Redox-induced 'zipper' action in the solid state. Unprecedented single-crystal to single-crystal to single-crystal cascade conversions in Cs3Bi7Se12. Framework evolution from 2D to 2D' to 3D [11]

Journal of the American Chemical Society

Volumn 122, Issue 34, 2000, Pages 8319-8320

  Iordanidis, Lykourgos ^a   Kanatzidis, Mercouri G ^a  

^a MICHIGAN STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKALI; SOLVENT;

CRYSTAL STRUCTURE; CRYSTALLIZATION; ELECTRON TRANSPORT; LETTER; OXIDATION; OXIDATION REDUCTION REACTION; STRUCTURE ANALYSIS; X RAY DIFFRACTION;

EID: 0034734339     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0015949     Document Type: Letter

References (21)

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11. (b) Wang, X.; Zhang, H.; Sinkler, W.; Poeppelmeier, K. R.; Marks, L. D. J. Alloys Compd. 1998, 270, 88-94.
12. Iordanidis, L.; Kanatzidis, M. G. Angew. Chem., Int. Ed. Engl. 2000, 119, 1927-1930.
13. 12.
14. 7c earlier in space group Cm: ( c) Cordier, G.; Schäfer, H.; Schwidetzky, C. Rev. Chim. Miner. 1985, 22, 676-683.
15. 7c earlier in space group Cm: ( c) Cordier, G.; Schäfer, H.; Schwidetzky, C. Rev. Chim. Miner. 1985, 22, 676-683.
16. 7c earlier in space group Cm: ( c) Cordier, G.; Schäfer, H.; Schwidetzky, C. Rev. Chim. Miner. 1985, 22, 676-683.
17. 12.
18. 2 = 1.02.
19. 12.
20. 12. Unfortunately, due to the broad shape of the peaks, the integration and the subsequent absorption correction with SADABS were not optimal; consequently, there were residual peaks around the heavy atoms, relatively high R values, and large atomic displacement parameters, particularly for the Cs atoms. Nevertheless, the overall crystal structure, atom connectivity, and presence of Se-Se bonds were clearly determined.
21. The room-temperature electrical conductivity of these systems (∼0.2-2 S/cm) is adequate to carry out this process.