pyridonate-bridged cis-diammineplatinum(III) dinuclear complex: Trans effect of the axial ligand through the Pt-Pt bond to the opposite axial ligand

European Journal of Inorganic Chemistry

Volumn , Issue 8, 2001, Pages 2081-2088

  Saeki, Nami ^a   Hirano, Yuji ^a   Sasamoto, Yasunari ^a   Sato, Ichiro ^a   Toshida, Tsuyoshi ^a   Ito, Sousei ^a   Nakamura, Noriko ^a   Ishihara, Koji ^a   Matsumoto, Kazuko ^a  

^a WASEDA UNIVERSITY   (Japan)

Author keywords

Kinetics; Platinum; PtIII dimer; Reaction mechanisms; Pyridone

Indexed keywords

BINARY ALLOYS; DIMERS; DISSOCIATION; LIGANDS; MOLECULES; PLATINUM; PLATINUM COMPOUNDS; SUBSTITUTION REACTIONS;

AXIAL LIGAND; HALIDE IONS; NO 2; PT ATOMS; PT-PT BONDS; PTIII DIMER; PYRIDONES; REACTION MECHANISM; TRANS- EFFECTS; Α-PYRIDONE; WATER MOLECULE;

KINETICS;

DIAMINE; DIMER; PLATINUM DERIVATIVE; PYRIDONE DERIVATIVE;

ARTICLE; CHEMICAL INTERACTION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; COMPLEX FORMATION; REACTION ANALYSIS; SPECTROPHOTOMETRY;

EID: 0034920294     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200108)2001:8<2081::aid-ejic2081>3.0.co;2-m     Document Type: Article

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