Preparation of a new type of homochiral L-proline derived cyclam and their nickel(II) complexes

Tetrahedron Letters

Volumn 41, Issue 31, 2000, Pages 5967-5970

  Achmatowicz, Michal ^a   Jurczak, Janusz ^a,b  

^a INSTITUTE OF ORGANIC CHEMISTRY   (Poland)

^b UNIVERSITY OF WARSAW   (Poland)

Author keywords

Chiral complexes; Lactams; Macrocycles; Nickel and compounds

Indexed keywords

CYCLAM DERIVATIVE; MACROCYCLIC COMPOUND; METAL ION; NICKEL COMPLEX; PROLINE;

ALKYLATION; ARTICLE; CATALYSIS; COMPLEX FORMATION; CRYSTAL STRUCTURE; CYCLIZATION; EPOXIDATION; HYDROLYSIS; REDUCTION; SYNTHESIS;

EID: 0034729960     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(00)00901-1     Document Type: Article

References (20)

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17. 3, 30°C, TMS): δ=178.6, 74.4, 57.3, 55.7, 40.4, 26.5, 24.8, 21.2.
18. 3OD, 30°C): δ=75.0, 70.1, 65.4, 60.0, 58.7, 58.2, 55.3, 49.4, 38.0, 29.4, 26.9, 25.8, 24.6, 24.4, 24.2.
19. 3, 30°C, TMS): δ=64.1, 56.4, 54.3, 52.4, 51.8, 29.7, 27.6, 27.2, 24.1.
20. Crystal structure analysis was performed for ligand 7 and complexes 10-12. Complete results are soon to be published in a full paper.