Regio- and stereoselective synthesis of allylboranes via platinum(0)- catalyzed borylation of allyl halides with pinacolborane

Tetrahedron Letters

Volumn 41, Issue 31, 2000, Pages 5877-5880

  Murata, Miki ^a   Watanabe, Shinji ^a   Masuda, Yuzuru ^a  

^a KITAMI INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

Allyl halides; Allylborane; Coupling reactions; Pinacolborane; Platinum catalyst

Indexed keywords

BORANE DERIVATIVE; HALIDE;

ARTICLE; CHEMICAL REACTION; DIASTEREOISOMER; STEREOCHEMISTRY; SYNTHESIS;

EID: 0034729977     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(00)00881-9     Document Type: Article

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23. 3N (0.25 mmol) in toluene (1 ml) was stirred at 50°C for 16 h. GLC analysis of the reaction mixture indicated formation of the corresponding 3b.