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Solntsev, K.A.5
Strauss, S.H.6
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76
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85037486407
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-
note
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2 groups. Their effect is indeed visible, since the CO vibrations are very slightly, but systematically, more energetic with the more electron-donating N-ethyl imidazole compared to N-methyl. This observation further supports that each absorption corresponds to an imidazole-CuCO moiety.
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77
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0000435228
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S. Blanchard, M.-N. Rager, A. F. Duprat, O. Reinaud, New J. Chem. 1998, 1143-1146.
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(1998)
New J. Chem.
, pp. 1143-1146
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-
Blanchard, S.1
Rager, M.-N.2
Duprat, A.F.3
Reinaud, O.4
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78
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85037455766
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note
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-1). This was attributed to the flexibility of the Cu-CO complex associated to a very nonpolar pocket. See ref. [45].
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-
-
-
79
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85037480783
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note
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-1 for 4a, 4b, 4c, and 4d, respectively).
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-
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80
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0038633748
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O. Sénèque, M.-N. Rager, M. Giorgi, O. Reinaud, J. Am. Chem. Soc. 2000, 122, 6183-6189.
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(2000)
J. Am. Chem. Soc.
, vol.122
, pp. 6183-6189
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Sénèque, O.1
Rager, M.-N.2
Giorgi, M.3
Reinaud, O.4
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81
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0348114339
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Biosym/MSI, San Diego, CA
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The calixarenes were sketched and optimized by using the application of the esff force field of the Biosym package Insight/Discover, Release 95.0, Biosym/MSI, San Diego, CA, 1995, on an IBM RISC 6 K workstation. The standard Discover3 algorithms were selected with their default inputs (0.001 for BFGS Newton energy convergence). Because of the medium size of the molecules, no cutoff was used to compute the nonbond contribution.
-
(1995)
Insight/Discover, Release 95.0
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82
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85037469647
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note
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-1 , 3) special effects, such as π stacking are not taken into account, these results are indicative of a more important steric crowding in conformation B for compounds 4c, d than for 4a, b, and not of inaccessible conformation B to family 4a, b..
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83
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33847799494
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C. Mealli, C. S. Arcus, J. L. Wilkinson, T. J. Marks, J. A. Ibers, J. Am. Chem. Soc. 1976, 98, 711-718.
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(1976)
J. Am. Chem. Soc.
, vol.98
, pp. 711-718
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Mealli, C.1
Arcus, C.S.2
Wilkinson, J.L.3
Marks, T.J.4
Ibers, J.A.5
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84
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85037468882
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note
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Examples of NMR studies revealing the loss of symmetry at low temperature in solution are rare (see ref. [62]).
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