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note
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The apparent shape of the Dye 2 J-band in Figure 2, with distinct tailing on the longer wavelength side, is not really associated with the Dye 2 J-aggregate. The optical constants of gold change rapidly in the spectral region shorter than ~520 nm; thereby, the high reflectance characteristic of metal drops seriously. In such a spectral region, the reflection absorbance defined in the text no longer simply scales to the absorption coefficient of thin adsorbates on the metal, as confirmed by a numerical simulation of the reflectance based on the Fresnel formula.
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33645931599
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When taken after the irreversible anodic scan, the intensity of XPS signals arising from the S, N, and Cl atoms associated with the dye molecules, which are probably stuck to the irreversibly oxidized dye remains as well, dropped by at least 70%
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When taken after the irreversible anodic scan, the intensity of XPS signals arising from the S, N, and Cl atoms associated with the dye molecules, which are probably stuck to the irreversibly oxidized dye remains as well, dropped by at least 70%.
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