Aqueous hybrid liquid membrane process for metal separation. Part I. A model for transport kinetics and its experimental verification

Journal of Membrane Science

Volumn 169, Issue 1, 2000, Pages 119-132

  Kislik, V ^a   Eyal, A ^a  

^a HEBREW UNIVERSITY OF JERUSALEM   (Israel)

Author keywords

Aqueous hybrid liquid membrane; Heavy metals; Ion exchange membranes; Phosphoric acid; Polyelectrolytes; Selectivity

Indexed keywords

BOUNDARY LAYERS; HEAVY METALS; ION EXCHANGE MEMBRANES; ION SELECTIVE MEMBRANES; MASS TRANSFER; MATHEMATICAL MODELS; PHOSPHORIC ACID; POLYELECTROLYTES; POLYMERIC MEMBRANES; PORE SIZE; SEPARATION; VINYL RESINS;

AQUEOUS HYBRID LIQUID MEMBRANES (AHLM); MASS TRANSFER COEFFICIENTS; POLYVINYLSULFONIC ACID;

LIQUID MEMBRANES;

CADMIUM; COPPER; METAL; PHOSPHORIC ACID; POLYELECTROLYTE; ZINC ION;

KINETICS; LIQUID MEMBRANE; METAL EXTRACTION;

ARTICLE; BOUNDARY LAYER; CONTROLLED STUDY; EXTRACTION; FLOW RATE; ION EXCHANGE; ISRAEL; LIQUID MEMBRANE; NONHUMAN; OSMOTIC PRESSURE; PRIORITY JOURNAL; TRANSPORT KINETICS;

EID: 0034732702     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0376-7388(99)00331-2     Document Type: Article

References (42)

