Synthesis of a complexed 2,2-bisphosphirane

Angewandte Chemie - International Edition

Volumn 39, Issue 16, 2000, Pages 2943-2945

  Vlaar, Mark J M ^a   Ehlers, Andreas W ^a   De Kanter, Frans J J ^a   Schakel, Marius ^a   Spek, Anthony L ^b   Lammertsma, Koop ^a  

^a VU UNIVERSITY AMSTERDAM   (Netherlands)

^b UTRECHT UNIVERSITY   (Netherlands)

Author keywords

Ab initio calculations; Phosphinidene complexes; Phosphiranes; Small ring systems; Tungsten

Indexed keywords

2,2 BISPHOSPHIRANE; ALKENE; ORGANOPHOSPHORUS COMPOUND; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL REACTION; ISOMERISM; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; STRUCTURE ACTIVITY RELATION; SYNTHESIS;

EID: 0034682931     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3773(20000818)39:16<2943::AID-ANIE2943>3.0.CO;2-I     Document Type: Article

References (36)

1. a) F. Mathey, Chem. Rev. 1990, 90, 997-1025;
2. b) F. Mathey, Angew. Chem. 1987, 99, 285-296; Angew. Chem. Int. Ed. Engl. 1987, 26, 275-286;
3. b) F. Mathey, Angew. Chem. 1987, 99, 285-296; Angew. Chem. Int. Ed. Engl. 1987, 26, 275-286;
4. Multiple bonds and low coordination in phosphorus chemistry (Eds.: M. Regitz, O. Scherer), Thieme, Stuttgart, 1990.
5. a) J.-T. Hung, S.-W. Wang, G. M. Gray, K. Lammertsma, J. Org. Chem. 1993, 58, 6786-6790;
6. b) L. Weber, E. Luker, R. D. Boese, Organometallics 1988, 7, 978-983;
7. M. Baudler, W. Leonhardt, Angew. Chem. 1983, 95, 632-633; Angew. Chem. Int. Ed. Engl. 1983, 22, 632-633;
8. M. Baudler, W. Leonhardt, Angew. Chem. 1983, 95, 632-633; Angew. Chem. Int. Ed. Engl. 1983, 22, 632-633;
9. K. Lammertsma, B. Wang, J.-T. Hung, A. W. Ehlers, G. M. Gray, J. Am. Chem. Soc. 1999, 121, 11650-11655.
10. J. Erden in Comprehensive Heterocyclic Chemistry II, Vol. 1A (Eds.: A. R. Katritzky, C. W. Rees, E. F. V. Scriven, A. Padwa), Pergamon, Oxford, 1996, pp. 145-171.
11. a) M. Breuninger, R. Schwesinger, B. Gallenkamp, K.-H. Müller, H. Fritz, D. Hunkler, H. Prinzbach, Chem. Ber. 1980, 13, 3161-3186;
12. b) B. Trupp, H. Fritz, H. Prinzbach, Angew. Chem. 1989, 101, 1381-1383; Angew. Chem. Int. Ed. Engl. 1989, 29, 1345-1347;
13. b) B. Trupp, H. Fritz, H. Prinzbach, Angew. Chem. 1989, 101, 1381-1383; Angew. Chem. Int. Ed. Engl. 1989, 29, 1345-1347;
14. R. S. Atkinson, E. Barker, C. K. Meades, H. A. Albar, Chem. Commun. 1998, 29-30;
15. M. W. Majchrzak, A. Kotelko, J. B. Lambert, Org. Magn. Reson. 1983, 21, 706-710.
16. H. Suzuki, N. Tokitoh, R. Okazaki, J. Am. Chem. Soc. 1994, 116, 11572-11573.
17. K. Hartke, A. Kumar, J. Köster, G. Henssen, T. Kissel, T. Kämpchen, Chem. Ber. 1982, 115, 3096-3106.
18. a) M. Link, E. Niecke, M. Nieger, Chem. Ber. 1994, 127, 313-319;
19. b) N. H. T. Huy, L. Ricard, F. Mathey, J. Chem. Soc. Dalton Trans. 1999, 2409-2410.
20. a) A. Marinetti, C. Charrier, F. Mathey, J. Fischer, Organometallics 1985, 4, 2134-2138;
21. b) K. Lammertsma, P. Chand, S.-W. Yang, J.-T. Hung, Organometallics 1988, 7, 1875-1876;
22. J.-T. Hung, K. Lammertsma, Organometallics 1992, 11, 4365-4366;
23. J.-T. Hung, S.-W. Yang, P. Chand, G. M. Gray, K. Lammertsma, J. Am. Chem. Soc. 1994, 116, 10966-10971.
24. a) A. Marinetti, F. Mathey, Organometallics 1984, 3, 456-461;
25. b) B. Wang, C. H. Lake, K. Lammertsma, J. Am. Chem. Soc. 1996, 118, 1690-1695;
26. M. J. van Eis, T. Nijbacker, F. J. J. de Kanter, W. H. de Wolf, K. Lammertsma, F. Bickelhaupt, J. Am. Chem. Soc. 2000, 122, 3033-3036;
27. J.-T. Hung, K. Lammertsma, J. Org. Chem. 1993, 58, 1800-1803;
28. e) K. Lammertsma, J.-T. Hung, P. Chand, G. M. Gray, J. Org. Chem. 1992, 57, 6557-6560.
29. K. Gollnick, A. Griesbeck, Tetrahedron 1984, 40, 3235-3250.
30. a) S. Sorensen, H. J. Jakobsen, Org. Magn. Reson. 1977, 9, 101-104;
31. b) R. K. Harris, M. S. Jones, A. M. Kenwright, Magn. Reson. Chem. 1993, 31, 1085-1087.
32. a) F. Mercier, B. Deschamps, F. Mathey, J. Am. Chem. Soc. 1989, 111, 9098-9100;
33. b) X. Li, S. I. Weissman, T.-S. Lin, P. P. Gaspar, J. Am. Chem. Soc. 1996, 116, 7899-7900.
34. 1 = 0.0312 (6350 reflections with 1 > 2σ(I); wR2 = 0.072; S = 1.045). The data ware corrected for absorption using PLATON/DELABS. Hydrogen atoms were taken into account at calculated positions. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-138219. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+44)1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
35. O. Bastiansen, A. de Meijere, Angew. Chem. 1966, 78, 142-143; Angew. Chem. Int. Ed. Engl. 1966, 5, 124-125.
36. O. Bastiansen, A. de Meijere, Angew. Chem. 1966, 78, 142-143; Angew. Chem. Int. Ed. Engl. 1966, 5, 124-125.