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Volumn 39, Issue 13, 2000, Pages 2866-2873

On the adiabaticity contribution to the rate of outer-sphere electron transfers. Reactions of cytochrome c related transition metal compounds

Author keywords

[No Author keywords available]

Indexed keywords

CYTOCHROME C; CYTOCHROME C PEROXIDASE; IRON; METAL DERIVATIVE; ORGANOMETALLIC COMPOUND; RUTHENIUM;

EID: 0034717461     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic991174o     Document Type: Article
Times cited : (4)

References (64)
  • 33
    • 0343675938 scopus 로고    scopus 로고
    • note
    • i.v) is the Dirac delta that imposes the equality of the energies of the departure and arrival states as a condition for the evolution from one to another.
  • 37
    • 0342805700 scopus 로고    scopus 로고
    • note
    • st is independent of time and includes only isotropic terms that survive the average in time over random motions. The time-dependent contribution, ℋ̂(t), contains the anisotropic terms, identified by a subscript "an" in the text, and only survives over short periods, i.e., an autocorelation time τ, thereby inducing relaxation among levels.
  • 55
    • 0342805699 scopus 로고    scopus 로고
    • note
    • There are several mechanisms that will provide the necessary density at the nucleus and give the perturbation some width. They are, however, intrinsically weak, and their presence in the electronic matrix element will be blurred by the more intense contributions from other perturbations.
  • 58
    • 0342370799 scopus 로고    scopus 로고
    • Reference 13a, pp 31-37.
    • (a) Reference 13a, pp 31-37.
  • 60
    • 0342805695 scopus 로고    scopus 로고
    • note
    • 19 Support of the possible participation of such excited stales in electron-transfer reactions is provided by this type of spin crossover and related phenomena.
  • 62
    • 0342805696 scopus 로고    scopus 로고
    • note
    • It must be noted that under particular experimental conditions and for a certain range of B only the MKE exhibits a dependence on B characteristic of a given hfc, SOC, or Zeeman mechanism.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.