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Volumn 195-196, Issue , 2000, Pages 215-223

The temperature dependence of absolute gas phase acidities

Author keywords

Acidity; Bond dissociation energy; Electron affinity; Gas phase anthalpy; Thermochemical

Indexed keywords

ACIDITY; ARTICLE; CALCULATION; CHEMICAL BOND; DISSOCIATION; ELECTRON; ENTHALPY; GAS; REACTION ANALYSIS; TEMPERATURE DEPENDENCE; THERMODYNAMICS;

EID: 0034695385     PISSN: 13873806     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1387-3806(99)00219-5     Document Type: Article
Times cited : (13)

References (81)
  • 1
    • 0007816713 scopus 로고
    • Techniques for the Study of Ion-Molecule Reactions, J.M. Farrar, W.H. Saunders Jr. (Eds.), Techniques of Chemistry, Vol. 20, Wiley, New York
    • (1988)
  • 2
    • 0007827378 scopus 로고    scopus 로고
    • The term 'gas phase acidity' strictly refers to free energy, whereas the enthalpic term is 'anion proton affinity.' Because of the accuracy of statistical mechanics by which the entropy of acidity can be calculated for many such acids, and the small range of such entropic effects, they are often used interchangeably in a loose sense.
  • 3
    • 0007819632 scopus 로고    scopus 로고
    • Negative Ion Energetics Data, in W.G. Mallard, P.J. Linstrom (Eds.), The NIST Chemistry WebBook, NIST Standard Reference Database Number 69, March 1998, National Institute of Standards and Technology, Gaithersburg, MD, 20899
    • Bartmess, J.E.1
  • 4
    • 0007822138 scopus 로고    scopus 로고
    • Ionization Energy Evaluation, in [3]
    • Lias, S.G.1
  • 11
    • 0007817536 scopus 로고
    • Thermochemical Kinetics, 2nd ed., Wiley, New York
    • (1976)
    • Benson, S.W.1
  • 15
    • 0007863652 scopus 로고
    • Quantum Chemistry, Prentice Hall, Englewood Cliffs, NJ
    • (1961)
    • Pitzer, K.S.1
  • 17
    • 0007869412 scopus 로고    scopus 로고
    • QCPE 455, Quantum Chemistry Program Exchange, Indiana Univ., Bloomington, IN 47405
  • 22
    • 0007816714 scopus 로고    scopus 로고
    • The uncertainty in the acidity is the rms average of those for the EA and the BDE


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.