Systematic characterization of prochirality, prostereogenicity, and stereogenicity by means of the sphericity concept

Tetrahedron

Volumn 56, Issue 5, 2000, Pages 735-740

  Fujita, Shinsaku ^a  

^a KYOTO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

Prochirality; Prostereogenicity; Stereogenicity

Indexed keywords

LIGAND;

ARTICLE; ATOM; CHEMICAL STRUCTURE; CHIRALITY; CONCEPT FORMATION; DIASTEREOISOMER; ENANTIOMER; MOLECULE; NOMENCLATURE; PRIORITY JOURNAL; STEREOCHEMISTRY;

EID: 0034723407     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(99)01033-9     Document Type: Article

References (24)

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17. 7 are replaced by the term prostereogenic center.
18. 23 has adopted the term 'stereogenic' in the form of 'chirality elements as stereogenic units of the CIP-system'.
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20. A promolecule is defined as a derivative of an appropriate skeleton with a set of proligands, which are in turn defined as structureless objects with chirality/achirality. See Ref. 21.
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22. s)-orbit, which is determined to be homospheric (Table 2). The relationships between the members of the homospheric orbit are determined to be holotopic by virtue of our membership criterion described in Table 3.
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