메뉴 건너뛰기




Volumn 6, Issue 16, 2000, Pages 3033-3042

Electrochemical reduction of a bridging imide: Generation of ammonia at a dimolybdenum tris(μ-thiolate) site

Author keywords

Ammine complexes; Bridging ligands; Cyclic voltammetry; Molybdenum; Nitrogen fixation; Nitrogen ligands

Indexed keywords

ACETONITRILE; ACID; AMINE; AMMONIA; CHLORIDE; ELECTROLYTE; IMIDE; MOLYBDENUM COMPLEX; NITROGEN;

EID: 0034683090     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3765(20000818)6:16<3033::AID-CHEM3033>3.0.CO;2-A     Document Type: Article
Times cited : (19)

References (35)
  • 13
    • 0002345759 scopus 로고
    • a) D. Sellmann, Angew. Chem. 1993, 105, 67, Angew. Chem. Int. Ed. Engl. 1993, 32, 64;
    • (1993) Angew. Chem. , vol.105 , pp. 67
    • Sellmann, D.1
  • 14
    • 0040413901 scopus 로고
    • a) D. Sellmann, Angew. Chem. 1993, 105, 67, Angew. Chem. Int. Ed. Engl. 1993, 32, 64;
    • (1993) Angew. Chem. Int. Ed. Engl. , vol.32 , pp. 64
  • 17
    • 85037487477 scopus 로고
    • Ph.D. Thesis, University of Sussex
    • a) M. Y. Mohammed, Ph.D. Thesis, University of Sussex, 1990;
    • (1990)
    • Mohammed, M.Y.1
  • 18
    • 85037488510 scopus 로고
    • Ph.D. Thesis, Université de Bretagne Occidentale, Brest
    • b) M. L. Abasq, Ph.D. Thesis, Université de Bretagne Occidentale, Brest, 1994;
    • (1994)
    • Abasq, M.L.1
  • 24
    • 85037461279 scopus 로고    scopus 로고
    • note
    • p are the potential and the current of the anodic and of the cathodic peak of a reversible process, respectively; an EC process is comprised of an electron transfer step (E) followed by a chemical reaction (C). CV and CPE stand for cyclic voltammetry and controlled-potential electrolysis, respectively.
  • 25
    • 85037460647 scopus 로고    scopus 로고
    • note
    • + to that of the product(s).
  • 28
    • 85037484236 scopus 로고    scopus 로고
    • note
    • 3(μ-N)] which would be formed along with amide 2 has never been observed.
  • 29
    • 85037482033 scopus 로고    scopus 로고
    • note
    • 3(μ-NH)].
  • 30
    • 85037489410 scopus 로고    scopus 로고
    • note
    • + is essentially unaffected by the addition of acid.
  • 31
    • 85037449644 scopus 로고    scopus 로고
    • note
    • + is regenerated, see Figures 1b-d.
  • 32
    • 85037490886 scopus 로고    scopus 로고
    • note
    • 2O.
  • 33
    • 85037462533 scopus 로고    scopus 로고
    • note
    • 3(μ-TsO)].


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.