Nickel catalyzed cascade conversion of propargyl halide and propargyl alcohol into 4,6-dimethyl-5-cyano-2-pyrone in water

Journal of the Chemical Society, Perkin Transactions 1

Volumn , Issue 10, 2000, Pages 1493-1494

  Rosas, Noé ^a   Salmon, Manuel ^b   Sharma, Pankaj ^a   Alvarez, Cecilio ^a   Ramirez, Rodrigo ^b   Garcia, José Luis ^a   Arzoumanian, Henri ^a  

^a Instituto de Quimica de la UNAM   (Mexico)

^b AIX MARSEILLE UNIVERSITY   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CARBONYLATION; CATALYSIS; CHEMICAL BONDS; NEGATIVE IONS; SYNTHESIS (CHEMICAL);

HYDROCYANATION;

UNSATURATED COMPOUNDS;

EID: 0034697431     PISSN: 14704358     EISSN: None     Source Type: Journal    
DOI: 10.1039/b002338h     Document Type: Article

References (13)

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6. Presented in part at Organo-Metallic Chemistry directed towards Organic Synthesis, OMCOS 10, Versailles, France, July, 1999.
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13. Under these experimental conditions, substituted homologues react extremely sluggishly and do not afford any detectable amount of 2-pyrone products. This could be due, in part, to the reduced solubility of these substrates in the aqueous medium. Further work, in order to extend the scope of this reaction, is underway.