Supramolecular control of reactivity in the solid state using linear molecular templates [4]

Journal of the American Chemical Society

Volumn 122, Issue 32, 2000, Pages 7817-7818

  MacGillivray, Leonard R ^a,b   Reid, Jennifer L ^a   Ripmeester, John A ^a  

^a NATIONAL RESEARCH COUNCIL CANADA   (Canada)

^b University of Iowa ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL REACTION; CHEMICAL STRUCTURE; CRYSTALLIZATION; HYDROGEN BOND; LETTER; PHOTOREACTIVATION; PROTON NUCLEAR MAGNETIC RESONANCE; SOLID STATE; SYNTHESIS;

EID: 0034674918     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja001239i     Document Type: Letter

References (33)

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18. (a) Template strategies to solid-state synthesis have been described. Molecule synthesis, see: Cho, T. H.; Chaudhuri, B.; Snider, B. B.; Foxman, B. M. Chem. Commun. 1996, 1337. Polymer synthesis, see: (b) Kane, J. J.; Liao, R.-F.; Lauher, J. W.; Fowler, F. W. J. Am. Chem. Soc. 1995, 117, 12003. Vela, M. J.; Snider, B. B.; Foxman, B. M. Chem. Mater. 1998, 10, 3167. Coa, G.; Mallouk, T. E. J. Solid State Chem. 1991, 94, 59. (e) Tieke, B.; Wegner, G. Makromol. Chem., Rapid. Commun. 1981, 2, 543. (f) Chatani, Y. Prog. Polym. Sci. Jpn 1974, 7, 149. See also ref 7.
19. (a) Template strategies to solid-state synthesis have been described. Molecule synthesis, see: Cho, T. H.; Chaudhuri, B.; Snider, B. B.; Foxman, B. M. Chem. Commun. 1996, 1337. Polymer synthesis, see: (b) Kane, J. J.; Liao, R.-F.; Lauher, J. W.; Fowler, F. W. J. Am. Chem. Soc. 1995, 117, 12003. Vela, M. J.; Snider, B. B.; Foxman, B. M. Chem. Mater. 1998, 10, 3167. Coa, G.; Mallouk, T. E. J. Solid State Chem. 1991, 94, 59. (e) Tieke, B.; Wegner, G. Makromol. Chem., Rapid. Commun. 1981, 2, 543. (f) Chatani, Y. Prog. Polym. Sci. Jpn 1974, 7, 149. See also ref 7.
20. (a) Template strategies to solid-state synthesis have been described. Molecule synthesis, see: Cho, T. H.; Chaudhuri, B.; Snider, B. B.; Foxman, B. M. Chem. Commun. 1996, 1337. Polymer synthesis, see: (b) Kane, J. J.; Liao, R.-F.; Lauher, J. W.; Fowler, F. W. J. Am. Chem. Soc. 1995, 117, 12003. Vela, M. J.; Snider, B. B.; Foxman, B. M. Chem. Mater. 1998, 10, 3167. Coa, G.; Mallouk, T. E. J. Solid State Chem. 1991, 94, 59. (e) Tieke, B.; Wegner, G. Makromol. Chem., Rapid. Commun. 1981, 2, 543. (f) Chatani, Y. Prog. Polym. Sci. Jpn 1974, 7, 149. See also ref 7.
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23. Single crystals of 1 were grown by cocrystallization of 4,4-bpe with resorcinol in EtOH/MeCN (1:1). Crystal data for 1: crystal size 0.3 × 0.3 × 0.4 mm, triclinic, space group P1, a = 8.070(1) Å, b = 9.832(1) Å, c = 10.876(1) Å, α = 73.119(1)°, β = 72.563(1)° γ = 66.184(1)°, U = 738.8(1) Å, 2θ = 45°, Mo Kα radiation (λ = 0.71070 Å) fo r Z = 2 and R = 0.054.
24. 1 may form a divergent, polymeric assembly. Studies are underway to determine factors that contribute to formation of the convergent, discrete structure.
25. For details, see Supporting Information.
26. 3 2θ = 45°, Mo Kα radiation (λ = 0.71070 Å) for Z = 2 and R = 0.064.
27. Studies are underway to determine if the crystal structure involving the reactants is maintained during the reaction. See: Enkelmann, V.; Wegner, G.; Novak, K.; Wagener, K. B. J. Am. Chem. Soc. 1993, 115, 10390.
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31. 3, 2θ = 45°, Mo Kα radiation (λ = 0.71070 Å) for Z = 2 and R = 0.059.
32. Galli, S.; Mercandelli, P.; Sironi, A. J. Am. Chem. Soc. 1999, 121, 3767.
33. Fu, G. C.; Nguyen, S. T.; Grubbs, R. H. J. Am. Chem. Soc. 1993, 115, 9856.