Effect of variations of the size and structure of the principal alkyl group on alkene elimination from the immonium ions CH3CH2CH=N+ (CH3)R, CH3CH2CH2CH=N+ (CH3)R and CH3CH2CH2CH2CH=N+(CH3)R

International Journal of Mass Spectrometry

Volumn 199, Issue 1-3, 2000, Pages 189-200

  Mandeville, Simon J ^a   Bowen, Richard D ^a   Trikoupis, Moschoula A ^b   Terlouw, Johan K ^b  

^a UNIVERSITY OF BRADFORD   (United Kingdom)

^b MCMASTER UNIVERSITY   (Canada)

Author keywords

Alkene elimination; Degree of freedom effects; Immonium ions; Kinetic energy release; Metastable ions

Indexed keywords

ALKENE; ALKYL GROUP; AMMONIUM DERIVATIVE; CARBON; HYDROGEN; METHYL GROUP;

ARTICLE; CHEMICAL STRUCTURE; DISSOCIATION; ENERGY; MASS SPECTROMETRY; MOLECULAR INTERACTION; MOLECULAR SIZE; STRUCTURE ACTIVITY RELATION;

EID: 0034713501     PISSN: 13873806     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1387-3806(00)00199-8     Document Type: Article

References (39)

1. The expression 'critical energy' corresponds conceptually to the term 'activation energy,' A. Maccoll