A reductive amination of carbonyls with amines using decaborane in methanol

Journal of the Chemical Society, Perkin Transactions 1

Volumn , Issue 2, 2000, Pages 145-146

  Bae, Jong Woo ^a   Lee, Seung Hwan ^a   Cho, Young Jin ^a   Yoon, Cheol Min ^a  

^a Korea University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID; ALDEHYDES; AMINATION; CHROMATOGRAPHY; HYDROGENATION; KETONES; METHANOL; ORGANIC SOLVENTS; REDUCTION; SYNTHESIS (CHEMICAL);

REDUCTIVE AMINATION;

AMINES;

EID: 0034695702     PISSN: 14704358     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (20)

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19. Decaborane in this reaction seems to have a dual action: a catalyst for the imine formation as well as a mild reducing agent for the reduction of the imine.
20. f value of the adduct was higher than that of the corresponding amine when a mixture of ethyl acetate and n-hexane (1:4) was used as the developing solvent.