Oligomerization of early transition metal {M(OH)3}2(μ-C2) acetylides toward the formation of [(OH)3MC](n) (n = 4, 6) metalla carbides: A theoretical study by density functional theory

Inorganic Chemistry

Volumn 39, Issue 6, 2000, Pages 1147-1151

  Belanzoni, Paola ^a   Sgamellotti, Antonio ^a   Re, Nazzareno ^b   Floriani, Carlo ^c  

^a UNIVERSITY OF PERUGIA   (Italy)

^b UNIVERSITY OF CHIETI   (Italy)

^c UNIVERSITY OF LAUSANNE   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

METAL COMPLEX; POLYENE; TITANIUM; VANADIUM;

ARTICLE; CHEMICAL STRUCTURE; COMPLEX FORMATION; CONFORMATIONAL TRANSITION; DENSITY; ITALY; METAL INDUSTRY; OLIGOMERIZATION;

EID: 0034689035     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic990845f     Document Type: Article

References (5)

1. Kosolapova, T. Ya. Carbides: Properties, Production and Applications; Plenum: New York, 1971.
2. Diederich, F.; Rubin, Y. Angew. Chem., Int. Ed. Engl. 1992, 31, 1101.
3. Beck, W.; Niemer, B.; Wieser, M. Angew. Chem., Int. Ed. Engl. 1993, 32, 923 and references therein.
4. Lang, H. Angew. Chem., Int. Ed. Engl. 1994, 34, 547 and references therein.
5. Guo, B. C.; Kerns, K. P.; Castleman, A. W., Jr. Science 1992, 255, 1411.