1. Eyal A., Kislik V. Aqueous hybrid liquid membrane. A novel system for separation of solutes using water-soluble polymers as carriers. J. Membr. Sci. 161:1999;201.
2. Donnan F.G. The theory of membrane equilibria. Chem. Rev. 1:1924;73.
3. Donnan F.G. Theory of membrane equilibria. J. Membr. Sci. 100:1995;805.
4. Sionkowski G., Wodzki R. Recovery and concentration of metal ions I. Donnan dialysis. Sep. Sci. Technol. 30:1995;441.
5. Miyoshi H. Diffusion coefficients of ions through ion exchange membrane in Donnan dialysis using ions of different valence. J. Membr. Sci. 141:1998;101.
6. Miyoshi H. Diffusion coefficients of ions through ion exchange membrane in Donnan dialysis using ions of the same valence. Chem. Eng. Sci. 52(7):1997;1087.
7. Miyoshi H. Donnan dialysis with ion-exchange membranes I. Theoretical equation. Sep. Sci. Technol. 31(15):1996;2117.
8. Ktari T., Larchet C., Auclair B. Mass transfer characterization in Donnan dialysis. J. Membr. Sci. 84:1993;53.
9. Ktari T., Larchet C., Auclair B. Simplified flux equation in Donnan dialysis. J. Membr. Sci. 32:1987;251.
10. Zheleznov A., Windmoller D., Korner S., Boddeker K.W. Dialytic transport of carboxylic acids through an anion exchange membrane. J. Membr. Sci. 139:1998;137.
11. F. Helfferich, Ion Exchange, McGraw-Hill, New York, 1962, Chapter 8.
12. Helfferich F. Ion-exchange kinetics. III. J. Am. Chem. Soc. 66:1962;39.
13. Helfferich F. Ion-exchange kinetics. IV. J. Am. Chem. Soc. 67:1963;1157.
14. Lake M.A., Melsheimer S.S. Mass transfer characterization of Donnan dialysis. AIChE J. 24(1):1978;130.
15. Cwirko E.H., Carbonell R.G. A theoretical analysis of Donnan dialysis across charged porous membranes. J. Membr. Sci. 48:1990;155.
16. Cwirko E.H., Carbonell R.G. Transport of electrolytes in charged pores: analysis using the method of spatial averaging. J. Colloid Interface Sci. 129(2):1989;513.
17. Higa M., Tanioka A., Kira A. A novel measurement method of Donnan potential at an interface between a charged membrane and mixed salt solution. J. Membr. Sci. 140:1998;213.
18. Higa M., Tanioka A., Kira A. A study of ion permeation across a charged membrane in multicomponent ion systems as a function of membrane charge density. J. Membr. Sci. 49:1990;145.
19. P. Molyneux, Water-Soluble Synthetic Polymers: Properties and Behavior, Vol. 2, CRC Press, Boca Raton, FL, 1984, p. 12.
20. G.S. Manning, Limiting laws for equilibrium and transport properties of polyelectrolyte solutions, in: E. Seleny et al., Charged and Reactive Polymers Vol. 1, Reidel Dordrecht, Boston, 1974, p.9.
21. Wall F.T., Gill S.J. Interaction of cupric ions with polyacrylic acid. J. Phys. Chem. 58:1954;1128.
22. Breslow D., Kutner A. Polymers and copolymers of sodium ethylenesulfonate. J. Polym. Sci. 27:1958;295.
23. Mika A.M. A new class of polyelectrolyte-filled microfiltration membranes with environmentally controlled porosity. J. Membr. Sci. 108:1995;37.
24. Hansen R.D., Anderson M.L. Anomalous osmosis in dialysis of acids with anion exchange membranes. I & E C Fundamentals. 6(4):1967;543.
25. Tishchenko G. Neosepta microporous ion-exchange membranes in dialysis desalination of immunoglobulin fraction of mouse ascitic fluids. J. Membr. Sci. 113:1996;237.
26. Tishchenko G. Diffusion permeability of track-membranes. Dokl. Akad. Nauk SSSR. 308:1989;655.
27. Kislik V., Eyal A. Hybrid liquid membrane (HLM) system in separation technologies. J. Membr. Sci. 111:1996;259.
28. W.S.W. Ho, K.K. Sirkar, Membrane Handbook, VNR, New York, 1992, pp. 267-273.
29. W.S.W. Ho, K.K. Sirkar, Membrane Handbook, VNR, New York, 1992, p. 277, pp. 485-493.
30. W.S.W. Ho, K.K. Sirkar, Membrane Handbook, VNR, New York, 1992, pp. 401-403.
31. Onsager L. Reciprocal relations in irreversible processes, I & II. J. Phys. Rev. I. 37:1931;405.
32. Onsager L. Reciprocal relations in irreversible processes, I & II. J. Phys. Rev. II. 38:1931;2265.
33. Kedem O., Katchalsky A. Thermodynamic analysis of permeability of biological membranes to nonelectrolytes. Biochim. Biophys. Acta. 27:1958;229.
34. Kedem O., Katchalsky A. Thermodynamics of flow processes in biological systems. Biophys. J. 2(suppl.):1962;53.
35. Staverman A. Theory of measurement of osmotic pressure. Rec. Trav. Chim. 70:1951;344.
36. H. Spriggs, N. Li, Liquid permeation through polymeric membranes, in: P. Mears (Ed.), Membrane Separation Processes, Elsevier, Amsterdam, 1976.
37. Noble R.D. Analysis of facilitated transport with fixed site carrier membranes. J. Membr. Sci. 50:1990;207.
38. Noble R.D. Facilitated transport mechanism in fixed site carrier membranes. J. Membr. Sci. 60:1991;297.
39. 2 in ion exchange membranes. AIChE J. 33(3):1987;480.
40. LeBlanc O.H. Facilitated transport in ion-exchange membranes. J. Membr. Sci. 6:1980;339.
41. Behr J.P., Kirch M., Lehn J.M. Carrier-mediated transport through bulk liquid membrane: dependence of transport rates and selectivity on carrier properties in diffusion-limited process. J. Am. Chem. Soc. 107:1985;241.
42. J.C. Giddings, Unated Separation Science, Wiley, New York, 1991, pp. 38, 45-48, 94, 112-114.