Total diastereoselective opening of chiral hydridophosphorane 'triquinphosphoranes' by hexacarbonylmolybdenum: An entry to Mo(CO)5: Chiral oxazaphospholidine complex

Inorganic Chemistry

Volumn 39, Issue 13, 2000, Pages 2951-2953

  Marchi, Caroline ^a   Buono, Gérard ^a  

^a Ecole Centrale Marseille   (France)

Author keywords

[No Author keywords available]

Indexed keywords

HEXACARBONYLMOLYBDENUM; HYDRIDOPHOSPHORANE; MOLYBDENUM; OXAZAPHOSPHOLIDINE; PHOSPHORANE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHIRALITY; COMPLEX FORMATION; NUCLEAR MAGNETIC RESONANCE; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; SPECTROPHOTOMETER; STEREOCHEMISTRY; SYNTHESIS; X RAY DIFFRACTION;

EID: 0034717437     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0000101     Document Type: Article

References (27)

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18. p (78%)]. The TBP structure is in accordance with the X-ray diffraction structure of the triquinphosphorane deriving from N.N′-bis[(-)-norephedrine]ethylene. In this structure, the phosphorus atom adopts a TBP geometry that agrees remarkably well with our computational results. Tlahuextl, M.; Martínez-Martínez, F. J.; Rosales-Hoz, M. J.; Contreras, R. Phosphorus, Sulfur, Silicon Relat. Elem. 1997, 123, 5-19.
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21. 5-phosphatricyclo[6.3.0.01,5]undecane was synthesized from the diaminodiol N.N′-(bis(hydroxyethyl)ethylene)-(1S,2S)-1,2-diphenyl-1,2-diamine (see ref 6b).
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