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st is independent of time and includes only isotropic terms that survive the average in time over random motions. The time-dependent contribution, ℋ̂(t), contains the anisotropic terms, identified by a subscript "an" in the text, and only survives over short periods, i.e., an autocorelation time τ, thereby inducing relaxation among levels.
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0342805699
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There are several mechanisms that will provide the necessary density at the nucleus and give the perturbation some width. They are, however, intrinsically weak, and their presence in the electronic matrix element will be blurred by the more intense contributions from other perturbations.
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58
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0342370799
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Reference 13a, pp 31-37.
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60
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0342805695
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note
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19 Support of the possible participation of such excited stales in electron-transfer reactions is provided by this type of spin crossover and related phenomena.
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0342805696
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note
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It must be noted that under particular experimental conditions and for a certain range of B only the MKE exhibits a dependence on B characteristic of a given hfc, SOC, or Zeeman mechanism.
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