메뉴 건너뛰기




Volumn 122, Issue 38, 2000, Pages 9078-9088

Photolysis of hexafluoro-2-butyne/ozone mixtures in cryogenic matrices

Author keywords

[No Author keywords available]

Indexed keywords

ALKYNE; ARGON; BUTANE; CARBENE; FLUORENE DERIVATIVE; KETENE DERIVATIVE; NITROGEN; OZONE;

EID: 0034721452     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja992654h     Document Type: Article
Times cited : (7)

References (44)
  • 9
    • 0040066504 scopus 로고
    • Noyes, W. A.; Hammond, G. S.; Pitts, J. N., Eds.; Wiley-Interscience: New York
    • Cvetanovic, R. J. Advances in Photochemistry; Noyes, W. A.; Hammond, G. S.; Pitts, J. N., Eds.; Wiley-Interscience: New York, 1963; Vol 1.
    • (1963) Advances in Photochemistry , vol.1
    • Cvetanovic, R.J.1
  • 13
    • 27844524038 scopus 로고
    • Harding, L. B.; Wagner, A. F. J. Phys. Chem. 1986, 90, 2974-87; Wagner, A. F. J. Phys. Chem. 1990, 94, 2453-64
    • (1990) J. Phys. Chem. , vol.94 , pp. 2453-2464
    • Wagner, A.F.1
  • 15
    • 0343603196 scopus 로고    scopus 로고
    • Reference 2c and references therein
    • Reference 2c and references therein.
  • 31
    • 0343365006 scopus 로고
    • 3 charge transfer: Singmaster, K. A.; Piementel, G. C. J. Phys. Chem. 1990, 94, 5226-5229; Jonnalagadda, S.; Chan, S.; Garrido, J.; Bond, J.; Singmaster, K. A. J. Am. Chem. Soc. 1995, 117, 562-563.
    • (1986) J. Chem. Phys. , vol.90 , pp. 529-532
    • Hashimoto, S.1    Akimoto, H.2
  • 32
    • 0000462214 scopus 로고
    • 3 charge transfer: Singmaster, K. A.; Piementel, G. C. J. Phys. Chem. 1990, 94, 5226-5229; Jonnalagadda, S.; Chan, S.; Garrido, J.; Bond, J.; Singmaster, K. A. J. Am. Chem. Soc. 1995, 117, 562-563.
    • (1987) Angew. Chem., Int. Ed. Engl. , vol.91 , pp. 1347-1354
    • Sander, W.1    Patyk, A.2
  • 33
    • 0000857290 scopus 로고
    • 3 charge transfer
    • 3 charge transfer: Singmaster, K. A.; Piementel, G. C. J. Phys. Chem. 1990, 94, 5226-5229; Jonnalagadda, S.; Chan, S.; Garrido, J.; Bond, J.; Singmaster, K. A. J. Am. Chem. Soc. 1995, 117, 562-563.
    • (1987) J. Phys. Chem. , vol.91 , pp. 1347-1354
    • Hashimoto, S.1    Akimoto, H.2
  • 34
    • 0001297425 scopus 로고
    • 3 charge transfer: Singmaster, K. A.; Piementel, G. C. J. Phys. Chem. 1990, 94, 5226-5229; Jonnalagadda, S.; Chan, S.; Garrido, J.; Bond, J.; Singmaster, K. A. J. Am. Chem. Soc. 1995, 117, 562-563.
    • (1990) J. Phys. Chem. , vol.94 , pp. 5226-5229
    • Singmaster, K.A.1    Piementel, G.C.2
  • 38
    • 0343167772 scopus 로고    scopus 로고
    • note
    • We did not include the spectrum of the butanedione because it is not a clean spectrum. A side product of the reaction was also present in the sample. We were not able to completely remove this species from the butanedione sample without the butanedione decomposing.)
  • 39
    • 0343167771 scopus 로고    scopus 로고
    • note
    • Perfluoro-2-butanone was purchased from Aldrich. A matrix spectrum of the butanone was obtained (1:200 Ar matrix) for the comparison.
  • 40
    • 0342298276 scopus 로고
    • Ph.D. Thesis, Dartmouth College, Hanover, NH
    • Laganis, E. D. Ph.D. Thesis, Dartmouth College, 1979 Hanover, NH.
    • (1979)
    • Laganis, E.D.1
  • 41
    • 0343167770 scopus 로고    scopus 로고
    • note
    • 2 doping experiments, traces of perfluoroacetic anhydride could be detected in our work after extended photolysis times. This assignment was confirmed by obtaining the matrix IR spectrum of perfluoroacetic anhydride purchased from Aldrich. As one might expected, extended photolysis the concentration of oxygen molecule produced by the photolysis of ozone increases, and the trapping abilities of the oxygen become apparent.
  • 44
    • 0343603191 scopus 로고    scopus 로고
    • unpublished work
    • We have initiated studies on the O atom addition to dimethylacetylene that suggest we have trapped the ketocarbene in this system as well as another intermediate that is very IR-sensitive. Wade, E. A.; Clemes, T.; Clohessy, C.; Singmaster, K. A. unpublished work.
    • Wade, E.A.1    Clemes, T.2    Clohessy, C.3    Singmaster, K.A.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.