Catalysis of a Diels-Alder reaction by amidinium ions

Journal of Organic Chemistry

Volumn 65, Issue 6, 2000, Pages 1697-1701

  Schuster, Tilmann ^a   Kurz, Markus ^a   Göbel, Michael W ^a  

^a GOETHE UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

AMIDINE; CATION; ESTRONE; GUANIDINE DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; CONTROLLED STUDY; CYCLIZATION; HYDROGEN BOND; MOLECULAR RECOGNITION; REACTION ANALYSIS;

EID: 0034708422     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo991372x     Document Type: Article

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33. The observation of significant enantioselectivities gives further evidence that amidinium catalysis is due to complex formation of cation and dienophile. Chirality transfer from amidinium ions to cycloadduct 8 cannot be explained by simple acid catalysis.