Palladium-catalyzed reaction of arynes with a bis-π-allyl palladium complex. An efficient method for the synthesis of 1,2-diallylated derivatives of benzene

Tetrahedron Letters

Volumn 41, Issue 5, 2000, Pages 729-731

  Yoshikawa, Eiji ^a   Radhakrishnan, K V ^a   Yamamoto, Yoshinori ^a  

^a TOHOKU UNIVERSITY   (Japan)

Author keywords

Arynes; Bis allyl palladium complex; Diallyl benzene; Palladium catalysts

Indexed keywords

ALLYL COMPOUND; PALLADIUM COMPLEX;

ARTICLE; CATALYSIS; CHEMICAL BINDING; CHEMICAL REACTION; CHEMICAL STRUCTURE; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0034728201     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(99)02114-0     Document Type: Article

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8. 4 and the solvent was evaporated in vacuo. The residue obtained was subjected to column chromatography (silica gel, 1% ethyl acetate in hexane as eluent) to afford 8b (0.061 g, 81%) as a colorless liquid.
9. 16O: C, 82.92%; H, 8.57%. Found: C, 82.65%; H, 8.75%.
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