Coordination chemistry of the novel 5,10,15-tris(pentafluorophenyl)corrole: Synthesis, spectroscopy, and structural characterization of its cobalt(III), rhodium(III), and iron(IV) complexes

Inorganic Chemistry

Volumn 39, Issue 13, 2000, Pages 2704-2705

  Simkhovich, Liliya ^a   Galili, Nitsa ^a   Saltsman, Irena ^a   Goldberg, Israel ^b   Gross, Zeev ^a  

^a TECHNION ISRAEL INSTITUTE OF TECHNOLOGY   (Israel)

^b TEL AVIV UNIVERSITY   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

5,10,15 TRIS(PENTAFLUOROPHENYL)CORROLE; COBALT COMPLEX; COORDINATION COMPOUND; CORRINOID; HEME DERIVATIVE; IRON COMPLEX; MACROCYCLIC COMPOUND; PORPHYRIN DERIVATIVE; RHODIUM COMPLEX; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL BOND; COLOR; COMPLEX FORMATION; SPECTROSCOPY; STRUCTURE ANALYSIS; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 0034717464     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic991342c     Document Type: Article

References (14)

1. Gross, Z.; Galili, N.; Saltsman, I. Angew. Chem., Int. Ed. Engl. 1999, 38, 1427.
2. For an excellent recent review about corroies, see the following. Sessler, J. L.; Weghorn, S. J. Expanded, Contracted, & Isomeric Porphyrins; Pergamon: Oxford, 1997; Chapter 1.
3. 3tpfc is now commercially available from Strem Chemicals (Illinois). (b) Patent pending application no. 126426 (Gross, Z.; Technion).
4. Gross, Z.; Simkhovich, L.; Galili, N. J. Chem. Soc., Chem. Commun. 1999, 599.
5. La Mar, G. N.; Walker, F. A. In The Porphyrins; Dolphin, D., Ed.; Academic Press: New York, 1979; Vol. IV, Chapter 2, pp 61-157.
6. -3) were found near the Fe ion in the corroie center.
7. Vogel, E.; Will, S.; Tilling, A. S.; Neumann, L.; Lex, J.; Bill, E.; Trautwein, A. X.; Wieghardt, K. Angew. Chem., Int. Ed. Engl. 1994, 33, 731.
8. -3) located around the inversion centers represent a disordered solvent included in the lattice (possibly a molecule of n-hexane) that could not be reliably identified. Correspondingly, the solvent content has not been included in the above data.
9. 3 corroles, see the following. Paolesse, R.; Jaquinod, L.; Nurco, D. J.; Mini, S.; Sagone, F.; Boschi, T.; Smith, K. M. J. Chem. Soc., Chem. Commun. 1999, 1307. Paolesse, R.; Licoccia, S.; Bandoli, G.; Dolmella, A.; Boschi, T. Inorg. Chem. 1994, 33, 1171. Boschi, T.; Licoccia, S.; Paolesse, R.; Tagliatesta, P.; Azarnia, M. J. Chem. Soc., Dalton Trans. 1990, 463.
10. 3 corroles, see the following. Paolesse, R.; Jaquinod, L.; Nurco, D. J.; Mini, S.; Sagone, F.; Boschi, T.; Smith, K. M. J. Chem. Soc., Chem. Commun. 1999, 1307. Paolesse, R.; Licoccia, S.; Bandoli, G.; Dolmella, A.; Boschi, T. Inorg. Chem. 1994, 33, 1171. Boschi, T.; Licoccia, S.; Paolesse, R.; Tagliatesta, P.; Azarnia, M. J. Chem. Soc., Dalton Trans. 1990, 463.
11. 3 corroles, see the following. Paolesse, R.; Jaquinod, L.; Nurco, D. J.; Mini, S.; Sagone, F.; Boschi, T.; Smith, K. M. J. Chem. Soc., Chem. Commun. 1999, 1307. Paolesse, R.; Licoccia, S.; Bandoli, G.; Dolmella, A.; Boschi, T. Inorg. Chem. 1994, 33, 1171. Boschi, T.; Licoccia, S.; Paolesse, R.; Tagliatesta, P.; Azarnia, M. J. Chem. Soc., Dalton Trans. 1990, 463.
12. (a) Ehlinger, N.; Scheidt, W. R. Inorg. Chem. 1999, 38, 1316 and references therein,
13. 11
14. Gross, Z.; Galili, N.; Simkhovich, L.; Saltsman, I.; Botoshansky, M.; Bläser, D.; Boese, R.; Goldberg, I. Org. Lett. 1999, 1, 599.