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18
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85163240771
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-
note
-
The twist angle is defined by the O(N)-Fe-O(C) angle of a single hydroxamate ligand projected onto the plane perpendicular to the idealized threefold axis. The idealized twist angle is calculated by the following equation: twist angle = -73.9 + 94.16, where b is a normalized bite and calculated from the bite angle, θ(O-Fe-O) = 2 sin (θ/2). See also refs. 2 and 9.
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19
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85163239998
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note
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[11a] BCT and BCTPT are the abbreviations for bicapped TRENCAM and bicapped TPTCAM, respectively, which are composed of three 2,3-dihydroxyterephthalic acids and two tris(aminoalkyl)amines. See also ref. 11b.
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20
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0001610596
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[11b] T. B. Karpishin, T. D. P. Stack, K. N. Raymond, J. Am. Chem. Soc. 1993, 115, 182-192.
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21
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85163237885
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note
-
111 = 30.6) complex were determined by the potentiometric titration and the spectrophotometric measurement of competition reaction with EDTA according to ref. 2.
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-
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23
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85163238826
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note
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4 were dissolved in 100 mL of water, and then the solution was adjusted pH to 7.4 with 1 M NaOH.
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26
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0032126774
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S. M. Cohen, M. Meyer, K. N. Raymond, J. Am. Chem. Soc. 1998, 120, 6277-6286.
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Cohen, S.M.1
Meyer, M.2
Raymond, K.N.3
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27
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85163238416
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note
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Crystallographic data (excluding structure factors) for the structure reported in this paper has been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-161835. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK [Fax: (internat.) +44-1223/336-033; E-mail: deposit@ccdc.cam.ac.uk].
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28
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85163238223
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Kynoch Press, Birmingham, England, Table 2.2A
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International Tables for X-ray Crystallography, Vol. IV (Eds.: J. A. Ibers, W. C. Hamilton), Kynoch Press, Birmingham, England, 1974, Table 2.2A.
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Ibers, J.A.1
Hamilton, W.C.2
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29
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0003528602
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Molecular Structure Corporation, The Woodlands, TX
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teXsan: Crystal Structure Analysis Package, Molecular Structure Corporation, The Woodlands, TX (1985 & 1992).
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(1985)
Crystal Structure Analysis Package
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