Thermolysis and photosensitized oxygenation of tetrasubstituted cyclopropenes

Journal of Organic Chemistry

Volumn 65, Issue 6, 2000, Pages 1807-1817

  Frimer, Aryeh A ^a   Afri, Michal ^a   Baumel, Simeon D ^a   Gilinsky Sharon, Pessia ^a   Rosenthal, Zilpa ^a   Gottlieb, Hugo E ^a  

^a BAR ILAN UNIVERSITY   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

BICYCLO COMPOUND; HYDROPEROXIDE; PROPYLENE;

ARTICLE; HEAT; ISOMERISM; OXYGENATION; PHOTOCHEMISTRY; PHOTOOXIDATION; PHOTOSENSITIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS;

EID: 0034708423     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo991803b     Document Type: Article

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63. 26b give a substantially higher value of 3.164 Å. In Scheme 8, we have given the average value of 3.088 Å. (a) Shand, W., Jr.; Schomaker, V.; Fischer, J. F. J. Am. Chem. Soc. 1944, 66, 636-640. See also: Huang, Y. S.; Beaudet, R. A. J. Chem. Phys. 1970, 52, 935-940. (b) Bingham, R. C.; Dewar, M. J. S.; Lo, D. H. J. Am. Chem. Soc. 1975, 97, 1294-1301.
64. 26b give a substantially higher value of 3.164 Å. In Scheme 8, we have given the average value of 3.088 Å. (a) Shand, W., Jr.; Schomaker, V.; Fischer, J. F. J. Am. Chem. Soc. 1944, 66, 636- 640. See also: Huang, Y. S.; Beaudet, R. A. J. Chem. Phys. 1970, 52, 935-940. (b) Bingham, R. C.; Dewar, M. J. S.; Lo, D. H. J. Am. Chem. Soc. 1975, 97, 1294-1301.
65. 26b give a substantially higher value of 3.164 Å. In Scheme 8, we have given the average value of 3.088 Å. (a) Shand, W., Jr.; Schomaker, V.; Fischer, J. F. J. Am. Chem. Soc. 1944, 66, 636- 640. See also: Huang, Y. S.; Beaudet, R. A. J. Chem. Phys. 1970, 52, 935-940. (b) Bingham, R. C.; Dewar, M. J. S.; Lo, D. H. J. Am. Chem. Soc. 1975, 97, 1294-1301.
66. 27b yield a substantially lower value of 3.229 Å. In Scheme 8, we have cited the experimental value of 3.241 Å. (a) Kemp, M. K.; Flygare, W. H. J. Am. Chem. Soc. 1969, 91, 3163-3167. See also: Allen, F. A. Tetrahedron 1982, 38, 645-655. (b) Eckert- Makasic, M.; Makasic, Z. B. J. Mol. Struct., THEOCHEM 1982, 86, 325-340.
67. 27b yield a substantially lower value of 3.229 Å. In Scheme 8, we have cited the experimental value of 3.241 Å. (a) Kemp, M. K.; Flygare, W. H. J. Am. Chem. Soc. 1969, 91, 3163-3167. See also: Allen, F. A. Tetrahedron 1982, 38, 645-655. (b) Eckert- Makasic, M.; Makasic, Z. B. J. Mol. Struct., THEOCHEM 1982, 86, 325-340.
68. 27b yield a substantially lower value of 3.229 Å. In Scheme 8, we have cited the experimental value of 3.241 Å. (a) Kemp, M. K.; Flygare, W. H. J. Am. Chem. Soc. 1969, 91, 3163-3167. See also: Allen, F. A. Tetrahedron 1982, 38, 645-655. (b) Eckert-Makasic, M.; Makasic, Z. B. J. Mol. Struct., THEOCHEM 1982, 86, 325-340.
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86. (a) 13 ft × 1/4 in. copper column packed with 20% Carbowax 20M Chromosorb WAW.
87. (b) 13 ft × 1/4 in. copper column packed with 7% SE-30 on Chromosorb WAW.