Asymmetric synthesis of 2-methyl cyclohexane carboxylic acids by heterogeneous catalysis: Mechanistic aspects

Chemistry - A European Journal

Volumn 6, Issue 6, 2000, Pages 949-958

  Besson, Michèle ^a   Delbecq, Françoise ^a   Gallezot, Pierre ^a   Neto, Samuel ^a   Pinel, Catherine ^a  

^a INST DE RECHERCHES SUR LA CATALYSE   (France)

Author keywords

Aromatic rings; Diastereoselectivity; Heterogeneous catalysis; Hydrogenations; Steric hindrance

Indexed keywords

AROMATIC COMPOUND; CARBOXYLIC ACID DERIVATIVE; CYCLOHEXANE DERIVATIVE; RUTHENIUM;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; DIASTEREOISOMER; HYDROGENATION; MOLECULAR MODEL; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 0034677690     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3765(20000317)6:6<949::AID-CHEM949>3.0.CO;2-H     Document Type: Article

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26. 1 was detected, allowed us to verify that there was actually no trans-2-methyl cyclohexane carboxylic acid produced.
27. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-125671. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 HEZ, UK (fax: (+ 44) 1223 336-033; e-mail: deposit@cede.cam.ac.uk).
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