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3Rubrcne and 3TTP were observed at 465 nm because this corresponds to the minima in the triplet-triplet absorption spectra of the ring-opened fullerene derivatives.
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3Rubrcne and 3TTP were observed at 465 nm because this corresponds to the minima in the triplet-triplet absorption spectra of the ring-opened fullerene derivatives.
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note
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Unfortunately, despite repeated attempts, no luminescence from these ring-opened fullerene derivatives could be detected under any experimental conditions to further confirm the triplet energy assignment. The calculated emission wavelengths are outside the sensitive region of the photomultiplier'in the phosphorimeter.
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29
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33645944150
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No change in the UV-vis spectra of the derivatives was noted after laser photolysis.
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No change in the UV-vis spectra of the derivatives was noted after laser photolysis.
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